Surface active agent in steel wire pickling solution

A technology of surfactant and pickling solution, which is applied in the field of surfactant, can solve the problems of reducing the adhesion between bead wire and rubber, the unevenness of the surface of the steel wire, and affecting the service life of the bead wire, so as to save acid Washing time, thorough removal, high adhesion effect

Inactive Publication Date: 2014-05-14
JIANGSU XINGDA STEEL TYPE CORD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In the current conventional bead wire production technology, electrolytic pickling is usually used before electroless plating. Electrolytic pickling is likely to cause "hydrogen embrittlement" of bead wires with high carbon content, which affects the service life of bead wires. ; At the same time, the conventional pre-plating treatment method is also easy to cause uneven unevenness on the surface of the steel wire, which affects the quality of the subsequent coating and reduces the adhesion between the bead steel wire and the rubber.

Method used

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  • Surface active agent in steel wire pickling solution

Examples

Experimental program
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Effect test

Embodiment 1

[0014] Embodiment 1: A kind of surfactant used in steel wire pickling solution, which is composed of nonylphenol polyoxyethylene ether and sodium lauryl sulfate, after it is prepared with hydrochloric acid to form pickling solution, nonylphenol polyoxyethylene The mass percentages of vinyl ether, sodium lauryl sulfate and hydrochloric acid in the hydrochloric acid pickling solution are 0.006%, 0.01% and 4% respectively, and the tempered steel wire of 0.96 mm is treated with the above-mentioned pickling solution containing surfactant. Pickling for 4 seconds can increase the release speed and expansion area of ​​hydrochloric acid in the pickling solution, improve the utilization rate of hydrochloric acid in the pickling solution, increase the pickling speed by 6%, and improve production efficiency; Compared with pickling solution, after pickling with surfactant, the oxide skin on the surface of steel wire is more thoroughly removed, and the surface is more uniform. After electrol...

Embodiment 2

[0015] Embodiment two: a kind of surfactant that is used in steel wire pickling solution, is made of sodium dodecylbenzenesulfonate and sodium dodecyl sulfate, after it is formulated with hydrochloric acid to form pickling solution, dodecyl The mass percentages of sodium benzenesulfonate, sodium lauryl sulfate and hydrochloric acid in the hydrochloric acid pickling solution are 0.10%, 0.06% and 9% respectively. The pickling of the steel wire for 4 seconds can increase the release speed and expansion area of ​​hydrochloric acid in the pickling solution, improve the utilization rate of hydrochloric acid in the pickling solution, increase the pickling speed by 8%, and improve production efficiency; Compared with the pickling solution with surfactant, after pickling with surfactant, the oxide skin on the surface of steel wire is more thoroughly removed, and the surface is more uniform. After chemical plating, the adhesion between steel wire and rubber is greater than 1100N.

Embodiment 3

[0016] Embodiment 3: A kind of surfactant used in steel wire pickling solution, which is composed of nonylphenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether and sodium lauryl sulfate, which is prepared with hydrochloric acid to form pickling solution Finally, the mass percentages of nonylphenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, sodium lauryl sulfate and hydrochloric acid in the hydrochloric acid pickling solution are 0.16%, 0.17%, 0.45% and 9%, respectively, using the above The pickling solution containing surfactant pickles the 1.20mm tempered steel wire for 5 seconds, which can increase the release speed and expansion area of ​​hydrochloric acid in the pickling solution, improve the utilization rate of hydrochloric acid in the pickling solution, and increase the acidity. The washing speed is 12%, which improves the production efficiency; compared with the pickling solution without surfactant, the oxide skin on the steel wire surface is...

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Abstract

The invention discloses a surface active agent in steel wire pickling solution. The surface active agent comprises any or combination of two or more in alkylbenzene sulfonate, alkane sulfonate, alkyl glycoside, aliphatic alcohol phosphate, fatty alcohol-polyoxyethylene ether and alkylphenol polyoxyethylene, and the mass percent of the surface active agent is 0.01-2.5% in hydrochloric acid pickling solution. After being prepared into the pickling solution together with the hydrochloric acid, the surface active agent can be used for carrying out acid pickling on a steel wire; compared with the hydrochloric acid pickling solution which does not contain the surface active agent, the pickling solution containing the surface active agent obviously improves the pickling efficiency and saves the pickling time; after pickling, the oxide skin on the surface of the steel wire can be more thoroughly removed, and the surface of the steel wire is more uniform; after chemical planting, the bonding force between the steel wire and the rubber is higher.

Description

technical field [0001] The invention relates to a method for treating the surface of bead steel wire before plating, in particular to a surface that can quickly wet the oxide skin on the surface of the steel wire, increase the release speed and expansion area of ​​hydrochloric acid in the pickling solution, and thereby improve the utilization rate of hydrochloric acid in the pickling solution. active agent. Background technique [0002] In the pickling process of steel materials, the pickling solution first needs to soak the oxide skin on the surface of the steel wire, and then when the pickling solution further penetrates the oxide scale, the oxide scale and the pickling solution chemically react to achieve the effect of removing the oxide scale on the surface of the material. Purpose. In the existing pickling process of bead steel wire after tempering, the steel wire enters the pickling solution, and the pickling solution wets and penetrates the oxide scale on the steel w...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23G1/08
Inventor 刘祥姚利丽董小帅倪自飞邓伟王万林华欣
Owner JIANGSU XINGDA STEEL TYPE CORD
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