Preparation method of blue/purple long-distance triggered LED (Light Emitting Diode) white-light emitting illumination material

A technology for remote excitation and luminescent materials, applied in luminescent materials, energy-saving lighting, chemical instruments and methods, etc., can solve the problems of decreased luminous efficiency of phosphors, limited application range of phosphors, color drift of white LEDs, etc., and achieves long service life , reduced dosage, and non-toxic raw materials

Inactive Publication Date: 2013-07-10
SHANGHAI NORMAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the traditional packaging method has the following problems: the phosphor must be in direct contact with the chip, and the operating temperature of the chip often reaches 200°C, which will cause temperature quenching of the phosphor at high temperature, and the temperature quenching will cause the fluorescence The luminous efficiency of the powder decreases, which leads to the phenomenon of "color drift" during the use of white LEDs; the direct contact between the chip and the phosphor also limits the application range of the phosphor, such as some classic sulfide phosphors such as: CaS:Eu 2+ , SrS:Eu 2+ can't apply
However, the current packaging method for remote excitation is not perfect, and there are mainly problems such as high cost, large amount of phosphor powder, and inflexible packaging methods.

Method used

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  • Preparation method of blue/purple long-distance triggered LED (Light Emitting Diode) white-light emitting illumination material
  • Preparation method of blue/purple long-distance triggered LED (Light Emitting Diode) white-light emitting illumination material
  • Preparation method of blue/purple long-distance triggered LED (Light Emitting Diode) white-light emitting illumination material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Glass pretreatment: Soak a 10cm×10cm square glass piece in an aqueous solution with a washing powder content of 4g / L, and ultrasonically clean it for 30 minutes, take out the glass piece, wash it with deionized water for 2 minutes, and then put it in the oven medium, dry at 120°C for 15 minutes, and set aside;

[0029] Pour 6.0g of liquid polyurethane into a 50mL beaker, then add 2.0g of butyl acetate and 0.05mL of defoamer (the content of polydimethylsiloxane is 0.015mg), and finally add Sr 2.97 al 0.025 Si 0.975 o 5 : Ce 3+ 0.025 , Eu 2+ 0.005 Phosphor powder 2.0g, stir for 1 hour; drop-coat the stirred paste substance on the pretreated glass sheet, the coating thickness is 0.3-0.4mm; put the coated glass sheet in an oven to dry at 40°C The blue / purple light remote excitation LED white light lighting luminescent material can be obtained by drying under the same conditions for 12 hours. Figure 5 It is a comparison diagram of the fluorescence intensity between ...

Embodiment 2

[0031] The addition amount of liquid polyurethane in Example 1 was adjusted to 6.5g, the addition amount of butyl acetate was adjusted to 1.5g, and the others were kept unchanged, and the blue / violet light remote excitation LED white light lighting luminescent material was obtained.

Embodiment 3

[0033] The addition amount of liquid polyurethane in Example 1 was adjusted to 7.0 g, the addition amount of butyl acetate was adjusted to 1.0 g, and the others were kept unchanged to obtain a blue / purple light remote excitation LED white light lighting luminescent material.

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Abstract

The invention belongs to the technical field of light-emitting materials and in particular relates to a preparation method of a blue / purple long-distance triggered LED (Light Emitting Diode) white-light emitting illumination material. The preparation method comprises the following steps of: mixing liquid-state polyurethane, an organic solvent and a defoaming agent, then adding florescent powder and stirring for 0.2-2 hours; and coating stirred paste onto a pretreated transparent plate and drying the transparent plate, wherein the organic solvent is butyl acetate, the defoaming agent is an organic siloxane defoaming agent, the paste is coated on the transparent plate by adopting one or more of steps, such as spin coating, dropwise coating, brush coating and spray coating, and the thickness of the coating is 0.2-0.6mm. The fluorescent powder used in the process of preparing the light emitting material by using the preparation method is not in direct contact with a chip, thereby being long in service life; the color temperature of the florescent powder can be adjusted between 3000K and 8500K; and in addition, a packaging process is simple and flexible. According to the preparation method, the use amount of the florescent powder is low, the raw material is easily available and non-toxic, and no industrial three wastes are formed in the preparation process. The light emitting material is wide in application field.

Description

technical field [0001] The invention belongs to the technical field of luminescent materials, and in particular relates to a preparation method of blue / purple light remote excitation LED white light illumination luminescent materials. Background technique [0002] Compared with traditional lighting sources, white LEDs have many advantages, such as: small size, low energy consumption, fast response, long life, no pollution, etc., so they are called the fourth generation of lighting sources. At present, traditional commercialized LEDs are dot-coated with phosphor powder on LED chips to emit white light. However, the traditional packaging method has the following problems: the phosphor must be in direct contact with the chip, and the operating temperature of the chip often reaches 200°C, which will cause temperature quenching of the phosphor at high temperature, and the temperature quenching will cause the fluorescence The luminous efficiency of the powder decreases, which lea...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K11/80
CPCY02B20/00
Inventor 余锡宾刘翃刘浦俊尧志凌李晓晴罗宏德郑霄
Owner SHANGHAI NORMAL UNIVERSITY
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