Method for preparing atomizing silver tin oxide electrical contactor material containing additives

A technology of electrical contact materials, silver tin oxide, applied in the direction of contacts, circuits, electric switches, etc., can solve the problems of long processing cycle, high production cost, easy agglomeration, etc., to increase the degree of densification, improve the bonding strength, The effect of improving wettability

Active Publication Date: 2014-04-02
桂林金格电工电子材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Additives in this process are smelted together with Ag and Sn and then atomized. Due to the small amount of additives and the fact that they are easy to agglomerate when oxidized, it is easy to cause the additives to not be evenly distributed in the matrix. Affects the modification of the obtained contact material, and the wettability of silver and tin oxide is not good enough
[0005] The chemical co-deposition method mainly refers to the preparation of AgSnO by co-deposition process. 2 The most representative contact material is to add a precipitant to the silver nitrate solution containing tin oxide powder. This method prepares AgSnO with more uniform structure and higher electrical properties. 2 However, processing the powder through chemical methods will cause serious pollution to the environment, and there are also disadvantages such as cumbersome process, high production cost, and long processing cycle.

Method used

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  • Method for preparing atomizing silver tin oxide electrical contactor material containing additives
  • Method for preparing atomizing silver tin oxide electrical contactor material containing additives
  • Method for preparing atomizing silver tin oxide electrical contactor material containing additives

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] 1) According to the preparation of 10kg of Ag-8SnO 2 -3In 2 o 3 -2CeO 2 Ratio of materials Calculate the amount of each raw material, weigh 10kg of pure silver ingot, 0.916kg of pure tin ingot, 0.65kg of indium nitrate, 0.51kg of cerium nitrate, and set aside;

[0029] 2) Take pure silver ingots and pure tin ingots and put them in an intermediate frequency melting furnace to melt into a uniform alloy melt, then atomize them through high-pressure water atomization equipment, dry the obtained powder slurry, and pass through a 200-mesh sieve to obtain silver Tin alloy powder;

[0030]3) Dissolve indium nitrate and cerium nitrate in 3L of water to form an aqueous solution, add 9.33kg of silver-tin alloy powder, and mix the resulting slurry with a low-speed mixer (2h, 30r / min) to obtain nitric acid Silver-tin alloy powder slurry with uniform distribution of indium and cerium nitrate;

[0031] 4) Dry the silver-tin alloy powder slurry evenly distributed indium nitrate an...

Embodiment 2

[0047] 1) First prepare 10kg of Ag-20SnO according to 2 -2La 2 o 3 Calculate the amount of each raw material according to the material ratio, weigh 10kg of pure silver ingot, 2.02kg of pure tin ingot, and 0.535kg of lanthanum nitrate hexahydrate for use;

[0048] 2) Take pure silver ingots and pure tin ingots and place them in an intermediate frequency melting furnace to melt them into a uniform alloy melt, and then atomize them through high-pressure water atomization equipment to obtain silver-tin alloy powder;

[0049] 3) Take lanthanum nitrate and dissolve it with 3L of water to make an aqueous solution, add 9.38kg of silver-tin alloy powder, and use a low-speed mixer to mix the obtained slurry (the time is 1h, and the number of revolutions is 30r / min) to obtain a uniform distribution of lanthanum nitrate silver tin alloy powder paste;

[0050] 4) Dry the silver-tin alloy powder slurry with uniform distribution of lanthanum nitrate at 100°C for 10 hours, crush it with a ...

Embodiment 3

[0054] 1) According to the preparation of 10kg of Ag-10SnO 2 -1.5WO 3 -1ZnO-1.5Mo 2 o 3 Ratio of materials to calculate the amount of each raw material, weigh 10kg of pure silver ingot, 0.916kg of pure tin ingot, 0.156kg of ammonium metatungstate, 0.55kg of zinc nitrate, 0.204kg of ammonium molybdate, and set aside;

[0055] 2) Take pure silver ingots and pure tin ingots and place them in an intermediate frequency melting furnace to melt them into a uniform alloy melt, and then atomize them through high-pressure water atomization equipment to obtain silver-tin alloy powder;

[0056] 3) Dissolve ammonium metatungstate, zinc nitrate, and ammonium molybdate in 2L of water to make an aqueous solution, add 9.39kg of silver-tin alloy powder, and mix the obtained slurry with a low-speed mixer (the time is 0.5h, and the number of revolutions is 20r / min), obtain the silver-tin alloy powder slurry with uniform distribution of ammonium metatungstate, zinc nitrate, and ammonium molybda...

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Abstract

The invention discloses a method for preparing atomizing silver tin oxide electrical contactor material containing additives. The method comprises the following steps: (1) calculating the dosages of needed pure silver ingots, pure tin ingots and salt compounds containing adding elements according to the compounding ratio of the silver tin oxide electrical contactor material needed to be prepared, and weighing for reverse; (2) atomizing the pure silver ingots and the pure tin ingots into silver tin alloy powder; (3) preparing the salt compounds containing the adding elements into aqueous solution or ethanol solution, adding the silver tin alloy powder, mixing materials to obtain silver tin alloy powder sizing agents in which the salt compounds containing the adding elements are distributed evenly; (4) drying and smashing the sizing agents to obtain the silver tin alloy powder in which the salt compounds containing the adding elements are distributed evenly; (5) performing the processes of pre-oxidizing, isostatic pressing, sintering and extruding for the obtained silver tin alloy powder. According to the method, the problem of additive aliquation caused by the traditional atomization and powder mixing technology is well solved, and the densifying degree, the processing performance, the yield and the electrical performance of the materials are improved.

Description

technical field [0001] The invention relates to the field of metal-based composite materials, in particular to a method for preparing an additive-containing atomized silver-tin oxide electrical contact material. Background technique [0002] From the perspective of environmental protection and human health, the universal silver cadmium oxide (AgCdO) contact material is gradually eliminated from the market. Silver tin oxide (AgSnO 2 ) is a new type of non-toxic electrical contact material that has developed rapidly in recent years, AgSnO 2 The contact material exhibits excellent wear resistance, welding resistance and arc erosion resistance, and has less material migration and uniform surface wear, making it the best substitute for AgCdO. But AgSnO 2 The contact resistance of the contact material is relatively large and the temperature rises, which seriously affects the electrical performance and limits the application of its material. [0003] Studies have shown that AgS...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C5/06C22C1/04C22C1/10H01H1/0237
Inventor 王振宇黄锡文叶凡张天锦冯朋飞陈光明
Owner 桂林金格电工电子材料科技有限公司
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