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Highly-conductive and high temperature resistant polymer

A high temperature resistant polymer, high conductivity technology, applied in the field of polymer and its preparation, can solve the problems of dust pollution, low dosage, difficult to evenly disperse, etc., to prevent electrostatic discharge, suppress electromagnetic interference, lubricate high efficiency Effect

Inactive Publication Date: 2015-04-15
QINGDAO LANNONGGU AGRI PROD RES & DEV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it is found in production that when such additives are directly added to the resin for use, its extremely low dosage is difficult to disperse evenly, especially when it is blended with pellets, this problem is particularly prominent, and there are still problems in production dust pollution problem

Method used

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  • Highly-conductive and high temperature resistant polymer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] (1) Mix 20 parts of commercially available tetrafluoroethylene and vinylidene fluoride with a weight-average molecular weight of 500,000 to 5 million, and 15 parts of pentaerythritol distearate with a high-speed mixer at a speed of 1000 rpm. The airtight mixing time is For 10 minutes, the temperature is controlled at 70°C, and then a single-screw or twin-screw extruder is used to obtain the required bonding material after drying;

[0020] (2) Mix the bonding material mixed in step 1 with 15 parts of resole phenolic resin IDP, 15 parts of PA46 and PA6T / 6I polyamide resin, and 5 parts of heat stabilizer CuI / KI (1:8), and add the Toluenesulfonic acid 20 parts; cured at room temperature for 7 days in an open polyethylene mold. Extrusion granulation at room temperature, vibrating sieve to produce high-conductivity and high-temperature-resistant polymers.

Embodiment 2

[0022] (1) Mix 25 parts of commercially available tetrafluoroethylene and vinylidene fluoride with a weight-average molecular weight of 500,000 to 5 million and 15 parts of pentaerythritol distearate with a high-speed mixer at a speed of 1000 rpm, and the airtight mixing time is For 15 minutes, the temperature is controlled at 75°C, and then a single-screw or twin-screw extruder is used to obtain the required bonding material after drying;

[0023] (2) Mix the bonding material mixed in step 1 with 10 parts of resole phenolic resin IDP, 15 parts of PA46 and PA6T / 6I polyamide resin, and 5 parts of heat stabilizer CuI / KI (1:8), and add the Toluenesulfonic acid 20 parts; cured at room temperature for 8 days in an open polyethylene mold. Extrusion granulation at room temperature, vibrating sieve to produce high-conductivity and high-temperature-resistant polymers.

[0024] The high-conductivity and high-temperature-resistant polymer described in the present invention is a white pr...

Embodiment 3

[0026] Example 3 Graphite was weighed into a plastic cup followed by the addition of solvated resole. The graphite and the solvated resole were premixed for 1 minute prior to the addition of the acid. After adding the acid, the pasty mixture was mixed for 30 seconds, then transferred to a 2 cm x 2 cm x 1 cm plastic mold and pressed manually. After 24 hours, the resistivity of the cured molded sample polymer was measured with the multimeter used in Example 1. The results obtained are shown in Table 1.

[0027] Example number Solvated Resole Resin acid weight Weight of Graphite (Based on Resole) acid weight Resistivity 1 10g 1g 0 10 20*10 4 2 10g 2g 0 40 10000 3 10g 4g 15g 100 1.5

[0028] The high-conductivity and high-temperature-resistant polymers produced in Embodiment 1 and Embodiment 2 of the present invention are used to replace fluorine-containing polymers (PPA 2800) at an equivalent dosage of 800 ppm, and are applied...

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Abstract

The invention relates to a highly-conductive and high temperature resistant polymer. The polymer is characterized by being composed of the following components in parts by weight: 15 to 25 parts of polyamide resin, 10 to 15 parts of resole phenol-formaldehyde resin EPR, 20 to 30 parts of p-toluenesulfonic acid, 25 to 30 parts of fluorine-containing polymer, 10 to 15 parts of active polyol stearate, and 5 to 10 parts of a thermal stabilizer with a CuI / KI ratio of 1:8. The resole phenol-formaldehyde resin EPR is added, and thus the polymer can be used as an electrode or an electrode shielding material. The polymer can inhibit electromagnetic interference and prevent electrostatic discharge in a position, and is a carrier-free polymer with advantages of wide universality, good heatproof performance, and excellent conductive property.

Description

technical field [0001] The invention relates to a polymer and a preparation method thereof, in particular to a high-conductivity high-temperature-resistant polymer. Background technique [0002] The sources of polymers are divided into natural polymers (such as cellulose, starch, etc.), synthetic polymers (such as chlorinated phosphazene rubber, various vinyl polymers, etc.) and semi-synthetic polymers (such as cellulose acetate, etc.). According to the name of the synthesis reaction, it is divided into addition polymer (ie, addition polymer), condensation polymer (ie, condensation polymer) and ring-opening polymer. According to the application function of the polymer, it is divided into general polymer, special polymer, functional polymer, bionic polymer and medical polymer. [0003] In order to obtain low production costs, it is desirable to extrude polymers at high rates. Higher extrusion rates can easily be obtained by increasing the extruder screw speed. However, thi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/18C08L27/16C08L77/06C08L61/10C08K13/02C08K5/42C08K5/103C08K3/16
CPCC08L27/18C08K2201/014C08L23/0815C08L27/16C08L2201/08C08L2203/16C08L2205/025C08L2205/03C08L2205/035C08L2207/066
Inventor 宋波
Owner QINGDAO LANNONGGU AGRI PROD RES & DEV
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