Dyeing method adopting activated dye with high fixation rate

A technology of reactive dyes and dyeing methods, applied in the field of dyeing with high color fixation rate of reactive dyes, can solve the problems of light fastness decline, salt pollution, high equipment requirements, etc., achieve good process reproducibility, broad application prospects, reduce Effects of Environmental Pollution

Active Publication Date: 2013-09-04
DONGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Dyes with high directness and high fixation rate are not easy to be washed off after hydrolysis, which will affect the color fastness and uniformity of dyeing; dyeing under low-alkali or neutral conditions requires the development of new dyes or changes in the dyeing process, such as increasing temperature and Increase the electrolyte concentration; cold-batch dyeing technology can increase the utilization rate of dyestuff by 10% to 15%, but the control of the production process is strict, the controllability of shade is poor, and the residual sodium hydroxide can easily cause the fabric to feel hard and the tear strength to decrease a

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Put 5mL4g / L Reactive Brilliant Red KE-7B, 20mL ethanol and 2g cotton fabric in a 50mL ground mouth Erlenmeyer flask, raise the temperature to 60°C at 2°C / min and keep it warm for 30min, pour out the dyeing bath and use a rotary evaporator to evaporate the solvent. The liquid-carrying rate of the fabric is reduced to 100%, and 20mL of ethanol, 2g / L triethanolamine and 5g / L soda ash are added, the temperature is raised to 78°C at 1°C / min and kept for 60min, the fabric is taken out, washed with water, soaped and washed with water The dyed cotton fabric is obtained. The dye uptake rate can reach 96%, and the fixation rate is 84%.

Embodiment 2

[0028] Add 5mL8g / L active dark blue M-2GE, 20mL propylene glycol methyl ether and 2g cotton fabric to a 50mL ground-mouth Erlenmeyer flask, raise the temperature to 80°C at 3°C / min and keep it warm for 20min, distill out the water in the dyeing bath at 80°C under reduced pressure Parts, use gas chromatography to detect the water content in the solvent, and keep it at about 5%, add propylene glycol methyl ether to maintain the volume of the dye bath at 25mL, and add 4g / L triethylenediamine and 5g / L soda ash, at 1 ℃ / min Raise the temperature to 100°C and keep it warm for 30 minutes, take out the fabric, wash with water, soap and water to obtain the finished cotton fabric dyeing. The dye uptake rate is 90%, and the fixation rate is 82%.

Embodiment 3

[0030] Put 5mL of 6g / L reactive yellow H-E4R, 15mL of isopropanol and 2g of cotton fabric in a 50mL ground mouth Erlenmeyer flask, raise the temperature to 60°C at 2°C / min and keep it warm for 30min, pour out the dyeing bath and use a rotary evaporator to evaporate the solvent. The liquid carrying rate of the fabric is reduced to 80%, and 20mL isopropanol, 2g / L triethanolamine and 5g / L soda ash are added, the temperature is raised to 80°C at 1°C / min and kept for 60min, the fabric is taken out, washed with water, soaped and washed with water After that, the finished product of cotton fabric dyeing is obtained. The dye uptake rate can reach 97%, and the color fixation rate is 90%.

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PUM

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Abstract

The invention relates to a dyeing method adopting an activated dye with a high fixation rate. The dyeing method comprises the steps as follows: firstly, a water/organic solvent co-solvent system is adopted to enable the activated dye to dye cotton fabrics; after dyeing is completed, the water content on the fabrics is reduced through changing dye bath or evaporation; organic alkali and inorganic alkali are added for fixation for a certain period at a certain temperature; and after the fixation is completed, the fabrics are subjected to washing, soaping, washing and drying. The technical scheme adopted by the invention has a simple technology, convenience in operation and no special requirement for dye and equipment, large-scale production can be performed by conventional equipment, the solvent is easy to recycle, and salt-free and low-alkaline dyeing can be achieved; and meanwhile, hydrolysis of the dye on the fabrics can be reduced, so that the dye can be fixed on fibers, the environmental pollution and the production cost are reduced, and the dyeing method has wide application prospect.

Description

technical field [0001] The invention belongs to the field of reactive dye dyeing methods, in particular to a dyeing method with high color fixation rate of reactive dyes. Background technique [0002] Reactive dyes can be covalently bonded with cellulose fibers, which can endow fabrics with excellent wet fastness. In addition, their bright colors and complete chromatograms have become the most important type of dyes for cellulose fiber dyeing. Reactive dyes are generally fixed on cotton under alkaline conditions, and the hydroxide ion OH in the dyeing solution - It can also undergo a nucleophilic reaction with the dye to generate a hydrolyzed dye, thereby reducing the color fixation rate of the dye (the color fixation rate is generally only 50% to 80%). Hydrolyzed dyes cannot react with cotton and have little affinity for fibers. In order to obtain dyed products with high wet fastness, they must be washed out in the washing process. Washing requires a lot of water, resultin...

Claims

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Application Information

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IPC IPC(8): D06P1/92D06P1/38D06P1/655D06P1/673D06P3/66
Inventor 何瑾馨董霞周浩杭彩云
Owner DONGHUA UNIV
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