Environment-friendly waterborne polyester coating and preparation method thereof

A water-based polyester and coating technology, which is applied in polyurea/polyurethane coatings, antifouling/underwater coatings, fireproof coatings, etc., can solve the problem that the properties of rosin cannot be fully reflected, the characteristics of rosin cannot be fully utilized, and the properties of rosin cannot be significantly improved. Product performance and other issues, to achieve the effect of enhanced interaction, improved heat resistance, and good gloss

Inactive Publication Date: 2016-11-23
BENGBU ZHENGYUAN ELECTRONICS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As one of the important forestry biomass resources in my country, rosin has been studied by scholars to add it to the synthesis of polyurethane to improve the gloss and adhesion of polyurethane products, but they all directly add rosin to polyurethane, while Rosin is a mixture of various resin acids and its functionality is not high, so it cannot be added to the main chain of polyurethane, and the performance of the product cannot be significantly improved, and the characteristics of rosin cannot be fully utilized; rosi

Method used

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Embodiment Construction

[0019] A kind of environment-friendly water-based polyester paint, it is made up of the raw material of following weight portion:

[0020] Oxidized polyethylene wax 2, calcium aluminate 2, polybutylacrylate 0.7, rosin 35, fumaric acid 8, 20% sodium hydroxide solution 6, ethylene glycol 20, antimony trioxide 0.1, sodium polyacrylate 2, chlorine Zinc chloride 13, polyether diol 80, toluene diisocyanate 100, 2,2 dimethylol propionic acid 2, diethylene glycol 4, triethylamine 1, 2-mercaptobenzimidazole 0.2, sorbitan mono-oil Ester 0.1, Tetrabutylammonium Bromide 1, Alkanolamide 2, Zinc Ricinoleate 0.6.

[0021] A kind of preparation method of described environment-friendly water-based polyester paint, comprises the following steps;

[0022] (1) Add the above-mentioned oxidized polyethylene wax to 10 times its weight in absolute ethanol, put it into an oil bath at 120°C, keep warm and stir for 6 minutes, discharge, add rosin and zinc ricinoleate, and stir to room temperature, Eth...

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Abstract

The invention discloses an environment-friendly waterborne polyester coating. The environment-friendly waterborne polyester coating is prepared from, by weight, 2-3 parts of oxidized polyethylene wax, 2-4 parts of calcium aluminate, 0.7-1 part of poly(butyl acrylate), 35-40 parts of rosin, 8-10 parts of fumaric acid, 6-7 parts of a 20-30% sodium hydroxide solution, 20-34 parts of ethanediol, 0.1-0.2 part of antimonous oxide, 2-3 parts of sodium polyacrylate, 13-20 parts of zinc chloride, 80-90 parts of polyether glycol, 100-130 parts of toluene diisocynate, 2-3 parts of 2,2-dimethylolpropionic acid, 4-5 parts of diethylene glycol, 1-2 parts of triethylamine, 0.2-0.4 part of 2-mercaptobenzimidazole, 0.1-0.3 part of sorbitan monooleate, 1-2 parts of tetrabutylammonium bromide, 2-3 parts of alkylolamide and 0.6-1 part of zinc diricinoleate. The coating is free of toxicity and pollution, high in safety and environmental friendliness and excellent in overall performance.

Description

technical field [0001] The invention relates to the technical field of polyester coatings, in particular to an environmentally friendly water-based polyester coating and a preparation method thereof. Background technique [0002] At present, although the commonly used water-based polyurethane materials are widely used in coatings, adhesives and other industries due to their environmental friendliness, conventional water-based polyurethane materials still have shortcomings such as poor heat resistance, weather resistance, and poor antistatic properties, which affect In order to better improve the overall performance of water-based polyurethane coatings, overcome its own shortcomings such as poor water resistance and low solid content, and expand its application range, the modification of water-based polyurethane has become a major research topic in recent years. Hotspots, the depth and breadth of discussions have also been expanded. The modification of waterborne polyurethan...

Claims

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Application Information

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IPC IPC(8): C09D175/08C09D175/06C09D7/12C09D5/14C09F1/04C08G18/76C08G18/48C08G18/42C08G18/34
CPCC08G18/0823C08G18/12C08G18/4018C08G18/7614C08K2003/2296C08K2201/011C09D5/14C09D5/18C09D175/06C09D175/08C09F1/04C09D7/61C08G18/348C08G18/3206C08L33/02
Inventor 夏云夏建生
Owner BENGBU ZHENGYUAN ELECTRONICS TECH
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