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A continuous casting roller crystallizer

A mold and continuous casting roll technology, applied in the field of continuous casting roll molds, can solve the problems of low coating hardness, weakened wear resistance, unsatisfactory corrosion resistance, etc., and achieve improved coating performance and wear resistance. The effect of improving and anti-corrosion performance

Active Publication Date: 2017-11-14
陈玲婷
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although compared with the brush plating method, the hardness of the coating obtained by the electroplating method is relatively low, and the wear resistance may be weakened. Performance requirements are more focused
[0006] The Chinese patent application whose publication number is CN101126169A discloses a method for electroplating the surface of a thin strip continuous casting crystal roll and its electroplating solution. The anti-corrosion performance is not ideal, and it is not suitable for some steel types with high self-corrosion

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A continuous casting roll crystallizer, including a roll core and a roll surface, the roll core is hollow, cooled by cooling water, the base material of the roll surface is a copper alloy, and the copper alloy is electroplated with a nickel coating, wherein the composition of the copper alloy is determined by mass Percentage is: Ni: 3%; Be: 0.2%; Al: 1%, Zr: 1%; Mn: 0.2%; Mg: 3%; Sn: 0.05%; 0.8mm; the electroplating process includes the following process steps:

[0019] 1) Pretreatment: cleaning the surface of the continuous casting crystal roll with organic solvent, alkali degreasing, electrolytic degreasing, acid etching and activation treatment;

[0020] 2) Electroplating metal nickel: The composition of the electroplating solution is: nickel sulfamate 180g / l, nickel sulfate 50g / l, nickel chloride 20g / l, tin chloride 30g / L, boric acid 45g / l, dodecyl sulfonate sodium citrate 0.1g / l, sodium citrate 10g / l, o-benzoylsulfonimide 0.5g / l, propionic acid 0.2g / L; the electro...

Embodiment 2

[0022] A continuous casting roll crystallizer, including a roll core and a roll surface, the roll core is hollow, cooled by cooling water, the base material of the roll surface is a copper alloy, and the copper alloy is electroplated with a nickel coating, wherein the composition of the copper alloy is determined by mass The percentages are: Ni: 5%; Be: 0.05%; Al: 2%, Zr: 0.5%; Mn: 0.4%; Mg: 1%; Sn: 0.1%; the rest is Cu; 1.6mm; the electroplating process includes the following process steps:

[0023] 1) Pretreatment: cleaning the surface of the continuous casting crystal roll with organic solvent, alkali degreasing, electrolytic degreasing, acid etching and activation treatment;

[0024] 2) Electroplating metal nickel: The composition of the electroplating solution is: nickel sulfamate 220g / l, nickel sulfate 30g / l, nickel chloride 30g / l, tin chloride 20g / L, boric acid 55g / l, dodecyl sulfonate Sodium citrate 0.05g / l, sodium citrate 14g / l, o-benzoylsulfonimide 0.1g / l, propionic...

Embodiment 3

[0026] A continuous casting roll crystallizer, including a roll core and a roll surface, the roll core is hollow, cooled by cooling water, the base material of the roll surface is a copper alloy, and the copper alloy is electroplated with a nickel coating, wherein the composition of the copper alloy is determined by mass The percentages are: Ni: 4%; Be: 0.1%; Al: 1.5%, Zr: 0.8%; Mn: 0.3%; Mg: 2%; Sn: 0.08%; 1.2mm; the electroplating process includes the following process steps:

[0027] 1) Pretreatment: cleaning the surface of the continuous casting crystal roll with organic solvent, alkali degreasing, electrolytic degreasing, acid etching and activation treatment;

[0028] 2) Electroplating metal nickel: The composition of the electroplating solution is: nickel sulfamate 200g / l, nickel sulfate 40g / l, nickel chloride 25g / l, tin chloride 25g / L, boric acid 50g / l, dodecyl sulfonate Sodium citrate 0.08g / l, sodium citrate 12g / l, o-benzoylsulfonimide 0.3g / l, propionic acid 0.4g / L; ...

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Abstract

The invention discloses a continuous casting roller type crystallizer. Copper alloy is adopted as the base material of the roller surface and is electroplated with a nickel coating. The copper alloy is composed of, by weight, 3-5% of Ni, 0.05-0.2% of Be, 1-2% of Al, 0.5-1% of Zr, 0.2-0.4% of Mn, 1-3% of Mg, 0.05-0.1% of Sn and the balance Cu. The thickness of the electroplated nickel coating ranges from 0.8 mm to 1.6 mm. The electroplating technology comprises the steps of 1, pre-treating; 2, metallic nickel electroplating; electroplating solutions are composed of 180-220 g / l of nickel aminosulfonate, 30-50 g / l of nickel sulfate, 20-30 g / l of nickel chloride, 20-30 g / l of stannic chloride, 45-55 g / l of boric acid, 0.05-0.1 g / l of sodium dodecyl sulfate, 10-14 g / l of sodium citrate, 0.1-0.5 g / l of saccharin and 0.2-0.6 g / l of propionic acid; according to the conditions of the electroplating technology, the plating solution temperature ranges from 40 DEG C to 46 DEG C, pH ranges from 2.8 to 4.5, the initial current density ranges from 0.8 A / dm<2> to 1.6 A / dm<2>, the current density ranges from 2 A / dm<2> to 4 A / dm<2> in the normal electroplating process, the roller rotation speed ranges from 12 turns / min to 20 turns / min, and air agitation is adopted; metallic nickel electroplating is carried out until the thickness of the electroplated nickel coating ranges from 0.8 mm to 1.6 mm.

Description

technical field [0001] The invention relates to the technical field of electroplating, in particular to a continuous casting roller crystallizer. Background technique [0002] Thin strip continuous casting technology is a cutting-edge technology in the field of metallurgy and material research, which has changed the production process of thin steel in the traditional metallurgical industry. The thin strip continuous casting technology is adopted, which integrates continuous casting, rolling, and even heat treatment, so that the thin strip produced can be formed into industrial products at one time after a little cold rolling, which simplifies the production process and shortens the production cycle. Line length is only 60m. Its appearance is bringing a revolution to the steel industry. [0003] According to the different crystallizers, the thin strip continuous casting technology can be divided into belt type, roll type, roll belt type, etc. Among them, the twin-roll thin ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C9/06C25D3/12B22D11/06
CPCB22D11/0651C22C9/06C25D3/12
Inventor 张颖
Owner 陈玲婷