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Method for preparing transparent soap by irradiating waste oil

A technology of waste oil and transparent soap, which is applied in the direction of soap recovery, alkali soap/ammonium soap composition, soap detergent and other compounding agents, can solve the problems of few research reports, cumbersome steps and high cost, and achieves high transparency, Simple process and low cost effect

Inactive Publication Date: 2017-11-03
YULIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although saponification is the core process of preparing soap and other detergents, if you want to use gutter oil to obtain qualified products, you need to pretreat the gutter oil, such as deodorization, disinfection and sterilization, and at the same time, if you want to make transparent soap with beautiful color and luster Also need to carry out decolouring treatment to waste oil, yet the research report of this respect is seldom, the problem to be solved urgently in existing research has: one, how to decolorize waste oil pretreatment stage, deodorize, eliminate wherein a large amount of poisonous viruses such as germs etc. Harmful microorganisms; 2. How to make transparent soap from gutter oil
[0004] At present, some scholars are committed to solving the above problems, such as using oily feet instead of part of the oil to produce transparent soaps, which improves the utilization of oily feet, reduces the production cost of transparent soaps, and improves the performance of transparent soaps. Ma Yongmei, Sichuan Chemical Industry and Corrosion Control, 2002, May, 5; A transparent soap was developed by saponification reaction using edible corn oil, palm kernel oil, and castor oil as the main raw materials, supplemented with stearic acid, Liu Xiaoling, Applied Chemical Industry, 2010, 39, 12; There is also the use of cattle and sheep crude oil, which is first pretreated (alkali refining, decolorization and filtration, etc.), and then saponified to produce transparent soap, but the cost of this method is relatively high, and the steps in the pretreatment stage are too cumbersome, and the final product Transparent soap is translucent, Yu Zhanfeng, Liu Yali, Deng Jianru, Daily Chemical Industry, 2004.34, 6

Method used

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  • Method for preparing transparent soap by irradiating waste oil
  • Method for preparing transparent soap by irradiating waste oil
  • Method for preparing transparent soap by irradiating waste oil

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] (1) Sampling of waste oil:

[0028] The gutter oil is collected from the dining waste in the student canteen, and is centrifuged to remove impurities.

[0029] (2) Irradiation treatment:

[0030] Use a measuring cylinder to accurately measure 100mL of the waste oil after removing impurities and put it in a polyvinyl chloride bottle and seal it. 60 Co γ-ray irradiation for 10min.

[0031] The olfactory odor of waste oil was determined by a precision electronic nose. Sampling is directly taken from the sample bottle, and the headspace sampling method is directly analyzed by the electronic nose under natural conditions at room temperature.

[0032] Table 1 Performance comparison of waste oil before and after irradiation

[0033]

[0034] Because gutter oil is rich in fat components, there are both animal oils (lard, tallow, sheep oil, etc.) and vegetable oils (soybean oil, corn oil, sesame oil, etc.), which provide a rich material basis for the preparation of transp...

Embodiment 2

[0050] The extraction of waste oil is the same as embodiment 1, and the waste oil after processing is placed in plastic bottle and sealed, then at room temperature in the radiation dose is 3KGy 60 Irradiate 8min under Co gamma ray; Add the existing 1mol / L sodium hydroxide ethanol solution saponification 15min with the operation method of embodiment 1 to obtain soap paste, wherein the mass ratio of sodium hydroxide ethanol solution and waste oil is 1:6; In gained soap paste, add the waste soap that the ethanol of soap paste quality 5wt%, the sucrose of soap paste quality 10wt%, the distilled water of soap paste quality 15wt% and the pulverization of soap paste quality 15wt% are fully stirred at 55 ℃ until completely dissolving, Pour into a mold at room temperature and cool and solidify naturally to dry to obtain transparent soap; and carry out the measurement of sensory quality, foaming ratio, foam stability and detergency with the operation method of Example 1.

[0051] Table ...

Embodiment 3

[0056] The extraction of waste oil is the same as embodiment 1, and the waste oil after processing is placed in plastic bottle and sealed, and then at room temperature, the radiation dose is 5KGy 60 Irradiate 7min under Co gamma ray; Add the sodium hydroxide ethanol solution saponification of existing 1mol / L with the operation method of embodiment 1 and obtain soap paste for 16min, wherein the mass ratio of sodium hydroxide ethanol solution and waste oil is 1:8; In gained soap paste, add the waste soap that the ethanol of soap paste quality 10wt%, the sucrose of soap paste quality 15wt%, the distilled water of soap paste quality 30wt% and the pulverization of soap paste quality 20wt% are fully stirred at 60 ℃ until completely dissolving, Pour into a mold at room temperature and cool and solidify naturally to dry to obtain transparent soap; and carry out the measurement of sensory quality, foaming ratio, foam stability and detergency with the operation method of Example 1.

[0...

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Abstract

The invention relates to a method for preparing transparent soap by performing irradiation treatment on illegal cooking oil. The method comprises the following steps: firstly, performing centrifugal separation on the illegal cooking oil to remove impurities, and sealing by using a sealing bottle; uniformly irradiating the sealing bottle filled with the illegal cooking oil by using cobalt source rays for 5-10 minutes with the auxiliary dosage of 1-5KGy at the room temperature; filtering the irradiated illegal cooking oil, adding sodium hydroxide ethanol solution to be saponified to obtain soap paste; adding ethanol, crane sugar, distilled water and waste soap into the soap paste to be fully stirred until the soap paste is saponified; pouring the saponified soap paste into a mould to be cured and dried to obtain the transparent soap. According to the method, the illegal cooking oil is irradiated by using the cobalt rays, a DNA sequence, a protein structure and the like in bacteria tissue in the illegal cooking oil can be destroyed to cause the death of the bacteria; meanwhile, volatile odor substances in the illegal cooking oil can be modified; the prepared transparent soap has the characteristics of shallow color, asepsis, no odor and long expiration date; the soap body has a uniform crystal structure, and is high in transparency and high in foaming capability; moreover, the harmless resource utilization of the illegal cooking oil can be realized.

Description

technical field [0001] The invention relates to the field of preparing transparent soap with waste oil, in particular to a method for preparing transparent soap with radiation treatment waste oil. Background technique [0002] In 2013, China consumed about 30 million tons of edible oils and fats, 15% of which, about 4.5 million tons, became waste oils and fats. Since 2009, the price of cooking oil has risen sharply, and the net profit of waste cooking oil has also increased. Driven by profit, most of the gutter oil is used by criminals as a raw material for the production of edible oil to endanger the society. [0003] Although it has lost its edible value, the main components of gutter oil are still triglycerides and free fatty acids with varying contents. Triglycerides and free fatty acids can all undergo saponification with alkali to form soap, that is, detergent soap, washing powder, etc. main ingredient. Although saponification is the core process of preparing soap a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C11D9/02C11D9/26C11D13/30
Inventor 相玉琳相玉秀王立鹏王若恺
Owner YULIN UNIV
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