A heat-resisting environmental-friendly polyvinyl chloride material

A technology of polyvinyl chloride and environmentally friendly materials, applied in the field of polyvinyl chloride, can solve the problems of accelerated degradation of polyvinyl chloride, unsatisfactory heat resistance, and decline in physical and mechanical properties, and achieve prevention of catalytic degradation, excellent thermal stability, The effect of improving strength

A technology of polyvinyl chloride and environmentally friendly materials, applied in the field of polyvinyl chloride, can solve the problems of accelerated degradation of polyvinyl chloride, unsatisfactory heat resistance, and decline in physical and mechanical properties, and achieve prevention of catalytic degradation, excellent thermal stability, The effect of improving strength

CN105348672AInactive Publication Date: 2016-02-24ANHUI GUANGYUAN TECH DEV

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A heat-resistant polyvinyl chloride environmental protection material proposed by the present invention, its raw materials include the following components by weight: 65 parts of polyvinyl chloride, 35 parts of nitrile rubber, methyl methacrylate-butadiene-styrene copolymer 5 parts, 8 parts of chlorinated polyethylene, 0.5 parts of stearic acid, 2.5 parts of zinc stearate phosphite, 0.5 parts of calcium stearate, 2 parts of zinc ammonia triacetate, 1 part of acetyl tributyl citrate, epoxy 8 parts of butyl stearate, 2 parts of pentaerythritol, 5 parts of stearyl benzoyl methane, 0.5 parts of phenolic resin recycled material, 15 parts of modified composite filler, 0.5 parts of polyethylene wax, 7 parts of silane coupling agent;

[0019] Wherein, the modified composite filler is prepared according to the following process: 15 parts by weight of nano-lanthanum oxide, 15 parts of nano-titanium dioxide, 3 parts of nano-aluminum hydroxide and 10 parts of nano-zinc borate are un...

Embodiment 2

[0021] A heat-resistant polyvinyl chloride environmental protection material proposed by the present invention, its raw materials include the following components by weight: 80 parts of polyvinyl chloride, 20 parts of nitrile rubber, methyl methacrylate-butadiene-styrene copolymer 15 parts, 2 parts of chlorinated polyethylene, 1.5 parts of stearic acid, 1 part of zinc stearate phosphite, 1.5 parts of calcium stearate, 0.2 parts of zinc ammonia triacetate, 2.5 parts of acetyl tributyl citrate, epoxy 2 parts of butyl stearate, 6 parts of pentaerythritol, 2 parts of stearyl benzoyl methane, 2.5 parts of phenolic resin recycled material, 5 parts of modified composite filler, 2 parts of polyethylene wax, 2 parts of silane coupling agent;

[0022] Wherein, the modified composite filler is prepared according to the following process: 30 parts by weight of nano-lanthanum oxide, 5 parts of nano-titanium dioxide, 10 parts of nano-aluminum hydroxide and 2 parts of nano-zinc borate are uni...

Embodiment 3

[0024]A heat-resistant polyvinyl chloride environmental protection material proposed by the present invention, its raw materials include the following components by weight: 70 parts of polyvinyl chloride, 32 parts of nitrile rubber, methyl methacrylate-butadiene-styrene copolymer 9 parts, 6.3 parts of chlorinated polyethylene, 0.9 parts of stearic acid, 2.2 parts of zinc stearate phosphite, 0.9 parts of calcium stearate, 1.3 parts of zinc ammonia triacetate, 1.8 parts of acetyl tributyl citrate, epoxy 6 parts of butyl stearate, 4.3 parts of pentaerythritol, 4 parts of stearyl benzoyl methane, 1.6 parts of phenolic resin recycled material, 11 parts of modified composite filler, 1.2 parts of polyethylene wax, silane coupling agent KH-5402 parts, silane coupling agent A-1711.2 parts, silane coupling agent A-1721.4 parts;

[0025] Wherein, the modified composite filler is prepared according to the following process: 18 parts by weight of nano-lanthanum oxide, 12 parts of nano-tita...

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PUM

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Abstract

A heat-resisting environmental-friendly polyvinyl chloride material is disclosed. The material comprises following components by weight: 65-80 parts of polyvinyl chloride, 20-35 parts of nitrile butadiene rubber, 5-15 parts of methyl methacrylate-butadiene-styrene copolymer, 2-8 parts of chlorinated polyethylene, 0.5-1.5 parts of stearic acid, 1-2.5 parts of zinc phosphite stearate, 0.5-1.5 parts of calcium stearate, 0.2-2 parts of zinc nitrilotiracetate, 1-2.5 parts of acetyl tributyl citrate, 2-8 parts of butyl epoxystearate, 2-6 parts of pentaerythritol, 2-5 parts of oxooctadecyl benzoyl methane, 0.5-2.5 parts of recycled phenolic resin, 5-15 parts of a modified composite filler, 0.5-2 parts of polyethylene wax and 2-7 parts of a silane coupling agent. The material is good in heat resistance and waterproofness, excellent in flame retardance and good in environmental protection performance.

Description

technical field [0001] The invention relates to the technical field of polyvinyl chloride, in particular to a heat-resistant polyvinyl chloride environmental protection material. Background technique [0002] Polyvinyl chloride has the advantages of high mechanical strength, good chemical corrosion resistance, low price, good flame retardancy and electrical insulation, and is mainly used in the production of transparent cables, soft toys, medical equipment, food packaging films, artificial leather products, etc. Soft products and hard products such as plates, doors and windows, pipes and valves have become the second largest general-purpose resin after polyethylene. Since the polyvinyl chloride macromolecular chain contains unstable chlorine atoms, it begins to decompose and release hydrogen chloride at 100°C, and a color-producing conjugated polyene structure is formed on the molecular chain, thereby discoloring the product. The degradation of ethylene has a catalytic effe...

Claims

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Application Information

Patent Timeline
24 Feb 2016
Publication
CN105348672A
IPC
C08L27/06; C08L9/02; C08L51/04; C08L23/28; C08L61/06; C08L23/06; C08K13/06; C08K9/04; C08K9/06; C08K3/22; C08K3/38; C08K5/09; C08K5/098; C08K5/11; C08K5/053
Inventors
梁晓燕