The invention relates to a wet
detoxification method for
chromium slag and
chromium-containing pollutants. The wet
detoxification method comprises the following steps: screening and crushing the
chromium slag and the chromium-containing pollutants, performing
wet milling on the chromium
slag and the chromium-containing pollutants in a
ball mill, adding a filtrate containing
sulfate ions, leaching out acid-soluble
calcium chromate in chromium slag
slurry, adding the chromium slag
slurry and a first
reducing agent sequentially into a reaction tank, stirring and mixing the chromium slag
slurry with the first
reducing agent to perform reduction reaction, reducing the acid-soluble
calcium chromate in chromium slag slurry to trivalent chromium, adding concentrated
sulfuric acid and to stirring and mixing for regulating, adjusting pH value of the chromium slag slurry to be 7+ / -0.5, then adding a second
reducing agent into the reaction tank and stirring and mixing for reducing, stirring the reduced slag slurry to cure the reduced slag slurry, and converting
hexavalent chromium in the chromium slag slurry to chromic
hydroxide sediment; and separating
solid and liquid of the cured chromium slag slurry. The wet
detoxification method has the characteristics of low cost, no waste liquid, no slag returning phenomenon, good detoxification effect and capability of being applicable to the large-scale industrial production.