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A comprehensive treatment method for oily sludge

An oil sludge and treatment method technology, applied in sludge treatment, water/sludge/sewage treatment, dehydration/drying/concentrated sludge treatment, etc. Incomplete and other problems, to achieve the effect of low operating costs and equipment investment, reducing equipment construction investment, and realizing resource utilization

Active Publication Date: 2015-10-28
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This technology does not carry out deep dehydration treatment on the oily sludge before extraction. During the process, there is too much water in the oily sludge, the extraction is not thorough, and the organic content in the separated solid phase is high, and the material needs to be heated during the extraction process. , requires multi-stage extraction, long process flow, many equipment, large equipment investment, and large energy consumption
[0007] CN101633574A and CN101362979A propose a treatment method for oily sludge, which involves conditioning and filtering the oily sludge and mixing it with coal as fuel, but fails to recycle the oil in the oily sludge
However, the raw materials currently used as oily sludge extraction solvents mainly include light coal tar, petroleum ether, naphtha, light oil, benzene, toluene, methyl ethyl ketone and other industrial products or wide boiling range combination solvents. Extraction effect, but the oil content of the solid residue after extraction is still high, which cannot reach the standard of general solid waste, and the extraction solvent will lose a lot during the process of process circulation, generally the loss can reach more than 6%. This affects the economic performance of oily sludge extraction technology and delays the popularization and application of this technology
At the same time, if the sludge is dried at high temperature, more energy consumption is required (if the water content of the oily sludge is reduced from 80% to 40%, 0.67 tons of water needs to be evaporated per ton of sludge), during the drying process A certain amount of exhaust gas also needs to be treated up to the standard

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Take 10 liters of oily sludge with a water content of 96.2% and an oil content of 2.2%. After being treated by a plate and frame filter press, the water content of the oily sludge is reduced to 84.1%, and the oil content is 8.3%. Then the oily sludge is mixed with Fine sand (particle size about 120μm) is mixed at a mass ratio of 1:0.1, stirred evenly, and then sent to an extruder. The extruding temperature is 25°C and the pressure is 26MPa. After extruding for 10 minutes, the water content of the resulting mud cake is 23.2%, and the oil content 59.0%, and then directly mix the mud cake with the mixed solvent (main agent 94% (v / v), auxiliary agent 3% (v / v), auxiliary agent 3% (v / v)) in a mass ratio of 1:8 , the mud cake can be crushed into small particles after slight stirring in the extractant, extracted for 30 minutes, and the extraction temperature is 30°C. After the extraction is completed, the solid-liquid mixture is sent to the centrifugal separator, and the separat...

Embodiment 2

[0045] Take 1 liter of oily sludge with a water content of 98.1% and an oil content of 1.1%, and pass it through a horizontal screw centrifugal dehydrator. After treatment, the water content is 81.3% and the oil content is 13.5%. Then mix the oily sludge and fine sand (particle size about 160μm) at a mass ratio of 1:0.25, stir evenly, and then enter the extruder at a temperature of 12°C, a pressure of 20MPa, and a processing time of 15 minutes. The resulting mud cake has a moisture content of 26.0%. , with an oil content of 51.9%, which is mixed with a mixed solvent (main agent 90% (v / v), auxiliary agent 8% (v / v), auxiliary agent 2% (v / v)) in a mass ratio of 1:10 Extract for 10 minutes at a temperature of 45°C. After the extraction is completed, the solid-liquid mixture is sent to a centrifugal separator, and the separated liquid phase is directly refined. After the separation process, the solvent loss rate is 1.4%, and the separated solid phase enters the slurry Leaf type dry...

Embodiment 3

[0049] Take 10 liters of oily sludge with a water content of 96.2% and an oil content of 2.2%. After being treated by a plate and frame filter press, the water content of the oily sludge is reduced to 84.1%, and the oil content is 8.3%. Then the oily sludge is mixed with Fine sand (particle size about 100μm) is mixed according to the mass ratio of 1:0.2, stirred evenly and then sent to the extruder. The extruding temperature is 25°C and the pressure is 25MPa. After extruding for 20 minutes, the water content of the mud cake is 20.2%, oily 59.5%, and then directly mix the mud cake with the mixed solvent (main agent 97% (v / v), auxiliary agent 3% (v / v), auxiliary agent 0% (v / v)) in a mass ratio of 1:25 , the mud cake can be crushed into small particles after slight stirring in the extractant, extracted for 30 minutes, and the extraction temperature is 40°C. After the extraction is completed, the solid-liquid mixture is sent to the centrifugal separator, and the separated liquid ph...

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Abstract

The invention relates to a treatment method of oily sludge, and is especially suitable for the oily sludge produced in a wastewater treating process of an oil refinery. The treatment method comprises the steps: firstly, carrying out mechanical dehydration, allows the water content of the oily sludge to be reduced to 50%-90%, then mixing with sand grains having a certain particle size, stirring evenly, then sending into a squeezing device for squeezing, mixing a mud cake generated after squeezing with an extracting agent, stirring evenly, extracting, after finishing extraction, sending the mixed material into a solid-liquid separator, directly recycling the separated-out liquid, and treating the dried separated solid residue as general solid waste. The treatment process has low energy consumption of the oil sludge treatment and fast extraction speed, can be combined with an oil refining device, has high waste oil recycling rate, and can realize resource utilization and harmless treatment of the oily sludge.

Description

technical field [0001] The invention relates to a treatment method of oily sludge, in particular to a treatment method in which the oily sludge produced by oil refineries and oil refinery sewage treatment plants is subjected to mechanical separation, pressing and dehydration, extraction and direct back-refining. Background technique [0002] Refining and chemical enterprises produce a large amount of oily sludge in the process of petroleum refining and wastewater treatment, which mainly come from grease traps, flotation tanks, excess activated sludge, crude oil dehydration tanks, oil storage tanks and waste oil tanks. These sludges are complex in composition and belong to a relatively stable multi-phase system with sufficient mixing and high viscosity. It is difficult for the solid phase to settle completely, and it is difficult to treat oily sludge. At present, in my country's petrochemical industry, an average of 800,000 tons of oily sludge is produced every year. With th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F11/12C02F11/00C10G1/04
Inventor 巫树锋刘发强赵保全刘光利李常青江岩梁宝锋杨岳王军贾媛媛何琳张媛
Owner PETROCHINA CO LTD