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Preparation method of high-solid content heavy-oil cleaning agent

A heavy oil stain cleaning agent with high solid content technology, applied in the field of cleaning agents, can solve the problems of flammability, high water content, high production cost, etc., and achieve the effect of improving the cleaning effect

Inactive Publication Date: 2016-08-10
大连和田科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, the patent application number: 200610013444.4 uses a highly toxic additive such as sodium nitrite, and the water content of the product is relatively high; another example is the patent application number: 201210353201.0, which uses a large amount of solvent oil, and the production cost is high , flammable

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Preparation of alcohol amine ether additive: mix 1 mole of monoethanolamine and 1 mole of propanol, then add sodium hydroxide and heat to reflux temperature, react for 10 hours, the weight of sodium hydroxide is 1% of the total weight of monoethanolamine and propanol , using a 300-mesh sieve to filter to obtain the alcohol amino ether additive; preparation of cleaning agent: Take 20 parts of alcohol amino ether into the stirring tank, stir and heat up to 50 ° C, then first add 3 parts of oxalic acid, after the oxalic acid is dissolved, add 3 parts of EDTA Sodium salt and 0.5 parts of sodium benzoate, after EDTA sodium salt and sodium benzoate are dissolved and dispersed, add 7 parts of a mixture of C8~10 alkyl glycosides and C12~14 alkyl glycosides, the weight ratio of the two is 40: 60, and stirred for 10 minutes, then added 8 parts of fatty alcohol polyoxyethylene ether sulfate, after dispersion, added 20 parts of the mixture of coconut oil fatty acid diethanolamide, f...

Embodiment 2

[0021] Preparation of alcohol amine ether additive: mix 1 mole of diethanolamine and 1.2 moles of ethanol, then add potassium hydroxide and heat to reflux temperature, react for 10 hours, the weight of potassium hydroxide is 2% of the total weight of diethanolamine and ethanol, use 300-mesh sieve to obtain the alcohol amine ether additive; preparation of cleaning agent: Take 10 parts of alcohol amine ether into the stirring tank, stir and heat up to 50°C, then add 1 part of citric acid first, and then add 5 parts of poly Epoxysuccinic acid and 1 part of sodium benzoate, after polyepoxysuccinic acid and sodium benzoate are dissolved and dispersed, add 5 parts of a mixture of C8~10 alkyl glycosides and C12~14 alkyl glycosides, the weight of the two The ratio is 50:50, and stir for 10 minutes, then add 5 parts of fatty alcohol polyoxyethylene ether sulfate, after dispersion, add the mixture of coconut oil fatty acid diethanolamide, fatty alcohol polyoxyethylene ether and nonylphen...

Embodiment 3

[0024] Preparation of alcoholamine ether additive: 1 mole of triethanolamine and 1.5 moles of n-butanol were mixed, then heated to reflux temperature after adding potassium hydroxide, reacted for 12 hours, and the weight of potassium hydroxide was 4% of the total weight of triethanolamine and n-butanol %, use a 300-mesh sieve to filter to obtain the alcohol amino ether additive; preparation of cleaning agent: take 30 parts of alcohol amino ether into the stirring tank, stir and heat up to 50°C, then add 5 parts of citric acid first, and add after the citric acid dissolves 2 parts of polyepoxysuccinic acid and 0.1 part of sodium benzoate, after the polyepoxysuccinic acid and sodium benzoate are dissolved and dispersed, add 10 parts of a mixture of C8~10 alkyl glycosides and C12~14 alkyl glycosides, two The weight ratio is 60:40, and stirred for 10 minutes, then add 10 parts of fatty alcohol polyoxyethylene ether sulfate, after dispersion, add coconut oil fatty acid diethanolamid...

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PUM

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Abstract

The invention discloses a preparation method of a high-solid content heavy-oil cleaning agent. The preparation method comprises the following steps: preparing an alcohol amine ether additive, namely mixing alcohol amine and alcohol in a ratio, wherein the molar ratio of the alcohol amine and alcohol is (1:1) to (1:1.5), then heating to reflux temperature after adding an alkali catalyst, reacting for 5 to 12 hours, and filtering by using a 300-mesh sieve to obtain the alcohol amine ether additive; preparing a cleaning agent, namely taking 5 to 30 parts of alcohol amine ether to be added into a stirring tank, stirring and heating to 50 DEG C, then adding 1 to 5 parts of organic carboxylic acid, adding 0.5 to 5 parts of chelating agents and 0.1 to 1 part of a sterilizing preservative after the organic carboxylic acid is dissolved, adding 5 to 10 parts of alkyl glycoside mixtures after the chelating agents and the sterilizing preservative are dissolved and dispersed, stirring for 10 minutes, then adding 5 to 10 parts of fatty alcohol polyoxyethylene ether sulfate, adding 10 to 30 parts of nonionic surfactant mixtures after the fatty alcohol polyoxyethylene ether sulfate is dispersed, and finally adding 0.5 to 5 parts of dispersion stabilizers. According to the invention, the water content of the cleaning agent is reduced, and the transportation cost of a product is lowered.

Description

technical field [0001] The invention relates to a cleaning agent, in particular to a preparation method of a cleaning agent for heavy oil stains with high solid content. Background technique [0002] After a period of operation of oil refining units and oil pipelines in petrochemical enterprises, a large amount of sludge, residual oil, Dirt such as catalyst dust, sulfur compounds and their mixtures. Traditional cleaning methods mainly include artificial high-pressure water jet cleaning and mechanical cleaning. However, these cleaning methods have disadvantages such as time-consuming, high power consumption, incomplete cleaning, and even equipment damage. Therefore, chemical cleaning technology is gradually replacing these traditional cleaning methods. [0003] However, there are still some problems in heavy oil cleaning for petrochemical enterprises. The main manifestations are as follows: First, for a single device or light crude oil system, chemical cleaning technology...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C11D1/83C11D3/30C11D3/20C11D3/48C11D3/33C11D3/37C11D3/34C11D3/60
CPCC11D1/83C11D1/29C11D1/66C11D1/662C11D1/721C11D3/00C11D3/2079C11D3/2082C11D3/2086C11D3/30C11D3/33C11D3/349C11D3/3707C11D3/48
Inventor 孙红旗王松夏琳
Owner 大连和田科技有限公司
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