A kind of preparation method of molecular sieve adsorption profiles
A molecular sieve and adsorption technology, which is applied in the field of molecular sieves and its preparation, can solve problems such as poor realization of pore size gradient distribution, difficulty in achieving effective coverage of components, and difficulty in precise control of the process, so as to achieve rich pore size distribution, easy processing and use performance, easy operation
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Embodiment 1
[0027] The molecular sieve used in this example is MFI type.
[0028] In this embodiment, the preparation method of molecular sieve adsorption profiles specifically includes the following steps:
[0029] Step 1, preparing a profile, extruding silicon dioxide, alumina, aluminum silicate or titanium dioxide powder to obtain a profile;
[0030] Step 2, adhering inorganic adhesives such as silica gel and aluminum glue to the surface of the obtained profile, uniformly adhering the MFI molecular sieve to the surface and gaps of the profile by impregnation, and drying to obtain a molecular sieve adsorption profile body;
[0031] Step 3, drying the molecular sieve adsorption profile body at a hot air temperature of 600° C. to obtain the molecular sieve adsorption profile.
[0032] The pore width of the MFI type molecular sieve profile prepared in embodiment 1 is 1.8mm, the height is 3mm, and the BET surface area is 200m 2 / g, the micropore diameter is concentrated in 0.4-0.5nm.
Embodiment 2
[0034] The difference from Example 1 is that the step of preparing the profile in step 1 is: use a mixture of fibers with a diameter of 2-20 microns and a length of 500-8000 microns for papermaking, wherein the mixture of fibers is ceramic fiber, glass A mixture of fiber, activated carbon fiber, synthetic fiber and natural fiber, and then extruded into a paper with a concave-convex surface. , to obtain profiles; before loading molecular sieves, through pre-oxidation (inert atmosphere, 150-300°C), high-temperature oxidation (inert atmosphere, 700-900°C) and steam treatment, synthetic fibers or natural fibers in profiles, such as Polyacrylonitrile, viscose fiber, etc. are converted into activated carbon fibers; if activated carbon fibers need to be retained during hot air drying, it must be carried out under an inert atmosphere.
[0035] The pore width of the MFI type molecular sieve profile prepared in embodiment 2 is 1.8mm, the height is 3mm, and the BET surface area is 220m ...
Embodiment 3
[0037] The molecular sieves used in this embodiment are MFI type and BEA type molecular sieves.
[0038] In this embodiment, the preparation method of molecular sieve adsorption profiles specifically includes the following steps:
[0039] Step 1, selecting a mixture of fibers with a diameter of 2-20 microns and a length of 500-8000 microns for papermaking, wherein the mixture of fibers is a mixture of ceramic fibers, glass fibers, activated carbon fibers, synthetic fibers and natural fibers, ceramic fibers , glass fiber and activated carbon fiber are 80 parts, synthetic fiber and natural fiber are 10 parts, and then extruded into a paper with a concave-convex surface, the paper with the concave-convex surface obtained is bonded on the flat paper to form a layered body, and the layered The profile is obtained by stacking or winding the profile; before loading the molecular sieve, it is pre-oxidized (inert atmosphere, 150-300°C), high temperature oxidation (inert atmosphere, 700...
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Abstract
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