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Filling resin of electrolytic zinc negative plate stripping mouth and processing technology thereof

A technology of filling resin and cathode plate, applied in the field of electrolytic zinc cathode plate peeling port filling resin and its processing technology, can solve the problems of poor current impact resistance, high maintenance cost, poor corrosion resistance and bonding performance, etc., and achieve Good anti-stripping performance, low storage requirements, excellent acid corrosion resistance

Active Publication Date: 2013-10-02
云南曲靖润扬商贸有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since the insulating material of the peeling port is in the environment of strong acid corrosion and current impact at about 50°C for a long time, and there will be strong mechanical vibration during mechanical stripping, the insulating material is easily loosened or peeled off due to corrosion and vibration, or due to the hardness of the insulating material. Insufficient and difficult to use with mechanized zinc stripping equipment, and once the insulating material is filled and replaced, it will seriously affect the normal production and the maintenance cost is high, so the corrosion resistance, bonding performance, and current shock resistance of the insulating material at the stripping port High performance and mechanical performance requirements
In the prior art, conventional resin glue is generally used for filling, and the anti-current shock performance is poor. Generally, there will be a small amount of zinc deposition on the surface after about 2 months of use, which is not conducive to zinc stripping operation; and the corrosion resistance and adhesive performance are also poor. Poor. According to research, in the current wet electrolytic zinc smelting factories, the service life of the stripping port after filling resin bonding is generally only 3 to 4 months

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Get 30 parts by mass of bisphenol F type epoxy resin, 25 parts by mass of epoxy resin reactive diluent, 15 parts by mass of dioctyl phthalate toughening agent, 20 parts by mass of silicon carbide filler, 5 parts by mass of hydrolysis stabilizer and Pour 5 parts by mass of adhesion promoter into the stirring tank, then heat the stirring tank to 65°C, fully stir under heating conditions, pour out the material after stirring evenly and grind it with a liquid grinder until the particle size of the material is less than 15 microns Use a filling machine to fill it into the component A rubber barrel at a constant speed to obtain component A;

[0028] Take 60 parts by mass of polyamide 650 curing agent, 9.5 parts by mass of polysulfide rubber toughening agent, 30 parts by mass of mica and 0.5 parts by mass of resin color paste and pour them into the stirring tank, then heat the stirring tank to 65 ° C, under heating conditions Stir fully, pour out the material after stirring ev...

Embodiment 2

[0032] Get 60 parts by mass of bisphenol F type epoxy resin, 14 parts by mass of epoxy resin reactive diluent, 10 parts by mass of dioctyl phthalate toughening agent, 13 parts by mass of silicon carbide filler, 1 part by mass of hydrolysis stabilizer and Pour 2 parts by mass of adhesion promoter into the stirring tank, then heat the stirring tank to 65°C, fully stir under heating conditions, pour out the material after stirring evenly, and grind it with a liquid grinder until the particle size of the material is less than 15 microns Use a filling machine to fill it into the component A rubber barrel at a constant speed to obtain component A;

[0033] Take 80 parts by mass of polyamide 650 curing agent, 7 parts by mass of polysulfide rubber toughening agent, 12 parts by mass of mica and 1 part by mass of resin color paste into the stirring tank, then heat the stirring tank to 65 ° C, under heating conditions Stir fully, pour out the material after stirring evenly and grind it w...

Embodiment 3

[0037] Get 45 parts by mass of bisphenol F type epoxy resin, 22 parts by mass of epoxy resin reactive diluent, 12 parts by mass of dioctyl phthalate toughening agent, 15 parts by mass of silicon carbide filler, 3 parts by mass of hydrolysis stabilizer and Pour 3 parts by mass of adhesion promoter into the stirring tank, then heat the stirring tank to 65°C, fully stir under heating conditions, pour out the material after stirring evenly and grind it with a liquid grinder until the particle size of the material is less than 15 microns Use a filling machine to fill it into the component A rubber barrel at a constant speed to obtain component A;

[0038] Take 70 parts by mass of polyamide 650 curing agent, 10 parts by mass of polysulfide rubber toughening agent, 19.2 parts by mass of mica and 0.8 parts by mass of resin color paste and pour them into the stirring tank, then heat the stirring tank to 65 ° C, under heating conditions Stir fully, pour out the material after stirring e...

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PUM

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Abstract

The invention discloses a filling resin of an electrolytic zinc negative plate stripping mouth and a processing technology thereof. The filling resin is prepared by mixing component A and component B at a weight ratio of 2:1; the component A comprises bisphenol-F-epoxy resin, a epoxy resin diluent, a flexibilizer, silicon carbide filling material, a hydrolytic stabilizer and an adhesion promoter; and the component B comprises polyamide 650 curing agent, polysulfide rubber flexibilizer, mica and a color paste. Optimized selection and reasonable combination of raw materials with different performances, and a double-component mixing process are employed in the preparation of the filling resin, so that the filling resin is capable of solidifying quickly at room temperature, and possesses high bonding strength and peeling resistance after solidification, and also possesses excellent acid corrosion resistance, high temperature resistance, ageing resistance, and current shock resistance. The insulativity is high, cost is low, and storage requirements are few. The filling resin is easy to produce, is non-toxic, and is appropriate to be used as the filling resin of the electrolytic zinc negative plate stripping mouth.

Description

technical field [0001] The invention relates to the technical field of electrolytic equipment, in particular to a resin for filling the peeling opening of an electrolytic zinc cathode plate and a processing technology thereof. Background technique [0002] In the wet electrolytic zinc smelting process, since the liquid level of the electrolyte in the electrolytic cell will fluctuate, the upper opening of the zinc sheet forms an irregular wavy slope, and it is difficult for the zinc stripping knife to be inserted between the zinc sheet and the cathode plate. It is conducive to the stripping of zinc flakes, so in the field of modern electrolytic zinc, the stripping port is usually pre-processed on the cathode plate, and the insulating material is poured in the stripping port. There is no zinc deposition or the deposition amount is small, and the zinc stripping knife can easily strip the zinc sheet and the cathode plate from the stripping opening, which improves the work effici...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L63/02C08L81/04C08K3/34C08K5/12
Inventor 李洪祥
Owner 云南曲靖润扬商贸有限公司
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