Composite pure waterborne hard-to-be-adhered material adhesive for packaging paper commodities and preparation method thereof
A pure water-based technology for packaging, applied in the direction of grafted polymer adhesives, adhesives, adhesive types, etc., can solve the problems that the surface tension cannot be reached, disappears, and endangers the health of the staff, and achieves good The effect of the bonding effect
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[0056] Example 1: Long-chain methacrylates are methyl methacrylate, butyl methacrylate, 2-ethylhexyl methacrylate according to methyl methacrylate: butyl methacrylate: 2-methacrylate Ethylhexyl ester = a mixed long-chain methacrylate prepared by mixing with a mass mixing ratio of 2:3:5; the hydroxyl-containing reactive monomer is pentaerythritol triacrylate; the double-bond-containing double-end ester is methoxy poly Ether methacrylate; functional monomer is pentaerythritol tetraacrylate; water-soluble modified rosin resin is water-soluble fumaric acid-modified rosin resin; special monomer for copolymerizable self-crosslinking emulsion is ethyl methacrylate acetoacetate Glycol diester; chain transfer agent is 2,4-diphenyl-4-methyl-1-pentene; reactive emulsifier is allyloxypropyl alkyl alcohol polyether and allyloxynonyl Phenoxypropanol polyoxyethylene ether ammonium sulfate is obtained by mixing allyloxypropyl alkyl alcohol polyether: allyloxynonylphenoxypropanol polyoxyethylen...
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[0082] Example 2: Long-chain methacrylates are methyl methacrylate, butyl methacrylate, 2-ethylhexyl methacrylate according to methyl methacrylate: butyl methacrylate: 2-methacrylate Ethylhexyl ester = a mixed long-chain methacrylate prepared by mixing with a mass mixing ratio of 3:4:3; the hydroxyl-containing reactive monomer is trimethylolpropane diacrylate; the double-bond-containing double-end ester is Methoxy polyether methacrylate; functional monomer is lauryl alcohol acrylate; water-soluble modified rosin resin is water-soluble fumaric acid modified rosin resin; special monomer for copolymerizable self-crosslinking emulsion is methyl Acrylic acid acetoacetate glycol diester; chain transfer agent is 2,4-diphenyl-4-methyl-1-pentene; reactive emulsifier is allyloxypropyl alkyl alcohol polyether and allyl Oxynonylphenol propanol polyoxyethylene (4) ether ammonium sulfate according to allyloxypropyl alkyl alcohol polyether: allyloxynonylphenol propanol polyoxyethylene (4) eth...
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