Drilling fluid for resisting heavy oil pollution

A drilling fluid and heavy oil technology, applied in the direction of drilling composition, chemical instruments and methods, etc., can solve the problems of funnel viscosity, shear force increase, loss of fluidity, drilling fluid slippage, etc., to reduce high temperature and high pressure filtration Loss, improve the purification ability, improve the effect of temperature resistance

Active Publication Date: 2017-01-11
中石化石油工程技术服务有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Heavy oil pollution problems are mainly manifested in: (1) The performance of drilling fluid deteriorates, the viscosity and shear force of the funnel increase suddenly, and even the fluidity is lost; (2) The screen cloth of the vibrating screen is blocked, causing the drilling fluid to run out of slurry and increasing the cost of drilling fluid; ( 3) Heavy oil forms a layer of oil film on the outer wall of the casing and the well wall, which affects the cementation of the cement slurry, the casing, and the formation, and affects the cementing construction, resulting in poor cementing quality
The existence of the above problems can easily lead to blockage of the annular space, induce complex situations such as blowout or leakage, and affect the safety of drilling construction
[0005] At present, crude oil is often used as a lubricant in on-site drilling operations. The content of crude oil in drilling fluid is generally 3% to 8%, which can form a stable emulsion. Rheology is difficult to control; conventional oil-in-water drilling fluids generally use light oil such as diesel oil or white oil as the oil phase in order to meet the purpose of safe drilling in low-pressure and leaky formations, with low density
"Drilling and Production Technology" No. 4, 2012, the article "Treatment Technology of Drilling Fluid Contaminated by Heavy Oil" introduces the methods of on-site treatment of drilling fluid invaded by heavy oil. Applicable when the speed is slow and the amount of intrusion is low; another method is the emulsification dispersion method, which uses up to 5% to 20% diesel oil to disperse the heavy oil and then emulsifies it. Due to the low density and large amount of diesel oil, this method will As a result, the density of the drilling fluid is further reduced, and the density of the drilling fluid needs to be adjusted frequently. There is a risk that the formation pressure cannot be balanced, causing wellbore instability, well kick or even blowout. cost of drilling
Therefore, the existing drilling fluids cannot well meet the requirements of dealing with heavy oil pollution during drilling operations in heavy oil reservoirs, and the drilling fluids are faced with the problem of maintaining good rheological properties while increasing the capacity limit of heavy oil

Method used

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  • Drilling fluid for resisting heavy oil pollution
  • Drilling fluid for resisting heavy oil pollution
  • Drilling fluid for resisting heavy oil pollution

Examples

Experimental program
Comparison scheme
Effect test

preparation example 1

[0020] Preparation of fluid loss additive A1: Mix 26.0 grams of 2-methyl-2-acryloyloxypropylsulfonic acid, 39.0 grams of acrylamide, 20.0 grams of acrylic acid and 2-hydroxy-3-methacryloyloxypropyltrimethyl 2.6 grams of ammonium chloride is formulated into an aqueous solution at room temperature, and the pH value of the aqueous solution is adjusted to 9.0 with sodium hydroxide, then 0.05 grams of ammonium persulfate and 0.05 grams of sodium bisulfite are added to initiate polymerization, and the initial temperature of the polymerization reaction is 20°C , the polymerization time is 5 minutes, and the product is granulated, dried and pulverized to obtain the fluid loss reducer A1, whose structural formula is as follows:

[0021]

preparation example 2

[0023] Preparation of fluid loss additive A2: Mix 56.0 grams of 2-methyl-2-acryloyloxypropylsulfonic acid, 28.0 grams of acrylamide, 10.0 grams of acrylic acid and 2-hydroxy-3-methacryloyloxypropyltrimethyl 2.8 grams of ammonium chloride is formulated into an aqueous solution at room temperature, and the pH value of the aqueous solution is adjusted to 11.0 with sodium hydroxide, then 0.2 grams of potassium persulfate and 0.2 grams of sodium thiosulfate are added to initiate polymerization, and the initial temperature of the polymerization reaction is 50°C , the polymerization time is 20 minutes, the product is granulated, dried and pulverized to obtain the fluid loss reducer A2, and its structural formula is as follows:

[0024]

Embodiment 1

[0026] Take 400 grams of clear water, add 16.0 grams of sodium-based bentonite and 0.8 grams of sodium carbonate to the clear water under high-speed stirring, stir for 20 minutes, and seal and maintain at room temperature for 24 hours to obtain the base slurry; take the above-mentioned base slurry, and add in sequence under high-speed stirring 2.8 grams of carboxymethyl cellulose sodium salt, 1.2 grams of low-viscosity polyanionic cellulose, 12.0 grams of fluid loss additive A, 8.0 grams of sulfonated phenolic resin, 8.0 grams of sulfonated lignite, stirred for 20 minutes; then added 80.0 grams of industrial salt gram, stirred at high speed to fully dissolve, then added 2.0 grams of emulsifier B, 2.0 grams of emulsifier C, and 35.0 grams of barite in turn, and then adjusted the pH value to 11 with sodium hydroxide, put it into an aging tank and aged it at 120 ° C and high temperature for 16 hours, the resulting density is 1.20g / cm 3 Anti-heavy oil pollution drilling fluid.

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Abstract

The invention relates to the technical field of drilling fluids used in petroleum drilling engineering, and particularly discloses a drilling fluid for resisting heavy oil pollution. The drilling fluid is prepared by mixing water, sodium bentonite, sodium carbonate, sodium carboxymethyl cellulose, low viscosity polyanionic cellulose, a filtrate loss reducer A, sulfonated phenolic resin, sulfonated lignite, industrial salt, an emulsifier B, an emulsifier C and barite, adjusting the pH value to 10 to 11 and aging at high temperature. The drilling fluid is prepared by reasonably compounding and synergistic effect of the above raw materials, can maintain good rheological properties, also increases significantly the capacity limitation of heavy oil, after the drilling fluid is polluted by 25% heavy oil, the drilling fluid still has good rheology and filtration loss property, the viscosity of the drilling fluid is effectively reduced, and the phenomenon of pasting a vibration sieve can be eliminated.

Description

technical field [0001] The invention relates to the technical field of drilling fluid for petroleum drilling engineering, in particular to a heavy oil pollution-resistant drilling fluid. Background technique [0002] As the recoverable reserves of conventional oil are decreasing, heavy oil (also known as heavy oil) has attracted more and more attention because of its resource potential several times higher than conventional oil resources, and is becoming an important substitute for global conventional oil resources. energy. According to relevant statistics, heavy oil accounts for more than 70% of the world's remaining oil resources, and there are 192 heavy oil-bearing basins, with original geological reserves of 4.9×10 11 t. Heavy oil and bitumen resources show the characteristics of concentrated distribution. At present, the proven heavy oil resources in the world are mainly concentrated in Venezuela, the former Soviet Union, the United States, Canada and other countries....

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/24
CPCC09K8/24
Inventor 马文英钟灵李保慧
Owner 中石化石油工程技术服务有限公司
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