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Preparation method of light-resistant and waterproof water-based flame-retardant polyurethane coating and adhesive

A polyurethane coating and waterproof technology, applied in the direction of polyurea/polyurethane coatings, polyurea/polyurethane adhesives, adhesives, etc., can solve problems such as large toxic side effects and carcinogenicity, reduce toxicity problems, and improve leveling. , the effect of high efficiency

Inactive Publication Date: 2016-05-11
慧融高科新型材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The light resistance of polyurethane is often improved by adding ultraviolet absorbers and antioxidants, but the traditional synthetic antioxidants include tert-butyl hydroxyanisole, tert-butyl hydroperoxide, tert-butyl hydroquinone, etc., which have greater Toxic side effects and carcinogenicity, so it is necessary to find efficient, environmentally friendly and light-resistant technologies

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0024] (1) Preparation of fullerene catalyst: Weigh 40mg of fullerene into a 250ml three-necked flask, add 20g of triethanolamine and 12g of ethanol, stir and react in an oil bath at 70°C under nitrogen protection for 8h, evaporate excess triethanolamine and Ethanol, the resulting brown sticky substance was dissolved by shaking with 10ml of distilled water, and then 50ml of acetone was added, a large amount of brown flocculent precipitates were precipitated, centrifuged, the precipitate was washed twice with acetone, and dried in vacuo to obtain 140mg of brown powder fullerene triethanolamine Derivatives; the above 140mg fullerene triethanolamine derivatives were dissolved in 20ml distilled water, poured into 30ml aqueous solution containing 200mg 4-amino-2,6-dibromophenol tin chloride hydrochloride, heated to 90°C, A tan precipitate was produced, and after being kept warm for 30 minutes, it was centrifuged while it was hot, and the solid was washed 4 times with distilled water...

example 2

[0029] (1) Preparation of fullerene catalyst: Weigh 40mg of fullerene into a 250ml three-necked flask, add 20g of triethanolamine and 12g of ethanol, stir and react in an oil bath at 70°C under nitrogen protection for 8h, evaporate excess triethanolamine and Ethanol, the resulting brown sticky matter was dissolved by shaking with 10ml of distilled water, and then 50ml of acetone was added, a large amount of brown flocculent precipitates were precipitated, centrifuged, the precipitate was washed twice with acetone, and vacuum-dried to obtain 140mg of brown powder fullerene triethanolamine Derivatives: Dissolve the above-mentioned 140mg fullerene triethanolamine derivative in 20ml distilled water, pour into 30ml aqueous solution in which 200mg of 4-amino-2,6-dibromophenol tin chloride hydrochloride is dissolved, heat to 90°C, There is a tan precipitate, after keeping warm for 30 minutes, centrifuge while it is hot, wash the solid matter with distilled water 4 times, and dry it in...

example 3

[0034] (1) Preparation of fullerene catalyst: Weigh 40mg of fullerene into a 250ml three-necked flask, add 20g of triethanolamine and 12g of ethanol, stir and react in an oil bath at 70°C under nitrogen protection for 8h, evaporate excess triethanolamine and Ethanol, the resulting brown sticky substance was dissolved by shaking with 10ml of distilled water, and then 50ml of acetone was added, a large amount of brown flocculent precipitates were precipitated, centrifuged, the precipitate was washed twice with acetone, and dried in vacuo to obtain 140mg of brown powder fullerene triethanolamine Derivatives: Dissolve the above-mentioned 140mg fullerene triethanolamine derivative in 20ml distilled water, pour into 30ml aqueous solution in which 200mg of 4-amino-2,6-dibromophenol tin chloride hydrochloride is dissolved, heat to 90°C, A tan precipitate is produced, after being kept warm for 30 minutes, centrifuged while hot, the solid is washed 4 times with distilled water, and dried...

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Abstract

The invention discloses a preparation method of a light-resistant and water-resistant water-based flame-retardant polyurethane coating and an adhesive. Under the condition that the prepared fullerene catalyst exists, polytetrahydrofuran ether diol and isophorone diisocyanate are mixed at 60 React at ~85°C for 1~2h, add coumarin and bromopropanine, react for 3h, and react at 70°C to obtain polyurethane prepolymer A; add chain extender, methyl ethyl ketone and nucleus to polyurethane prepolymer A Sodium flavin phosphate, react at 60~85℃ for 2.5~3.5h, add flame retardant, reaction temperature 75~85℃, reaction time 1~2h, add 1,4-dihydroxyanthraquinone, polyacrylamide and tackifier, the reaction temperature is 75°C, the reaction time is 1~2h, then triethylamine is added for neutralization reaction for 30~50min, and water is added for emulsification for 30min to obtain light-resistant and waterproof water-based flame-retardant polyurethane coating and adhesive. It has the triple performance of flame retardant, light resistance and waterproof, and polyurethane is environmentally friendly and low in price. It is widely used on the surface of walls, furniture and metal appliances, as an adhesive for plastics, glass, paper, textiles and leather.

Description

[0001] Technical Field The present invention relates to a preparation method of flame-retardant coatings and adhesives, in particular to a preparation method of light-resistant and waterproof water-based flame-retardant polyurethane coatings and adhesives. Background technique [0002] Polyurethane is mainly used in leather finishing, textile printing and dyeing, papermaking, architectural coatings, adhesives, etc. The coatings and paints sprayed on the surface of internal and external walls, furniture, and metal appliances are in direct or indirect contact with humans all the time. , Harmful coatings have also threatened people's health at all times. Because the field of use is often exposed to sunlight, because the sun’s rays contain a large amount of ultraviolet light harmful to colored objects, its wavelength is about 290-460nm, these harmful ultraviolet light changes the color of the paint through chemical oxidation and reduction. [0003] The main application fields of w...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D175/08C09D7/12C09J175/08C09J11/06C09J11/08C08G18/73C08G18/66C08G18/48C08G18/16C08G18/10B01J31/26
Inventor 段小宁罗声王亚茜宋丽夏雪影
Owner 慧融高科新型材料科技有限公司