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Glass bead for outdoor advertisement reflective membrane and preparation method thereof

A technology of glass beads and reflective film, which is applied in glass manufacturing equipment, glass molding, optics, etc., can solve the problems of inability to meet the use requirements of reflective film, poor compatibility and affinity, and affect the performance of reflective film. Mechanical properties and weather resistance, avoiding agglomeration, improving reflective properties and quality effects

Inactive Publication Date: 2015-10-07
HEFEI DINGLIANG OPTICAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, glass microspheres are an important raw material for the manufacture of reflective films, but in actual production, due to the polar state of "hydrophilic and oleophobic" on the surface, the compatibility and affinity between them and the polymer matrix Poor, the obvious interface effect with the polymer matrix makes the glass beads agglomerate and other phenomena, which affects the performance of the reflective film and leads to a decline in quality. In addition, the glass beads on the existing market still have poor weather resistance and poor durability. The disadvantages lead to a greatly shortened service life and cannot meet the requirements for the use of outdoor advertising reflective film

Method used

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  • Glass bead for outdoor advertisement reflective membrane and preparation method thereof

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Embodiment Construction

[0015] A glass microsphere for outdoor advertising reflective film, made of the following raw materials in weight (kg): purple sand soil 36, shell powder 27, adiophyllite 30, cement slag 24, sunstone 32, kaleite 27, soda Stone 20, 1,3-Butanediol 8, Potassium Lauryl Ether Phosphate 5, Sodium Diisobutyl Naphthalene Sulfonate 7, Cocamidopropyl Betaine 4, Ethoxylated Fatty Acid Methyl Esters 3, Additives 7;

[0016] The preparation method of described additive is as follows: a, take the raw material of following weight (kg): fluorite tailings 40, discarded molding sand 25, pebble chip 18, cryolite 15, calcium tungstate 12, lanthanum nitrate 5, strontium sulfate 8, Bismuth germanate 6, calcium tetraborate 7, barium metaphosphate 10, beryllium carbonate 10; b. Mix fluorite tailings, waste molding sand, pebble chips, and cryolite evenly, crush them, pass through an 80-mesh sieve, and add 8 times the amount of water , Wet ball milling at 4000r / min for 25min, dried, calcined at 810°C ...

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Abstract

The invention discloses glass beads for outdoor advertisement reflective membranes and a preparation method thereof. The glass beads are prepared from following raw materials by weight: 27-41 Yixing clay, 19-33 shell powder, 23-34 lamprophyllite, 18-30 cement slurry, 24-38 sunstone, 22-34 kaliophilite, 15-25 nahcolite, 5-10 1,3-butylene glycol, 4-7 potassiam polyoxyethylene laurylether phosphate, 6-8 nekal, 3-5 cocoamidopropyl betaine, 2-4 fatty methyl ester ethoxylates, and 6-9 additive. Yixing clay, lamprophyllite, cement slurry, sunstone, kaliophilite or the like are added to the raw materials, and the raw materials interact with each other, so the mechanical strength of the glass beads can be improved, and also the weatherability and endurance of the glass beads are substantially improved. The prepared glass beads have the good optical performance, are high in mechanical strength and long in service life, exhibit excellent weatherability and endurance, and fully meet use requirements of outdoor advertisement reflective membranes.

Description

technical field [0001] The invention relates to a glass microsphere for an outdoor advertising reflective film and a preparation method thereof, belonging to the field of glass microsphere manufacture. Background technique [0002] Reflective film is a film with a special structure that uses optical principles to retroreflect light back to the light source. Reflective film is a novel reflective material formed by combining the reflective layer formed by glass beads with polymer materials such as PVC, PU, ​​PET, acrylic, and PC by using a special process. Among them, glass microspheres are an important raw material for the manufacture of reflective films, but in actual production, due to the polar state of "hydrophilic and oleophobic" on the surface, the compatibility and affinity between them and the polymer matrix Poor, the obvious interface effect with the polymer matrix makes the glass beads agglomerate and other phenomena, which affects the performance of the reflective...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G02B5/128C03C12/02C03B19/10
Inventor 范春平
Owner HEFEI DINGLIANG OPTICAL TECH
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