Repairing method of scrapped continuous casting crystallizer copper plate
A continuous casting mold and repair method technology, applied in electroforming, electrolysis process and other directions, can solve the problems of complex repair method steps, low thermal conductivity, energy waste, etc., and achieve strong sustainable development, excellent performance, and guaranteed products. quality effect
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Embodiment 1
[0053] A method for repairing copper plates of scrapped continuous casting crystallizers, comprising the following steps:
[0054] (1) Pretreatment: Degreasing, mechanical sandblasting, electrolytic degreasing, ultrasonic degreasing, and acid spray activation are performed on the mechanically processed copper plate base material to obtain the copper plate base material to be cast;
[0055] (2) Inject the electroforming solution: inject the electroforming solution into the electroforming tank, then use ammonia water and citric acid to adjust the pH to 9.0, and heat the electroforming solution to 30°C;
[0056] The composition of the electroforming solution is: copper pyrophosphate: 50g / L, potassium pyrophosphate: 460g / L, potassium nitrate: 12g / L, silver nitrate: 0.25g / L, sodium citrate: 12g / L, ammonia water: 15mL / L, 2-Mercaptobenzoimidazole: 0.005g / L, 2-Mercaptobenzothiazole: 0.02g / L;
[0057] (3) Electroforming: Put the base material of the copper-plated plate as the cathode ...
Embodiment 2
[0061] A method for repairing copper plates of scrapped continuous casting crystallizers, comprising the following steps:
[0062] (1) Pretreatment: Degreasing, mechanical sandblasting, electrolytic degreasing, ultrasonic degreasing, and acid spray activation are performed on the mechanically processed copper plate base material to obtain the copper plate base material to be cast;
[0063] (2) Inject the electroforming solution: inject the electroforming solution into the electroforming tank, then use ammonia water and citric acid to adjust the pH to 8.0, and heat the electroforming solution to 60°C;
[0064] The composition of the electroforming solution is: copper pyrophosphate: 130g / L, potassium pyrophosphate: 190g / L, potassium nitrate: 43g / L, silver nitrate: 0.03g / L, sodium citrate: 43g / L, ammonia water: 1mL / L, 2-Mercaptobenzoimidazole: 0.1g / L, 2-Mercaptobenzothiazole: 0.001g / L;
[0065] (3) Electroforming: Put the base material of the copper-plated plate as the cathode i...
Embodiment 3
[0069] A method for repairing copper plates of scrapped continuous casting crystallizers, comprising the following steps:
[0070] (1) Pretreatment: Degreasing, mechanical sandblasting, electrolytic degreasing, ultrasonic degreasing, and acid spray activation are performed on the mechanically processed copper plate base material to obtain the copper plate base material to be cast;
[0071] (2) Inject the electroforming solution: inject the electroforming solution into the electroforming tank, then use ammonia water and citric acid to adjust the pH to 8.8, and heat the electroforming solution to 35°C;
[0072] The composition of the electroforming solution is: copper pyrophosphate: 60g / L, potassium pyrophosphate: 400g / L, potassium nitrate: 18g / L, silver nitrate: 0.11g / L, sodium citrate: 36g / L, ammonia water: 3mL / L, 2-Mercaptobenzoimidazole: 0.020g / L, 2-Mercaptobenzothiazole: 0.017g / L;
[0073] (3) Electroforming: Put the base material of the copper-plated plate as the cathode ...
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