Laser-marked PBT material with epoxy resin cohesiveness and preparation technology of laser-marked PBT material

A technology of laser marking and epoxy resin, which is applied in the field of polymer materials, can solve the problems of reduced packaging efficiency, difficulty in controlling the curing process of epoxy resin viscosity changes, etc., and achieve the effect of improving adhesion, good marking effect, and small dosage

Inactive Publication Date: 2016-08-31
BENGBU ZHENGYUAN ELECTRONICS TECH
View PDF5 Cites 4 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Chinese patent CN 104610711 B discloses a PBT material with good epoxy resin adhesion and its preparation method. The invention uses antioxidant 24-44, antioxidant 168, antioxidant 1010 and carbon free scavenger HP136 The compounding, through the synergistic effect of each component, makes the material have excellent anti-aging performance, introduces reactive functional groups that have the ability to react with epoxy resin, and improves the interfacial adhesion with epoxy resin, but when using epoxy resin Rapid viscosity changes make it difficult to control the curing process, and rapid curing results in reduced encapsulation efficiency

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Weighing: PBT 70 kg, cardanolamine 18 kg, polyvinyl alcohol microspheres 18 kg, sodium dodecyl sulfonate 6 kg, gelatin 6 kg, glass fiber 8 kg, silicone powder 2 kg, laser marking powder 4 kg, antioxidant 245 2 kg;

[0028] The laser marking powder is formed by mixing graphene, bismuth oxide and pearlescent powder, and its weight ratio is 2:1:1.

[0029] Specific steps are as follows:

[0030] (1), preparation of microcapsule curing agent:

[0031] ①. Under stirring conditions, add 0.5wt% gelatin aqueous solution and 0.5wt% sodium dodecylsulfonate aqueous solution, and disperse for 40 minutes under mechanical stirring at 800 rpm to obtain an aqueous phase;

[0032] 2. In the dichloromethane solvent, add cardanolamine and polyvinyl alcohol microspheres, and disperse evenly in an ultrasonic instrument to obtain an oil phase, and gradually add the water phase prepared in step 1 into the oil phase;

[0033] ③. Stir and emulsify the mixed solution for 60 minutes, raise the...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
tensile strengthaaaaaaaaaa
bending strengthaaaaaaaaaa
heat deflection temperatureaaaaaaaaaa
Login to view more

Abstract

The invention discloses a laser-marked PBT material with epoxy resin cohesiveness. The laser-marked PBT material is prepared from the following raw materials in parts by weight: 60-80 parts of PBT, 15-20 parts of cashew phenol amine, 15-20 parts of polyvinyl alcohol microspheres, 5-8 parts of sodium dodecyl sulfate, 5-10 parts of gelatin, 6-12 parts of glass fibers, 1-3 parts of silicone powder, 2-5 parts of laser marking powder and 1-3 parts of antioxidant 245. A coated curing agent is introduced to improve the content of a functional group which has reaction capacity with epoxy resin; meanwhile, a microcapsule curing agent can break a microcapsule under a certain condition to release slowly; and the curing behavior is finished, so that the target of controlling the potting adhesive curing process of the material and the epoxy resin is achieved; and the interface adhesion between the material and the epoxy resin is improved. Graphene is utilized; the laser marking powder is added; the dosage is small; the marking effect is good; and different laser-marked PBT materials can be prepared; and the laser-marked PBT material has relatively good mechanical property and meets the requirements of laser marking in the field of automotive electronics.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a laser-markable PBT material with epoxy resin adhesion and a preparation method thereof. Background technique [0002] Polybutylene terephthalate (English name Polybutylene Terephthalate, referred to as PBT) is milky white [0003] Color Translucent to opaque, crystalline thermoplastic polyester. It has excellent electrical properties, high heat resistance, toughness, fatigue resistance, self-lubrication, low coefficient of friction, weather resistance, low water absorption, and maintains various physical properties (including electrical properties) in a humid environment. Good, so it is widely used as engineering plastics in automobiles, electronic and electrical components. [0004] The engine ignition coil is the main component of the engine ignition system. Its function is to increase the low voltage of the car battery to a high voltage of 20kv to 40kv that can c...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08L89/00C08K13/06C08K9/10C08K7/14C08K3/04C08K5/17C08K3/22
CPCC08L67/02C08L2205/03C08L89/00C08K13/06C08K9/10C08K7/14C08K3/04C08K5/17C08K3/22
Inventor 夏云夏建生
Owner BENGBU ZHENGYUAN ELECTRONICS TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products