High-solid-content finishing oil-based acrylic resin for automobiles and preparation method thereof

An acrylic resin, high-solid technology, applied in the direction of coating, etc., can solve the problems of low solid content, poor solubility, high viscosity, etc., and achieve the effect of increasing the thickness of the paint film, improving the vividness of image, and improving the fullness and texture

Active Publication Date: 2015-11-11
安徽优科新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Aiming at the problems of low solid content, high viscosity and poor solubility in existing acrylic resin coatings, the invention provides a high-solid varnish type oily acrylic resin for automobiles and a preparation method thereof

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0068] In this embodiment, a high-solid varnish oil-based acrylic resin for automobiles contains components and the content of each component is:

[0069] No. 100 solvent oil 10% (No. 100 solvent oil consists of trimethylbenzene (mass fraction is 80-85%), tetramethylbenzene (mass fraction is 5-8%), xylene (mass fraction is 1%), ethylbenzene (mass fraction Fraction is 2%), propylbenzene (mass fraction is 3%) other trace impurities (mass fraction is 1%) component composition, purchased from Jiangsu Hualun Chemical Co., Ltd.)

[0070] Acrylic 1.7%

[0071] Styrene 1%

[0072] Butyl Acrylate 4.7%

[0073] Hydroxyethyl Methacrylate 5%

[0074] Methyl methacrylate 2%

[0075] Methacrylic acid 0.8%

[0076] Butyl methacrylate 7.8%

[0077] Isooctyl Acrylate 5%

[0078] n-Dodecanethiol 0.8%

[0079] Lauryl Methacrylate 16%

[0080] Isobornyl Methacrylate 20%

[0081] Hydroxyethyl Acrylate 4.8%

[0082] Hydroxypropyl Acrylate 4.7%

[0083] Di-tert-Amyl Peroxide 3%

[0084]...

Embodiment 2

[0096] In this embodiment, a high-solid varnish oil-based acrylic resin for automobiles contains components and the content of each component is:

[0097] No. 100 mineral spirits 10%

[0098] Acrylic 1%

[0099] Styrene 3%

[0100] Butyl Acrylate 2%

[0101] Hydroxyethyl Methacrylate 8%

[0102] Methyl methacrylate 1%

[0103] Methacrylic acid 1%

[0104] Butyl methacrylate 5%

[0105] Isooctyl Acrylate 8%

[0106] n-Dodecanethiol 0.3%

[0107] Lauryl Methacrylate 18%

[0108] Isobornyl Methacrylate 24.8%

[0109] Hydroxyethyl Acrylate 5%

[0110] Hydroxypropyl Acrylate 2%

[0111] Di-tert-Amyl Peroxide 2.9%

[0112] Glycidyl tert-carbonate 3%

[0113] Resin reactive diluent 5%.

[0114] Resin active diluent is saturated polyester resin, which is obtained by reacting the following components in proportion: 2% phosphoric acid, 29.9% adipic acid, 30% neopentyl glycol, 20% isooctanoic acid, 15% stearic acid, Butyl acetate 3%, monobutyltin oxide (catalyst) 0.1%, all...

Embodiment 3

[0124] In this embodiment, a high-solid varnish oil-based acrylic resin for automobiles contains components and the content of each component is:

[0125] No. 100 mineral spirits 10%

[0126] Acrylic 2%

[0127] Styrene 2.1%

[0128] Butyl Acrylate 5%

[0129] Hydroxyethyl Methacrylate 6.78%

[0130] Methyl methacrylate 1.6%

[0131] Methacrylic acid 0.1%

[0132] Butyl methacrylate 8%

[0133] Isooctyl Acrylate 7.5%

[0134] n-Dodecanethiol 1%

[0135] Lauryl Methacrylate 10%

[0136] Isobornyl Methacrylate 25%

[0137] Hydroxyethyl Acrylate 2%

[0138] Hydroxypropyl Acrylate 5%

[0139] Di-tert-Amyl Peroxide 1%

[0140] Glycidyl tert-carbonate 8%

[0141] Resin reactive diluent 5%.

[0142] Resin active diluent is saturated polyester resin, which is obtained by reacting the following components in proportion: 2% phosphoric acid, 32% adipic acid, 24.9% neopentyl glycol, 17% isooctanoic acid, 18% stearic acid, Butyl acetate 6%, monobutyl tin oxide (catalyst) 0.1%,...

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Abstract

The invention discloses a high-solid-content finishing oil-based acrylic resin for automobiles and a preparation method thereof, which belong to the field of automobile paints and solve the problems of low solid content, high viscosity, poor solubility and the like in the existing acrylic resin paint. The resin contains acrylic acid, styrene, butyl acrylate, hydroxyethyl methacrylate, methyl methacrylate, methacrylic acid, butyl methacrylate, 2-ethylhexyl acrylate, n-dodecyl mercaptan, lauryl methacrylate, isoborneol methacrylate, 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, 100# solvent oil, di-tert-pentyl peroxide, glycidol tert-carboxylate and a resin reactive diluent. The solid content can reach 90%. The acrylic resin has the advantages of favorable dilution property and low viscosity. The self-made reactive diluent can greatly enhance the water resistance and acid resistance of the paint. The construction solid content of the resin is nearly 70%. The acrylic resin greatly lowers the discharge of VOC (volatile organic compound), and is environment-friendly and practical.

Description

technical field [0001] The invention belongs to the field of automobile coatings, and more specifically relates to a high-solid varnish type oily acrylic resin for automobiles and a preparation method thereof. Background technique [0002] As countries around the world pay more and more attention to the pollution of organic volatiles to the atmosphere and the protection of the environment, some industrialized countries have established special management agencies to formulate various laws and regulations to impose strict restrictions on the amount of solvent volatilization during coating construction. Therefore, various low-pollution coatings have emerged at the historic moment since the 1970s, and one type of coating with better effect and promising development is high-solid coating. High-solid acrylic paint, as a kind of high-solid paint, has attracted more and more people's attention because of its light color, color retention, gloss retention and other characteristics in...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D133/10C09D7/12C08F220/18C08F220/28
Inventor 王世玉曹志华
Owner 安徽优科新材料科技有限公司
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