Liquid calcium/zinc heat stabilizer, preparing method thereof and device for implementing method

A heat stabilizer and liquid calcium technology, applied in the field of liquid calcium/zinc heat stabilizers, can solve the problems of manual transfer of semi-finished products, great harm to operators, long production time cycle, etc., to reduce unsafe factors and short production cycle , The effect of simplifying the production process

Active Publication Date: 2015-12-02
GUANGZHOU YINGSU NEW MATERIAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Its disadvantages are: 1. The production steps are cumbersome and the process is complex, including feeding, salt formation, dehydration, compounding, pressure filtration, and finished product packaging processes. Each process is completed in different equipment, and semi-finished products need to be manually transferred. It is very troublesome; 2. Production The time period is long and the energy consumption is high, especially the dehydration, and the two production processes of the filter press consume a lot of energy; 3. A large amount of acid mist is formed during high-temperature production, and the production of the equipment is not closed, which is harmful to the operators; 4. New process production The resulting product has stable performance, and its anti-separation and heat resistance are significantly better than the previous process

Method used

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  • Liquid calcium/zinc heat stabilizer, preparing method thereof and device for implementing method

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Effect test

Embodiment 1

[0054] A liquid calcium / zinc heat stabilizer, comprising the following preparation raw materials in parts by weight: 10 parts of calcium hydroxide, 15 parts of zinc oxide, 36 parts of acid solution, 0.6 parts of catalyst, 1 part of water-carrying agent, and 17 parts of saturated naphthenic solvent , 20 parts of heat-resistant additives;

[0055] Among them, the acid solution is a mixture of 8 parts of isooctanoic acid, 3 parts of octanoic acid, 18 parts of oleic acid, 4 parts of p-tert-butylbenzoic acid and 3 parts of benzoic acid, the catalyst is a mixture of 0.5 parts of acetic acid and 0.1 part of formic acid, and the water carrier It is 1 part of ethylene glycol, the saturated cycloalkane solvent is a mixture of butanone, 7 parts of odorless kerosene and 2 parts of albino oil, and the heat-resistant additive is a mixture of 12 parts of soybean oil and 8 parts of phosphite ester.

[0056] A preparation method of liquid calcium / zinc heat stabilizer, comprising the following ...

Embodiment 2

[0063] A liquid calcium / zinc heat stabilizer, comprising the following preparation raw materials in parts by weight: 15 parts of calcium oxide, 18 parts of zinc oxide, 40 parts of acid solution, 1 part of catalyst, 1 part of water-carrying agent, 12 parts of saturated naphthenic solvent, 14 parts of heat-resistant additive;

[0064] Among them, the acid liquid is a mixture of 20 parts of oleic acid and 20 parts of isooctanoic acid, the catalyst is 1 part of propionic acid, the water-carrying agent is 1 part of ethylene glycol, the saturated naphthenic solvent is 12 parts of deodorized kerosene, and the heat-resistant additive is 1 part A mixture of 1 part SBM and 2 parts DBM, 5 parts soybean oil, 6 parts phosphite.

[0065] A preparation method of liquid calcium / zinc heat stabilizer, comprising the following steps:

[0066] 201. Pre-heat the oil bath temperature of the reactor to 135°C, add 40 parts of acid solution into the reactor, cover the lid of the reactor, start stirri...

Embodiment 3

[0072] A liquid calcium / zinc heat stabilizer, comprising the following preparation raw materials in parts by weight: 15 parts of calcium hydroxide, 20 parts of zinc oxide, 40 parts of acid solution, 1 part of catalyst, 2 parts of water-carrying agent, and 10 parts of saturated naphthenic solvent , 13 parts of heat-resistant additives;

[0073] Among them, the acid liquid is a mixture of 28 parts of isooctanoic acid and 12 parts of p-tert-butylbenzoic acid, the catalyst is a mixture of 0.6 parts of acetic acid, 0 part of formic acid and 0.4 part of propionic acid, and the water carrier is 2 parts of methanol, saturated naphthenic solvent It is a mixture of 0 parts of triethylene glycol and 10 parts of cyclohexanone, and the heat-resistant additive is a mixture of 8 parts of soybean oil, 4 parts of phosphite ester and 1 part of antioxidant.

[0074] A preparation method of liquid calcium / zinc heat stabilizer, comprising the following steps:

[0075] 301. Preset the temperature ...

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Abstract

The invention discloses a liquid calcium/zinc heat stabilizer. The liquid calcium/zinc heat stabilizer comprises, by weight, 10 parts to 15 parts of calcium oxide and/or calcium hydroxide, 10 parts to 20 parts of zinc oxide and/or zinc hydroxide, 30 parts to 40 parts of acid liquor, 1 part to 2 parts of azeotropic agents, 10 parts to 20 parts of saturated cycloparaffin solvents and 10 parts to 20 parts of heat-proof assistants. The invention further discloses a preparing method of the liquid calcium/zinc heat stabilizer and a device for implementing the method. According to the liquid calcium/zinc heat stabilizer, the product performance is stable, floccule can not be separated out during placing, the product is free of pungent smells, and the body of an operator can not be hurt. The preparing method of the liquid calcium/zinc heat stabilizer adopts a one-step method, the production technology is simplified, the unsafe factors in the production process are reduced, the production efficiency is improved, and the output rate is increased.

Description

technical field [0001] The invention belongs to the field of liquid stabilizers, and in particular relates to a liquid calcium / zinc heat stabilizer, a preparation method thereof and equipment for implementing the method. Background technique [0002] With the improvement of living standards, the requirements for environmental protection of industrial and household PVC products are increasing day by day. In the early 1990s, the compound lead salt stabilizer and cadmium barium zinc stabilizer were widely used. Among them, the heat stabilizers of lead salt and barium cadmium soap are cheap and have excellent performance. In developed countries, their output accounts for about 60% to 70% of the total heat stabilizers; in my country, the proportion is even larger, accounting for about 80% to 90%. %. For a long time, lead and cadmium stabilizers have dominated the consumer market of PVC heat stabilizers in the world. However, due to the high toxicity of lead salts and barium cadm...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08K5/098
Inventor 李俭
Owner GUANGZHOU YINGSU NEW MATERIAL TECH CO LTD
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