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Suspension compounded from difenoconazole and mancozeb and preparation method for suspension

A technology of difenoconazole and mancozeb, which is applied in the directions of botanical equipment and methods, biocides, fungicides, etc., can solve the problems of increasing environmental hazards, environmental pollution, influence of control effects and the like, and achieve economical savings. The effect of production cost, lower use cost and good control effect

Inactive Publication Date: 2012-12-26
河北双吉化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the existing problem is that, for the single agent of difenoconazole and mancozeb, the bacteria develop drug resistance during the use process, which affects the control effect, reduces the utilization rate of the drug, and the cost of use is high. To a certain extent, the harm to the environment has been increased
This application has the following disadvantages: (1) During the production process of the powder, it is easy to generate dust and cause environmental pollution; in the process of mixing with water, the powder is easily inhaled into the human body, posing a threat to human health, and the dosage is difficult to control
(2) The above application is simply grinding difenoconazole and mancozeb after mixing, which is equivalent to completing simple physical mixing, and its drug effect is equivalent to the superposition of two single doses, and it is impossible to achieve complex matching effect
However, the melting point of difenoconazole is 76°C. If the sanding parameters are not properly controlled, it is very easy to be higher than 76°C. In addition, the addition of surfactants and antifreeze agents will increase the plasticity and durability of difenoconazole during the grinding process. Lower its melting temperature, while the melting of difenoconazole leads to poor suspension effect on the one hand, and fails to achieve the compounding effect on the other hand

Method used

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  • Suspension compounded from difenoconazole and mancozeb and preparation method for suspension
  • Suspension compounded from difenoconazole and mancozeb and preparation method for suspension
  • Suspension compounded from difenoconazole and mancozeb and preparation method for suspension

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Step 1. Calculate the parts by weight required when using maneb wet material and zinc chloride as the starting raw materials, and then weigh the raw materials of the following parts by weight:

[0033] Difenoconazole: 10 parts

[0034] Maneb wet material (the weight content of Maneb is 50%, the same below): 40 parts

[0035] Sodium lignosulfonate: 2 parts

[0036] D. 500 : 1 part

[0037] Zinc chloride: 0.9 parts

[0038] Ethylene glycol: 5 parts

[0039] Sulfuric acid: 0.5 parts

[0040] Polyvinyl alcohol: 1 part

[0041] Water: 39.6 parts.

[0042] Step 2: Put water, maneb, zinc chloride, calcium lignosulfonate, carboxymethyl cellulose, phosphoric acid and difenoconazole into a high-speed disperser, and mix evenly to form a slurry.

[0043] Step 3. Grind the slurry in step 2 in a sand mill to a fineness of 2-3 μm, and control the grinding temperature at 40-60°C, and finally add 0.1 parts by weight of formaldehyde to obtain 30% difenoconazole Mancozeb suspensi...

Embodiment 2

[0076] Step 1. Calculate the parts by weight required when using maneb wet material and zinc chloride as the starting raw materials, and then weigh the raw materials of the following parts by weight:

[0077] Difenoconazole: 5 parts,

[0078] Maneb wet material: 10 parts,

[0079] Zinc chloride: 0.25 parts,

[0080] Calcium lignosulfonate: 20 parts,

[0081] Ethylene glycol: 5 parts,

[0082] Carboxymethylcellulose: 1 part,

[0083] Phosphoric acid: 0.1 parts,

[0084] Water: 58 parts.

[0085] Step 2: Put water, maneb, zinc chloride, calcium lignosulfonate, carboxymethyl cellulose, phosphoric acid and difenoconazole into a high-speed disperser, mix evenly, and form a slurry;

[0086] Step 3. Grind the slurry in step 2 in a sand mill to a fineness of 2-3 μm, and control the grinding temperature at 40-60° C., and finally add 0.1 parts by weight of sodium benzoate.

[0087] According to the method of Example 1, the medicament of the present embodiment is carried out t...

Embodiment 3

[0090] The difference with embodiment 1 is:

[0091] Difenoconazole: 20 parts

[0092] Maneb wet material: 40 parts

[0093] Zinc chloride: 1 part

[0094] Sulfuric acid: 0.5 parts

[0095] Xanthan gum: 2 parts

[0096] Ethylene glycol: 3 parts

[0097] Glycerol: 1 part

[0098] D. 425 :4 parts

[0099] Water: 28 parts

[0100] Sodium benzoate: 0.5 parts.

[0101] According to the method of Example 1, the medicament of the present embodiment is carried out the bacteriostasis test of apple ringworm, anthracnose, leaf spot, powdery mildew and scab. 5 times, the bacteriostasis rate is 100%, showing that the medicament of the present embodiment has very strong bacteriostasis.

[0102] Taking apple ringworm as an example, the field test was carried out according to the method in Example 1, and the results showed that: after the medicament of this example was diluted 5000 times, the average diseased fruit rate at the harvest period was 9.1%.

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Abstract

The invention discloses a suspension compounded from difenoconazole and mancozeb. Maneb, a dissoluble zinc salt and difenoconazole are taken as initial raw materials, and the maneb and the dissoluble zinc salt are complexed into a mixed preparation in a grinding process. The mixed preparation comprises the following components in percentage by weight: 5 to 40 percent of difenoconazole, 5 to 40 percent of mancozeb, 0.5 to 50 percent of dispersing wetting agent, 0.01 to 0.5 percent of preservative, 1 to 5 percent of antifreezing agent and the balance of water. According to the technical scheme, the maneb and the dissoluble zinc salt are taken as the initial raw materials, and are synthesized into complexed mancozeb in the grinding process, and the generated mancozeb and the difenoconazole are compounded into the suspension. According to a method, the step of drying the mancozeb is eliminated, so that production cost is saved; and moreover, complexing reaction belongs to endothermic reaction, and is favorable for controlling grinding temperature to be far lower than a melting point of the difenoconazole, so that the prepared suspension is high in quality.

Description

technical field [0001] The invention belongs to the technical field of pesticide compounding, and in particular relates to a suspending agent compounded with difenoconazole and mancozeb and a preparation method thereof. Background technique [0002] Difenoconazole is a broad-spectrum systemic fungicide with protective and therapeutic effects. It is mainly used for various crops such as anthracnose, leaf spot, powdery mildew, scab and wheat take-all. Triazole fungicide, melting point 76°C, solubility (20°C): water 3.3mg / L, easily soluble in organic solvents. Mancozeb is an organosulfur protective fungicide, which has a good control effect on tomato early blight, cucumber downy mildew, and apple ring spot. [0003] At present, the existing problem is that for the single agent of difenoconazole and mancozeb, the pathogens develop drug resistance during the use process, which affects the control effect, reduces the utilization rate of the drug, and the cost of use is high. To...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A01N47/14A01N43/653A01N25/04A01P3/00
Inventor 郑跃杰范子良
Owner 河北双吉化工有限公司