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Modified pyrophyllite for nylon corrugated pipe material and preparation method thereof

A bellows and nylon technology, which is applied in the field of modified pyrophyllite for nylon bellows materials and its preparation, can solve the problems of difficult interface formation and poor compatibility, and achieves improved mechanical strength and wear resistance, improved dispersibility, reduced Hydrophilic effect

Inactive Publication Date: 2014-10-29
HEFEI HEAN MACHINERY MFG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are hydrophilic groups on the surface of pyrophyllite, which are polar, while nylon materials are hydrophobic, so the compatibility between the two is poor, and it is difficult to form a good bond at the interface. Therefore, in order to improve the bond between pyrophyllite and nylon Compatibility, to enhance the interfacial combination of the two, it is necessary to modify the pyrophyllite

Method used

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Embodiment Construction

[0010] A modified pyrophyllite for nylon corrugated pipe material, made of the following raw materials by weight (kg): 90 pyrophyllite, 20 tuff, 16 ball soil, 4 waste animal and vegetable oils, bis(γ-triethoxysilylpropyl ) tetrasulfide 2.5, cobalt neodecanoate 2, lechner gum 15, N,N-dimethyl-p-toluidine 3, 1,4-butane sultone 8, ethylene bisstearamide 4, octane Sucrose acetate 11, cellulose acetate butyrate 8, polyhydroxybutyrate 50, chloroether resin 25, polyvinyl butyral 18, acetyl tributyl citrate 12, tetrakis (3-mercaptopropionate) pentaerythritol ester 2.5. Auxiliary 6;

[0011] The preparation method of described auxiliary agent is as follows: a, get the raw material of following weight (kg): tri-tert-butylphosphine tetrafluoroborate 4, aluminum triacetylacetonate 3, stearyl methacrylate 6, hexamethylenetetramine 3.5, magnesite 8, dicyclopentadiene 7, zinc p-toluene sulfinate 2, waste glass powder 12, bamboo charcoal powder 8, mannide monooleate 2.5, tetramethyltetraviny...

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Abstract

The invention discloses modified pyrophyllite for a nylon corrugated pipe material and a preparation method thereof. The modified pyrophyllite is prepared from the following raw materials in parts by weight: 80-100 parts of pyrophyllite, 15-25 parts of tuff, 12-18 parts of ball clay, 3-6 parts of waste animal and vegetable oils and fats, 2-3 parts of bis-(gamma-triethoxysilylpropyl)tetrasulfide, 1.5-2.5 parts of cobalt neodecanoate, 10-15 parts of polyisocyanate adhesive, 3-4 parts of N,N-dimethyl-p-toluidine, 6-12 parts of 1,4-butane sultone, 3-5 parts of ethylene bisstearamide, 7-13 parts of sucroseocta-acetate, 5-10 parts of cellulose acetate butyrate, 40-60 parts of polyhydroxybutyrate, 20-30 parts of vinyl chloride-vinyl isobutyl ether copolymer resin, 16-22 parts of polyvinyl butyral, 10-15 parts of acetyl tributyl citrate, 2-3 parts of pentaerythritol tetra(3-mercaptopropionate), and 4-7 parts of an auxiliary agent. Pyrophyllite is subjected to a certain modification treatment, the surface hydrophilicity is reduced, the compatibility and the chemical affinity with a nylon material are improved, the dispersion in a nylon base material is improved, comprehensive performance of a nylon composite material is improved, and the mechanical strength and wear resistance of the nylon composite material are improved significantly.

Description

technical field [0001] The invention relates to a modified pyrophyllite for nylon bellows material and a preparation method thereof, belonging to the technical field of inorganic fillers. Background technique [0002] Pyrophyllite is a mineral with layered silicate structure, the main chemical components are SiO2 and Al2O3. Pyrophyllite powder has the characteristics of heat resistance, corrosion resistance, insulation, low hardness, low refractive index, flaky particles, etc. It is one of the commonly used inorganic mineral fillers for nylon materials. However, there are hydrophilic groups on the surface of pyrophyllite, which are polar, while nylon materials are hydrophobic, so the compatibility between the two is poor, and it is difficult to form a good bond at the interface. Therefore, in order to improve the bond between pyrophyllite and nylon Compatibility, to enhance the interfacial combination of the two, the pyrophyllite must be modified. Contents of the inventio...

Claims

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Application Information

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IPC IPC(8): C08L77/00C08K9/06C08K9/04C08K9/02C08K3/34C09C1/40C09C3/12C09C3/08C09C3/10C09C3/06
CPCC08L67/04C08L77/00C08L2203/18C08L2205/035C09C1/405C09C3/006C09C3/04C09C3/08C09C3/12
Inventor 杨月琴杨晓伟郑海波武子静万丽丽沈先明牛保余海飞杨辉
Owner HEFEI HEAN MACHINERY MFG
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