Processing method of tinpot oil

A low-quality heavy oil and treatment method technology, which is applied in the treatment of hydrocarbon oil, hydroprocessing technology, petroleum industry, etc., can solve the problems of poor quality of solid petroleum coke, reduced dry gas production, environmental pollution, etc., and can improve the conversion rate of residual oil , simple process flow and low equipment investment

Active Publication Date: 2015-05-27
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although this process increases the conversion rate of light oil, it does not fundamentally solve the problem of reducing the coke production of the unit and reducing the dry gas output
[0007] In addition, when the suspension bed hydrocracking and coking process are combined, due to the high impurity content in the inferior raw material, the value suspension bed catalyst cannot be separated and enters the coking raw material, so that the solid petroleum coke obtained in the coking process is of poor quality and difficult to use and handle
[0008] Hydroprocessing of inferior heavy oil can increase the yield of liquid products, but the quality of the generated tail oil is poor and difficu

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~4

[0036] This example investigates the hydrotreating reaction of residual oil when an oil-soluble molybdenum-nickel bimetallic catalyst is used under different operating conditions such as pressure, temperature, space velocity, and hydrogen-to-oil ratio. The test raw materials are Liaohe normal slag, Gudao normal slag, light sand normal slag and sand reduced slag. The properties of raw materials are shown in Table 1. It can be seen from Table 1 that the properties of slag reduction in sand are the worst, with high sulfur content and metal content, asphaltene content of 8.4m%, residual carbon exceeding 20m%, and high nitrogen content, which is a kind of inferior slag that is difficult to handle. Liaohe slag is a low-sulfur low-quality residue; Gudao slag and light sand slag have high sulfur content and poor raw material properties. During the test, the oil-soluble catalyst solution was first added to the residual oil to make it evenly stirred, and then the mixture was subjected t...

Embodiment 5~8

[0043] In this embodiment, the tail oil obtained after hydrotreating the residual oil is subjected to cyclone separation. Table 3 shows the properties of the tail oil obtained after the fractional distillation of the hydrogenation products in Examples 1-4. The data in the table shows that after hydrogenation of residual oil, the residual carbon value of the tail oil decreases, and the hydrogen-carbon ratio decreases. Table 4 shows the properties of the deslagging tail oil after cyclone separation. During the test, more than 95m% of unconverted tail oil can be used as coking feed.

[0044] Table 3 Properties of hydrogenated tail oil

[0045] raw material

[0046] Table 4 The properties of deslagging tail oil after cyclone separation

[0047] Numbering

[0048] The data in Table 4 shows that the density, viscosity, carbon residue and ash content of the deslagging tail oil after cyclone separation are all reduced, and the sulfur and nitrogen content are al...

Embodiment 9~12

[0050] Embodiments 9 to 12 use the hydrogenation products obtained in Examples 5 to 8 as the feedstock for the coking reaction, and carry out the coking test on a small device. The reaction conditions and reaction results are listed in Table 5, and the properties of the coke product are listed in Table 5. Table 6.

[0051] Table 5 coking reaction conditions and results

[0052] Numbering

9

10

11

12

raw material

Deslagging tail oil 5

Deslagging tail oil 6

Deslagging tail oil 7

Deslagging tail oil 8

Coking reaction conditions

Coke tower inlet temperature ℃

495

493

500

504

Coke tower outlet temperature ℃

420

418

425

420

Heating furnace outlet temperature ℃

500

505

510

510

Coke tower top pressure MPa

0.8

0.9

0.7

0.8

Processing capacitykg / h

4.0

4.0

4.5

4.0

Water injection m%

6.0 ...

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PUM

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Abstract

The invention relates to a processing method of tinpot oil, comprising the following steps: a, an oil-soluble catalyst and a heavy oil raw material are uniformly mixed and the mixture is then sent into a hydrogenation reactor to carry out a hydrogenation reaction under the existence condition of hydrogen; b, a liquid product obtained from the hydrogenation reaction enters a distiller to be cut into light oil and tail oil; c, the tail oil from the step b undergoes general hydrocyclone separation to obtain slag-removed tail oil and tailings; d, the slag-removed tail oil from the step c is sent into a delayed coker to undergo thermal cracking so as to obtain light distillate oil, dry gas and coke; and e, the tail oil from the step c is roasted and metal in the oil-soluble catalyst is recovered. By the above method, residual oil conversion rate is raised; green coke during the process is avoided; the problem that it is difficult to hydrotreat tail oil and metal in the catalyst cannot be recovered is solved; and the problem that coke obtained by coking of a high-sulfur raw material cannot be used is solved. Light distillate oil yield is raised by 10%. The technology is simple; the method is convenient to operate; investment is low; and the method is environmentally friendly.

Description

technical field [0001] The invention relates to a treatment method for processing low-quality heavy oil, which includes a combined process of hydrogenation treatment-tail oil coking-tail residue roasting. Background technique [0002] Crude oil resources are increasingly scarce in the world, and the quality of crude oil is becoming heavier and worse, while the demand for petroleum products is increasing, which requires the full and effective use of limited crude oil resources. Among them, the effective utilization of inferior heavy oil is the key to make full use of crude oil. In addition to the production of a small amount of asphalt in the utilization of inferior heavy oil, most of it needs to be lightened to produce light distillate products. At present, the main technologies for lightening heavy oil in the existing technology include decarburization and hydrogenation. The decarburization process is greatly affected by the properties of the raw oil, especially when the ...

Claims

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Application Information

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IPC IPC(8): C10G67/14
CPCC10G67/14C10G2300/201
Inventor 付兴国蔺爱国赵广辉高飞张艳梅薛鹏侯经纬刘银东于志敏张璐瑶崔岩
Owner PETROCHINA CO LTD
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