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Electrowetting hydrophobic dielectric layer, preparation method thereof, and electrowetting device

A hydrophobic, electro-wetting technology, applied in instruments, optical components, optics, etc., can solve the problem that epoxy compounds cannot play a role, and achieve the effect of prolonging life, improving insulation, and increasing dielectric constant

Active Publication Date: 2017-01-04
SOUTH CHINA NORMAL UNIVERSITY +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For inorganic oxide particles, compounds containing epoxy groups can react with the oxygen polar bonds on the surface to achieve the purpose of modification, and make them participate in the polymerization of the crosslinking system, thereby improving compatibility and dispersion, but electrowetting Wet hydrophobic dielectric layer materials are usually fluoropolymers with saturated main chains and no reactive groups, epoxy-based compounds will not play a role

Method used

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  • Electrowetting hydrophobic dielectric layer, preparation method thereof, and electrowetting device
  • Electrowetting hydrophobic dielectric layer, preparation method thereof, and electrowetting device
  • Electrowetting hydrophobic dielectric layer, preparation method thereof, and electrowetting device

Examples

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Effect test

Embodiment 1

[0031] Put 1g of zirconia nanoparticles into a 50mL centrifuge tube, the particle size of the zirconia nanoparticles is 5-20nm, add 25mL of acetone, the amplitude of the ultrasonic breaker is 45%, and disperse for five minutes to ensure that the zirconia nanoparticles and acetone are mixed evenly. The supernatant was removed by centrifugation, and the process was repeated three times. Treat with absolute ethanol and deionized water for three times, and use deionized water to disperse with an ultrasonic breaker for the last treatment, remove the supernatant by centrifugation, and put the zirconia powder in the lower layer into a vacuum drying oven for vacuum drying at 60°C 12h. Connect the two-necked flasks to the argon gas and the vacuum pump respectively, and pass the argon gas in while evacuating. At the same time, heat the bottom of the flasks with an alcohol lamp. Repeat the above steps three times to remove the air and water in the two-necked flasks. ZrO 2 Add nanoparti...

Embodiment 2

[0035] Put 1g of titanium oxide nanoparticles into a 50mL centrifuge tube, the particle size of the titanium oxide nanoparticles is 5-20nm, add 25mL of acetone, the amplitude of the ultrasonic breaker is 45%, and disperse for five minutes to ensure that the titanium oxide nanoparticles and acetone are mixed evenly. The supernatant was removed by centrifugation, and the process was repeated three times. In the same way, use absolute ethanol and deionized water for three times. When using deionized water for the last time, use an ultrasonic breaker to disperse, centrifuge to remove the supernatant, and put the zirconia powder in the lower layer in a vacuum drying oven. Vacuum dried for 12h. Connect the two-necked flasks to the argon gas and the vacuum pump respectively, and pass the argon gas in while evacuating. At the same time, heat the bottom of the flasks with an alcohol lamp. Repeat the above steps three times to remove the air and water in the two-necked flasks. Take tit...

Embodiment 3

[0037] Put 0.8g of α-alumina nanoparticles into a 50mL centrifuge tube, add 25mL of acetone, and disperse for five minutes at the amplitude of the ultrasonic breaker at 45%, to ensure that the α-alumina nanoparticles and acetone are evenly mixed, centrifuge to remove the supernatant, and repeat the process three times. In the same way, use absolute ethanol and deionized water for three times. When using deionized water for the last time, use an ultrasonic breaker to disperse, centrifuge to remove the supernatant, and put the lower layer of α-alumina powder in a vacuum drying oven. Dry under vacuum for 12h. Connect the two-necked flasks to the argon gas and the vacuum pump respectively, and pass the argon gas in while evacuating. At the same time, heat the bottom of the flasks with an alcohol lamp. Repeat the above steps three times to remove the air and water in the two-necked flasks. Take 0.8gα-Al 2 o 3 Nanoparticles, 1H, 1H, 2H, 2H-perfluorooctyltrichlorosilane were added...

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Abstract

The invention discloses an electrowetting hydrophobic dielectric layer, a preparation method thereof, and an electrowetting device. The electrowetting hydrophobic dielectric layer contains a hydrophobic fluorine-containing high-molecular material doped with inorganic oxide particles subjected to surface fluorination. Through surface fluorination of the inorganic oxide particles, the inorganic oxide particle surfaces are improved in hydrophobicity, stability and compatibility with hydrophobic fluorine-containing polymers, so that the fluorinated inorganic oxide particles can be evenly dispersed in the fluorine-containing high-molecular material without agglomeration. The fluorine-containing polymers doped with the inorganic oxide particles subjected to surface fluorination are prepared into the hydrophobic dielectric layer. The wetting performance of the fluorine-containing polymers is not affected, and the dielectric constant of the hydrophobic dielectric layer can be substantially improved. The insulating performance of a conventional electrowetting hydrophobic dielectric layer can also be significantly enhanced. By applying the hydrophobic dielectric layer to an electrowetting display, the breakdown problem of hydrophobic dielectric layers under the effect of repeated electric field can be improved.

Description

technical field [0001] The invention relates to the technical field of electrowetting display, in particular to an electrowetting hydrophobic dielectric layer, a preparation method thereof and an electrowetting device. Background technique [0002] The principle of electrowetting technology is to use an electrode covered with an insulating layer as the substrate of a conductive liquid. During the electrification process, the contact angle of the droplet on the substrate can be greatly changed. Therefore, in electrowetting technology, there are two factors that cannot be ignored, namely the contact angle hysteresis and the dielectric failure of the insulating layer. Droplets are affected by contact angle hysteresis as they move across a surface, similar to static friction between objects moving from rest to sliding. Hysteresis hinders droplet morphology changes and negatively affects microfluidic actuation performance. Under the action of electrolyte environment and repeate...

Claims

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Application Information

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IPC IPC(8): G02B26/00C08L101/00C08L25/06C08K9/06C08K3/36C08K3/22
CPCC08K3/22C08K3/36C08K9/06C08K2003/2227C08K2003/2241C08K2003/2244C08K2201/011C08L25/06C08L101/00G02B26/005
Inventor 李皓侯嘉欣丁文文周国富
Owner SOUTH CHINA NORMAL UNIVERSITY
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