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A kind of preparation method of molecular sieve adsorption profiles

A molecular sieve and adsorption technology, which is applied in the field of molecular sieves and its preparation, can solve problems such as poor realization of pore size gradient distribution, difficulty in achieving effective coverage of components, and difficulty in precise control of the process, so as to achieve rich pore size distribution, easy processing and use performance, easy operation

Active Publication Date: 2018-08-17
青岛纳博科环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, molecular sieves have a regular structure and uniform pore size, and only have a good adsorption effect on molecules with comparable pore size and polarity. However, the composition of exhaust gas is usually very complex, and the molecular size and polarity of various compounds are different. Use It is difficult to achieve effective coverage of all components with a single molecular sieve
[0003] At present, molecular sieves with micropores and mesoporous hierarchical pore structures have been developed in the existing technology, which are mainly used for heavy oil catalytic cracking to realize the step-by-step cracking of long-chain macromolecular hydrocarbons. Similarly, mesopores and micropores are used Molecular sieve compounding or co-crystal is also to achieve step-by-step catalysis of macromolecules, but this method is not aimed at small organic molecules and cannot solve the above problems; The process is difficult to control precisely, the repeatability is poor, and limited by the synthesis conditions, the combination of molecular sieves that can be realized is limited, and the expected range of pore size gradient distribution cannot be well achieved.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] The molecular sieve used in this example is MFI type.

[0028] In this embodiment, the preparation method of molecular sieve adsorption profiles specifically includes the following steps:

[0029] Step 1, preparing a profile, extruding silicon dioxide, alumina, aluminum silicate or titanium dioxide powder to obtain a profile;

[0030] Step 2, adhering inorganic adhesives such as silica gel and aluminum glue to the surface of the obtained profile, uniformly adhering the MFI molecular sieve to the surface and gaps of the profile by impregnation, and drying to obtain a molecular sieve adsorption profile body;

[0031] Step 3, drying the molecular sieve adsorption profile body at a hot air temperature of 600° C. to obtain the molecular sieve adsorption profile.

[0032] The pore width of the MFI type molecular sieve profile prepared in embodiment 1 is 1.8mm, the height is 3mm, and the BET surface area is 200m 2 / g, the micropore diameter is concentrated in 0.4-0.5nm.

Embodiment 2

[0034] The difference from Example 1 is that the step of preparing the profile in step 1 is: use a mixture of fibers with a diameter of 2-20 microns and a length of 500-8000 microns for papermaking, wherein the mixture of fibers is ceramic fiber, glass A mixture of fiber, activated carbon fiber, synthetic fiber and natural fiber, and then extruded into a paper with a concave-convex surface. , to obtain profiles; before loading molecular sieves, through pre-oxidation (inert atmosphere, 150-300°C), high-temperature oxidation (inert atmosphere, 700-900°C) and steam treatment, synthetic fibers or natural fibers in profiles, such as Polyacrylonitrile, viscose fiber, etc. are converted into activated carbon fibers; if activated carbon fibers need to be retained during hot air drying, it must be carried out under an inert atmosphere.

[0035] The pore width of the MFI type molecular sieve profile prepared in embodiment 2 is 1.8mm, the height is 3mm, and the BET surface area is 220m ...

Embodiment 3

[0037] The molecular sieves used in this embodiment are MFI type and BEA type molecular sieves.

[0038] In this embodiment, the preparation method of molecular sieve adsorption profiles specifically includes the following steps:

[0039] Step 1, selecting a mixture of fibers with a diameter of 2-20 microns and a length of 500-8000 microns for papermaking, wherein the mixture of fibers is a mixture of ceramic fibers, glass fibers, activated carbon fibers, synthetic fibers and natural fibers, ceramic fibers , glass fiber and activated carbon fiber are 80 parts, synthetic fiber and natural fiber are 10 parts, and then extruded into a paper with a concave-convex surface, the paper with the concave-convex surface obtained is bonded on the flat paper to form a layered body, and the layered The profile is obtained by stacking or winding the profile; before loading the molecular sieve, it is pre-oxidized (inert atmosphere, 150-300°C), high temperature oxidation (inert atmosphere, 700...

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Abstract

The invention discloses a preparation method of a molecular sieve adsorption profile material, and belongs to the technical fields of molecular sieves and preparation thereof. The molecular sieve adsorption profile material is in a honeycomb structure, and composed of a plurality of parallel channels; each channel has height of 1-30 mm and width of 2-60 mm; the molecular sieve adsorption profile material has specific surface area of 200-400 m<2> / g, and uses raw material molecular sieves including one or more of the followings in combination: MFI type, BEA type, FAU type and MOR type molecular sieves. The profile material of the invention has rich aperture distribution than the single molecular sieve, can cover most of the gas to be treated such as volatile organic compounds and odor gas, has a wide range of processing; the combination of a variety of molecular sieves and adhesion of the molecular sieves on the profile surface and in the gaps achieve different aperture distribution on the profile material.

Description

technical field [0001] The invention relates to the technical field of molecular sieves and their preparation, in particular to a method for preparing molecular sieve adsorption profiles. Background technique [0002] Adsorption materials such as activated carbon and molecular sieves have been widely used in the removal of volatile organic compounds and other purposes. Compared with traditional activated carbon materials, molecular sieves are non-flammable and safe as inorganic materials, and can handle VOC components with higher boiling points. The adsorption performance of hydrophobic molecular sieves is not sensitive to humidity, and can selectively adsorb organic waste gases. This technology applications are expanding. However, molecular sieves have a regular structure and uniform pore size, and only have a good adsorption effect on molecules with comparable pore size and polarity. However, the composition of exhaust gas is usually very complex, and the molecular size a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/20B01J20/28B01J20/30
CPCB01J20/20B01J20/28045B01J20/28078B01J2220/42B01J2220/4806
Inventor 刘冰汪茂菊陈保磊杜月娟冯晓郅立鹏
Owner 青岛纳博科环保科技有限公司