Processing method of tinpot oil
A low-quality heavy oil and treatment method technology, which is applied in the treatment of hydrocarbon oil, hydroprocessing technology, petroleum industry, etc., can solve the problems of poor quality of solid petroleum coke, reduced dry gas production, environmental pollution, etc., and can improve the conversion rate of residual oil , simple process flow and low equipment investment
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Examples
Embodiment 1~4
[0036] This example investigates the hydrotreating reaction of residual oil when an oil-soluble molybdenum-nickel bimetallic catalyst is used under different operating conditions such as pressure, temperature, space velocity, and hydrogen-to-oil ratio. The test raw materials are Liaohe normal slag, Gudao normal slag, light sand normal slag and sand reduced slag. The properties of raw materials are shown in Table 1. It can be seen from Table 1 that the properties of slag reduction in sand are the worst, with high sulfur content and metal content, asphaltene content of 8.4m%, residual carbon exceeding 20m%, and high nitrogen content, which is a kind of inferior slag that is difficult to handle. Liaohe slag is a low-sulfur low-quality residue; Gudao slag and light sand slag have high sulfur content and poor raw material properties. During the test, the oil-soluble catalyst solution was first added to the residual oil to make it evenly stirred, and then the mixture was subjected t...
Embodiment 5~8
[0043] In this embodiment, the tail oil obtained after hydrotreating the residual oil is subjected to cyclone separation. Table 3 shows the properties of the tail oil obtained after the fractional distillation of the hydrogenation products in Examples 1-4. The data in the table shows that after hydrogenation of residual oil, the residual carbon value of the tail oil decreases, and the hydrogen-carbon ratio decreases. Table 4 shows the properties of the deslagging tail oil after cyclone separation. During the test, more than 95m% of unconverted tail oil can be used as coking feed.
[0044] Table 3 Properties of hydrogenated tail oil
[0045] raw material
[0046] Table 4 The properties of deslagging tail oil after cyclone separation
[0047] Numbering
[0048] The data in Table 4 shows that the density, viscosity, carbon residue and ash content of the deslagging tail oil after cyclone separation are all reduced, and the sulfur and nitrogen content are al...
Embodiment 9~12
[0050] Embodiments 9 to 12 use the hydrogenation products obtained in Examples 5 to 8 as the feedstock for the coking reaction, and carry out the coking test on a small device. The reaction conditions and reaction results are listed in Table 5, and the properties of the coke product are listed in Table 5. Table 6.
[0051] Table 5 coking reaction conditions and results
[0052] Numbering
9
10
11
12
raw material
Deslagging tail oil 5
Deslagging tail oil 6
Deslagging tail oil 7
Deslagging tail oil 8
Coking reaction conditions
Coke tower inlet temperature ℃
495
493
500
504
Coke tower outlet temperature ℃
420
418
425
420
Heating furnace outlet temperature ℃
500
505
510
510
0.8
0.9
0.7
0.8
Processing capacitykg / h
4.0
4.0
4.5
4.0
Water injection m%
6.0 ...
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