Process for producing olefin from methanol and for co-producing gasoline and aromatic hydrocarbon

A technology for producing olefins and aromatics from methanol, which is applied in the petroleum industry, ethylene production, and hydrocarbon production from oxygen-containing organic compounds. The effect of achieving zero emissions

Active Publication Date: 2016-01-20
CHINA UNIV OF PETROLEUM (EAST CHINA) +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Therefore, the technical problem to be solved by the present invention is to overcome the defect that low-value-added by-products cannot be fully utilized in the production of low-carbon olefins from coal-based methanol in the prior art, thereby providing a process for co-producing gasoline and aromatics from methanol to olefins

Method used

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  • Process for producing olefin from methanol and for co-producing gasoline and aromatic hydrocarbon
  • Process for producing olefin from methanol and for co-producing gasoline and aromatic hydrocarbon
  • Process for producing olefin from methanol and for co-producing gasoline and aromatic hydrocarbon

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Catalyst preparation

[0034] Mix the commercially available HZM-5 molecular sieve, alumina, scallop powder, water and nitric acid, stir evenly, shape, and dry naturally, then dry at 120°C for 3h, and finally in the muffle furnace from room temperature at 5°C / min Rise to 550°C and keep it for 3 hours to obtain a pretreatment catalyst; the mass ratio of HZM-5 molecular sieve to alumina is 7:3, the mass of kale powder added is 2.9% of the mass of HZM-5 molecular sieve, and the mass of water added is HZM 75% of the mass of -5 molecular sieve, and the added mass of nitric acid is 2.3% of the mass of HZM-5 molecular sieve.

[0035] With described pretreatment catalyst 15g, impregnate in the mixed solution of 7.5ml potassium nitrate (0.001mol / mL and calcium nitrate (0.02mol / mL), let stand 24h, dry naturally, then dry 3h at 120 ℃, finally in In the muffle furnace, the temperature was raised from room temperature to 550° C. at 5° C. / min and kept for 3 hours to obtain the MTO c...

Embodiment 2

[0042] Catalyst preparation

[0043] Mix the commercially available HZM-5 molecular sieve, alumina, scallop powder, water and nitric acid, stir evenly, shape, and dry naturally, then dry at 120°C for 3h, and finally in the muffle furnace from room temperature at 5°C / min Rise to 550°C and keep it for 3 hours to obtain a pretreatment catalyst; the mass ratio of HZM-5 molecular sieve to alumina is 6:4, the mass of kale powder added is 2.5% of the mass of HZM-5 molecular sieve, and the mass of water added is HZM 70% of the quality of -5 molecular sieve, the quality of adding nitric acid is 2% of the quality of HZM-5 molecular sieve.

[0044] 15g of the pretreatment catalyst was impregnated in a mixed solution of 7.5mL potassium nitrate (0.001mol / mL), calcium nitrate (0.02mol / mL), lanthanum nitrate (0.001mol / mL), cerium nitrate (0.001mol / mL) In the middle, let stand for 24h, dry naturally, then dry at 120°C for 3h, and finally raise from room temperature to 550°C at 5°C / min in a m...

Embodiment 3

[0051] Catalyst preparation

[0052] Mix the commercially available HZM-5 molecular sieve, alumina, scallop powder, water and nitric acid, stir evenly, shape, and dry naturally, then dry at 120°C for 3h, and finally in the muffle furnace from room temperature at 5°C / min Rise to 550°C and keep it for 3 hours to obtain a pretreatment catalyst; the mass ratio of HZM-5 molecular sieve to alumina is 5:3, the mass of kale powder added is 2.4% of the mass of HZM-5 molecular sieve, and the mass of water added is HZM 45% of the mass of -5 molecular sieve, and the added mass of nitric acid is 3% of the mass of HZM-5 molecular sieve.

[0053] 15g of the pretreatment catalyst was impregnated in 7.5mL of potassium nitrate (0.001mol / mL) solution, left to stand for 24h, dried naturally, then dried at 120°C for 3h, and finally in a muffle furnace from room temperature to 5°C / min increased to 550°C and kept for 3h to obtain an MTO catalyst.

[0054] 15g of the pretreatment catalyst was impr...

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Abstract

The invention provides a process for producing olefin from methanol and for co-producing gasoline and aromatic hydrocarbon. The process comprises the following steps: (1) introducing a methanol solution into an MTO fixed bed reactor, facilitating a reaction in the existence of an MTO catalyst, cooling a reaction product, separating the product in a separation tower to obtain a gas phase containing low-carbon olefin and a liquid phase containing the aromatic hydrocarbon; (2) separating ethylene, propylene, butylenes and methane from the gas phase in the step (1), introducing the residual gas into a light-hydrocarbon aromatization reactor, facilitating a reaction in the existence of an aromatization catalyst to obtain an aromatization reaction product, mixing the aromatization reaction product and the reaction product in the step (1), and separating a mixture in the separation tower of the step (1). According to the process, the low-additional-value byproduct formed after the MTO reaction is sufficiently utilized and is converted into the gasoline and aromatic hydrocarbon by virtue of the light-hydrocarbon aromatization reaction, so that the zero emission of the byproduct is realized, the yield of liquid hydrocarbon is increased, and the economic benefit of an enterprise is increased.

Description

technical field [0001] The invention relates to the field of methanol conversion technology, in particular to a technology for producing olefins from methanol and co-producing gasoline and aromatics. Background technique [0002] Low-carbon olefins such as ethylene and propylene are important basic chemical raw materials. With the development of my country's national economy, especially the development of modern chemical industry, the demand for low-carbon olefins is increasing day by day. The MTO process of methanol to low-carbon olefins has become increasingly important chemical technology. The MTO process refers to the chemical process technology that uses coal-based or natural gas-based synthetic methanol as a raw material to produce low-carbon olefins with the help of a fluidized bed reaction similar to a catalytic cracking unit. Its main products are ethylene, propylene, etc. Resources to produce core technologies for ethylene, propylene and other products. [0003] W...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C1/20C07C11/04C07C11/06C07C11/08C07C9/04C10G3/00C07C15/02
CPCY02P20/52Y02P30/20Y02P30/40
Inventor 张佳佳王玲玲洪正鹏商红岩李昭清
Owner CHINA UNIV OF PETROLEUM (EAST CHINA)
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