Touch oil and preparation method for touch membrane utilizing same
A tactile, polyether diol technology, applied in the direction of surface coating liquid devices, coatings, pre-treated surfaces, etc., can solve problems such as unfavorable construction, strong odor of organic solvents, etc., and achieve good crystallinity and yellowing resistance Improved denaturation and good recovery effects
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[0024] The present invention provides a kind of preparation method of tactile oil, comprises the following steps:
[0025] (1) Mix polyether diol and polyester diol uniformly at 100°C-105°C. The polyether diol includes polyoxypropylene diol and polytetrahydrofuran diol with an average molecular weight of 3000-4000 Alcohol, polyester diol is polycaprolactone diol with a molecular weight of 3500-4500, and the weight ratio of the three raw materials in the mixed diol is 10%-15% of polyoxypropylene diol, polytetrahydrofuran diol 5%-10%, polycaprolactone diol 75%-85%; vacuumize at 100℃-105℃ for 1-2 hours to remove the water in the mixed diol. Mixed use of three diols, both polyether type and polyester type, can make the crystallinity of the soft segment reach 35%-45%, and the glass transition temperature is 65°C-70°C, the soft segment has recoverability;
[0026] (2) Cool down to 85°C-90°C, add isophorone diisocyanate to react for 2-3 hours under nitrogen protection, the amount a...
Embodiment 1
[0048] Preparation of tactile oil:
[0049] (1) Mix polyoxypropylene diol, polytetrahydrofuran diol, and polycaprolactone diol evenly at 100°C, and the weight ratio of the three raw materials in the mixed diol is 10% of polyoxypropylene diol , polytetrahydrofuran diol 5%, polycaprolactone diol 85%; vacuumize at 100°C for 2 hours to remove the water in the mixed diol;
[0050] (2) Cool down to 85°C, add isophorone diisocyanate to react for 3 hours under nitrogen protection, the amount added is 45% of the weight of the mixed diol, cool down to 60°C, add hydrophilic chain extender 1,2 -sodium dihydroxy-3-propanesulfonate, crosslinking agent trimethylolpropane, catalyst stannous octoate reacted for 3 hours to obtain the water-based polyurethane prepolymer, and the add-on was respectively 3% of isophorone diisocyanate weight, 2%, 1%;
[0051] (3) Cool down to 20°C, add deionized water and disperse with a disperser to obtain a water-based polyurethane dispersion. The amount of dei...
Embodiment 2
[0058] Preparation of tactile oil:
[0059] (1) Mix polyoxypropylene diol, polytetrahydrofuran diol, and polycaprolactone diol evenly at 105°C, and the weight ratio of the three raw materials in the mixed diol is 15% of polyoxypropylene diol , polytetrahydrofuran diol 10%, polycaprolactone diol 75%; vacuumize at 105°C for 1 hour to remove the water in the mixed diol;
[0060] (2) Cool down to 90°C, add isophorone diisocyanate to react for 2 hours under nitrogen protection, the amount added is 30% of the weight of the mixed diol, cool down to 70°C, add hydrophilic chain extender 1,2 -sodium dihydroxy-3-propanesulfonate, cross-linking agent trimethylolpropane, catalyst stannous octoate reacted for 2 hours to obtain aqueous polyurethane prepolymer, and the add-on was respectively 4% of isophorone diisocyanate weight, 3%, 2%;
[0061] (3) Cool down to 30°C, add deionized water and disperse with a disperser to obtain a waterborne polyurethane dispersion. The amount of deionized w...
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