Degraded mulch film containing nanometer level TiO2 photocatalysis, water, oxidation and biological degradation technologies

A degradable mulch, nano-scale technology, applied in the direction of coating, etc., can solve the problems of uneven distribution of functional components, short-term effect is not obvious, slow degradation, etc., to save manpower and material resources, reduce production costs, long-term stability Effect

Inactive Publication Date: 2015-12-09
SHENYANG INSTITUTE OF CHEMICAL TECHNOLOGY
View PDF5 Cites 13 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chinese patent CN1277228 and patent application CN101828495A form, wherein the patent CN1277228 adopts the method of liquid spraying to be directly applied to the scene, so that some raw materials will be quickly absorbed by the surface soil layer, but because it is liquid, the functional components are easily unevenly distributed, and After the plastic film is discarded, there will still be a small amount of pesticides, fertilizers and other additives on the plastic film, which will cause land pollution to a certain extent, which is not conducive to environmental protection
And the patent application CN101828495A uses the upper layer of mulch as the matrix resin, and the lower layer is sprayed with micro-fertilizers, herbicides, degradation agents, etc., but only biodegradation is used, the degradation is slow, and the short-term effect is not obvious

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Embodiment 1, get 30 parts of plant stalks, 20 parts of starch / polyvinyl alcohol, 10 parts of aliphatic polyester, 10 parts of polylactic acid, 0.5 part of surfactant (sodium lauryl sulfate), film-forming agent (naphthene Sodium acid) 0.5 parts, stabilizer (potassium water glass) 4 parts, urea 3 parts, rare earth fertilizer 2 parts, water 20 parts. Dissolve starch / polyvinyl alcohol in hot water at 90-95°C, then add plant straw powder crushed to 300 mesh, surfactant, sodium naphthenate, potassium silicate, urea and rare earth micro-fertilizer, stir and squeeze Come out evenly.

Embodiment 2

[0018] Embodiment 2, get 30 parts of plant stalks, 10 parts of starch / polyvinyl alcohol, 10 parts of aliphatic polyester, 10 parts of polylactic acid, 1 part of surfactant (lignin amine), 3 parts of potassium nitrate, 4 parts of sodium water glass 3 parts of ammonium sulfate, 1 part of rare earth fertilizer, 2 parts of sodium hydroxide, and 26 parts of water.

[0019] First, steam the plant straw with sodium hydroxide aqueous solution for one hour under pressure to form a slurry; then add starch / polyvinyl alcohol to stir and dissolve, and then add aliphatic polyester and polylactic acid; then add surfactant, potassium nitrate, and sodium water Glass, ammonium sulfate and rare earth micro-fertilizer, just stir well.

Embodiment 3

[0020] Example 3, take 60 parts of concentrated papermaking liquid from a paper mill, 10 parts of starch / polyvinyl alcohol, 10 parts of aliphatic polyester, 10 parts of polylactic acid, 3 parts of potassium nitrate, 4 parts of sodium water glass, 2 parts of ammonium sulfate, rare earth 1 portion of micro-fertilizer.

[0021] Firstly, add polyvinyl alcohol into the concentrated papermaking black liquor at 90-95°C and stir to dissolve, then add aliphatic polyester and polylactic acid; then add potassium nitrate, sodium water glass, ammonium sulfate and rare earth micro-fertilizer, stir evenly Can.

[0022] The product of embodiment 1 is laid film on peanut ground. The film cracked in 31 days and completely degraded in 80 days. The yield per mu increased by 25%, and the maturity period was advanced by 5 days.

[0023] The product of embodiment 2 is laid film on peanut ground. The film cracked in 44 days and completely degraded in 105 days. The yield per mu increased by 35%, ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention provides a degraded mulch film containing nanometer level TiO2 photocatalysis, water, oxidation and biological degradation technologies, and relates to an agricultural mulch film. The mulch film is mixed from aliphatic polyester, polylactic acid, starch / polyvinyl alcohol, a modified plant straw, a film forming agent and a surfactant, and the mulch film comprises three layers, the mulch film middle layer contains the nanometer level TiO2 photocatalyst and a hydrolytic agent which are mixed in proportion; the upper layer is sprayed with a paint containing an oxidation degradation agent; the mulch film lower layer is sprayed with a fertilizer, a microelement fertilizer, a pesticide and a herbicide or the like which are mixed in proportion and are needed by plant growth; The three-layer mulch film provided by the invention can decay and decompose by itself, integrates pesticide, fertilizer and pesticide without residual, and comprises nanometer level TiO2 photocatalysis, water, oxidation and biological degradation technologies. The invention has the advantages of wide raw material sources, low cost, various degradation modes and fast degradation speed, and is suitable for different crop growths.

Description

technical field [0001] The invention relates to a degradable plastic film, in particular to a nano-scale TiO 2 Photocatalytic, water, oxidation, biodegradable plastic film. Background technique [0002] Plastic film plays an important role in my country's agricultural production process. It not only has the functions of heat preservation, moisture retention and fertilizer preservation, but also has the functions of preventing diseases and insect pests, preventing drought and waterlogging, which can promote the growth and development of crops, effectively increase crop yield, and increase production. benefit. However, due to the difficulty of decomposing the plastic itself, the traditional mulch film has poor air permeability and water permeability, and difficulties in weeding and fertilization, which limit the use of mulch film and affect land productivity. The three-layer mulch film is a combination of itself that can be completely decomposed, and the upper and lower layer...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08L97/02C08L67/00C08L67/04C08L3/02C08L29/04C08K13/02C08K3/22C08K5/098C08K3/34C08J7/04
Inventor 葛铁军周志阳任晓东吴姝
Owner SHENYANG INSTITUTE OF CHEMICAL TECHNOLOGY
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products