Organic electroluminescent device and preparation method thereof

An electroluminescent device and electroluminescent technology, which is applied in the fields of electro-solid devices, semiconductor/solid-state device manufacturing, and electrical components, etc., can solve the problems of reduced luminous efficiency of light-emitting devices, increased operating voltage and decreased stability of light-emitting devices, etc. Improve hole injection efficiency, reduce operating voltage, and increase the effect of logarithm

Inactive Publication Date: 2015-09-02
OCEANS KING LIGHTING SCI&TECH CO LTD +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Taking the anode side as an example, the holes must overcome the energy barriers that exist at the interface between the anode and the hole injection layer, between the hole injection layer and the hole transport layer, and between the hole transport layer and the organic light-emitting layer. ; When a larger energy barrier exists at the interface of the above-mentioned layers, holes should not enter the organic light-emitting layer, but will accumulate at the interface of each layer, so that the work of the organ

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  • Organic electroluminescent device and preparation method thereof
  • Organic electroluminescent device and preparation method thereof

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Example Embodiment

[0032] The present invention also provides a method for preparing the above-mentioned organic electroluminescent device, the steps of which are:

[0033] a) Pretreatment of anode conductive substrate

[0034] Use ITO glass (also known as indium tin oxide transparent conductive glass) as the anode conductive substrate, and wash it with detergent, deionized water, acetone and ethanol successively. All are cleaned with an ultrasonic cleaning machine. Each washing takes 5 minutes. , Stop for 5 minutes, repeat the method 3 times respectively, and then dry it in an oven for later use; the cleaned ITO glass needs to be surface activated to increase the oxygen content on the surface of the ITO glass and improve the ITO glass The work function of the surface; the thickness of ITO glass is 100~150nm;

[0035] b) Preparation of the first hole injection layer

[0036] Using N,N'-diphenyl-N,N'-bis(1-naphthyl)-1,1'-biphenyl-4,4'-diamine (NPB), 4,4',4'' -Tris(carbazol-9-yl)triphenylamine (TCTA), 4...

Example Embodiment

[0052] Example 1

[0053] Such as figure 1 As shown, this embodiment 1 provides an organic electroluminescent device, the organic electroluminescent device has a layered structure, and the organic electroluminescent device in turn includes an anode conductive substrate 101 and a first hole injection layer 102 , The first electron injection layer 103, the second hole injection layer 104, the hole transport layer 105, the green light emitting layer 106, the electron transport layer 107, the second electron injection layer 108, and the cathode layer 109.

[0054] The expression of the organic electroluminescent device is: ITO glass / MoO 3 :NPB(30:100) / Cs 2 CO 3 :Bphen(30:100) / MoO 3 :NPB(30:100) / NPB / Ir(ppy) 3 :TCTA(10:100) / Bphen / Cs 2 CO 3 :Bphen(30:100) / Ag, where the colon ":" means that the former is doped in the latter.

[0055] This embodiment 1 also provides a method for preparing the above-mentioned organic electroluminescent device, the steps of which are:

[0056] a) Pretreatment ...

Example Embodiment

[0074] Example 2

[0075] Such as figure 1 As shown, the present embodiment 2 provides an organic electroluminescent device, the organic electroluminescent device has a layered structure, and the organic electroluminescent device sequentially includes an anode conductive substrate 101 and a first hole injection layer 102 , The first electron injection layer 103, the second hole injection layer 104, the hole transport layer 105, the green light emitting layer 106, the electron transport layer 107, the second electron injection layer 108, and the cathode layer 109.

[0076] The expression of the organic electroluminescent device is: ITO glass / WO 3 :TCTA(25:100) / CsF:BCP(25:100) / WO 3 :TCTA(25:100) / TCTA / Ir(ppy) 2 (acac):mCP(2:100) / BCP / CsF:BCP(25:100) / Al, where the colon ":" means that the former is mixed in the latter.

[0077] This embodiment 2 also provides a method for preparing the above-mentioned organic electroluminescent device, and the steps are as follows:

[0078] a) Pretreatment...

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Abstract

The invention relates to an organic electroluminescent device and a preparation method thereof, wherein the organic electroluminescent device has a layered structure and comprises an anode conductive substrate, a first hole injection layer, a first electron injection layer, a second hole injection layer, a hole transport layer, a green light emitting layer, an electron transmission layer, a second electron injection layer and a cathode layer; wherein the anode conductive substrate, the first hole injection layer, the first electron injection layer, the second hole injection layer, the hole transport layer, the green light emitting layer, the electron transmission layer, the second electron injection layer and the cathode layer are successively laminated. The first hole injection layer and the second hole injection layer are made of hole injection material and p-type material which is doped into the hole injection material. The first electron injection layer and the second electron injection layer are made of electron injection material and n-type material which is doped into the electron injection material. According to the organic electroluminescent device, through the added second hole injection layer and the second electron injection layer, working voltage can be reduced and luminous efficiency can be improved effectively.

Description

technical field [0001] The invention relates to the field of optoelectronic devices, in particular to an organic electroluminescent device and a preparation method thereof. Background technique [0002] Organic electroluminescent devices (OLEDs) have some unique advantages: (1) OLEDs are diffuse surface light sources, and do not require an additional light guide system to obtain large-area white light sources like light-emitting diodes (LEDs); (2) Due to the diversity of organic light-emitting materials, OLED lighting can design the required color of light according to needs. At present, both small molecule OLEDs and polymer organic light-emitting diodes (PLEDs) have obtained all colors of light including the white light spectrum. ; (3) OLED can be made on a variety of substrates such as glass, ceramics, metal, plastic and other materials, which makes the design of lighting sources more free; (4) OLED lighting panels can be made in the way of making OLED displays. (5) OLED ...

Claims

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Application Information

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IPC IPC(8): H01L51/50H01L51/54H01L51/56
CPCH10K85/00H10K50/17H10K50/171H10K71/00
Inventor 周明杰钟铁涛王平冯小明
Owner OCEANS KING LIGHTING SCI&TECH CO LTD
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