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Thickened oil well polymer plugging remover

A technology of plugging remover and polymer, which is applied in the field of polymer plugging remover for heavy oil wells, can solve problems such as poor fluidity of blockages, reduced contact probability of blockages, strong corrosion of pipelines, etc., and achieves good plugging effect, Long shelf life and strong corrosion resistance

Active Publication Date: 2017-05-10
SOUTHWEST PETROLEUM UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in actual formations, most heavy oil wells have complicated causes of clogging, and most of the clogs are stable systems composed of high molecular polymers, oil scales, and inorganic scales in different proportions.
Especially for the blockage of heavy oil wells, on the one hand, the blockage and the heavy oil wrap each other, which makes the fluidity of the blockage poor and aggravates the blockage of the heavy oil well; on the other hand, the high viscosity of the heavy oil makes the injection The flow is difficult, the probability of contact with the blockage is greatly reduced, and the difficulty of degrading the blockage is increased, resulting in low efficiency or even ineffectiveness of the commonly used blockage removal measures such as a single strong oxidant
[0005] In addition, the currently commonly used strong oxidant blockage remover products are highly corrosive to pipelines and have poor stability. They are prone to lose activity after long-term storage, and the release rate of active components in the formation is not easy to control. There are certain safety hazards. Colloidal asphaltenes and other organic matter are not effective in removing plugs and are likely to cause secondary damage to the reservoir

Method used

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  • Thickened oil well polymer plugging remover
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  • Thickened oil well polymer plugging remover

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] The heavy oil well polymer blockage removal agent of this embodiment, calculated by mass percentage, includes the following components: gel breaker 1.5%, cleaning agent 2.5%, clay stabilizer 0.1%, iron ion stabilizer 1.0%, surfactant 1.0%, corrosion inhibitor 0.1%, fungicide 0.5% and the balance of water. Wherein, the breaker comprises 60% of breaker I and 40% of breaker II by mass percentage.

[0034] Specifically, the breaker I is ammonium persulfate, the breaker II is sodium periodate, the cleaning agent is tetrahydrofuran, the clay stabilizer is EDTA, the iron ion stabilizer is hydroxyethylidene diphosphoric acid, and the surfactant is α- Sodium alkenyl sulfonate, the corrosion inhibitor is cetyl pyridinium chloride, and the fungicide is sodium dichloroisocyanurate.

Embodiment 2

[0036] The heavy oil well polymer blockage removal agent of this embodiment, calculated by mass percentage, includes the following components: gel breaker 2.0%, cleaning agent 3.0%, clay stabilizer 1.5%, iron ion stabilizer 1.5%, surfactant 1.0%, corrosion inhibitor 1.0%, fungicide 1.0% and the balance of water. Wherein, the breaker includes 30% of breaker I and 70% of breaker II by mass percentage.

[0037] Specifically, the breaker I is potassium periodate, the breaker II is calcium peroxide, the cleaning agent is isopropanol, and the clay stabilizer is NH 4 Cl, the iron ion stabilizer is ethylenediamine tetramethylene phosphoric acid, the surfactant is fatty alcohol polyoxyethylene ether, the corrosion inhibitor is aldehyde ketone ammonium, and the bactericide is sodium trichloroisocyanurate.

Embodiment 3

[0039] The heavy oil oil well polymer plugging remover of this embodiment, calculated by mass percentage, includes the following components: gel breaker 2%, cleaning agent 4%, clay stabilizer 2.0%, iron ion stabilizer 2.0%, surfactant 1.5%, corrosion inhibitor 1.5%, fungicide 1.5% and the balance of water. Wherein, the breaker comprises 45% of breaker I and 55% of breaker II by mass percentage.

[0040] Specifically, the gel breaker I is potassium persulfate, the gel breaker II is potassium persulfate, the cleaning agent is 2-methyltetrahydrofuran, the clay stabilizer is tetramethylammonium chloride, and the iron ion stabilizer is hydroxyethylidene Diphosphoric acid, the surfactant is N-ethyl, N-hydroxyethyl perfluorooctane sulfonamide, the corrosion inhibitor is formamide, and the fungicide is sodium dichloroisocyanurate.

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Abstract

The invention discloses a thickened oil well polymer plugging remover. The plugging remover is prepared from the following materials in percentage by mass: 0.5 to 5.0 percent of gel breaker, 1.0 to 10.0 percent of cleaning agent, 0.1 to 5.0 percent of clay stabilizer, 0.1 to 5.0 percent of iron ion stabilizer, 0.1 to 5.0 percent of surfactant, 0.1 to 5.0 percent of corrosion inhibitor, 0.1 to 5.0 percent of bactericide and the balance of water, wherein the gel breaker is prepared from 30 to 70 percent of gel breaker I and 30 to 70 percent of gel breaker II, the gel breaker I is one or more of ammonium persulfate, sodium thiosulfate, potassium periodate and potassium monopersulfate, and the gel breaker II is one or more of calcium peroxide, potassium peroxodisulfate, sodium periodate and iron sulfide. The thickened oil well polymer plugging remover is suitable for solving the plugging problem caused by a thickened oil well polymer, has a better plugging removal effect than a conventional single oxidizer or single acid liquor, and has the advantages of good plugging removal effect, strong corrosion resistance, long period of validity, safety and the like.

Description

technical field [0001] The invention belongs to the technical field of oil well chemistry, and more specifically relates to a heavy oil oil well polymer plug-removing agent. Background technique [0002] Heavy oil well polymer refers to a class of additives used in the process of oil drilling, production and transportation, water quality treatment and enhanced oil recovery. However, with the continuous increase of polymer injection volume and the prolongation of injection time, heavy oil wells will be blocked. With the long-term accumulation of bottom hole plugs, most polymer injection wells have experienced a sharp increase in injection pressure and a sharp drop in water absorption index of oil layers. And other problems seriously affect the polymer flooding effect. In addition, heavy oil has poor fluidity in reservoirs and well bores, and is easy to wrap with plugs to form oil scale, which further aggravates the pollution near the wellbore and affects the production of he...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/524
CPCC09K8/524C09K2208/26C09K2208/32
Inventor 刘平礼张健刘长龙刘义刚李凤赵立强周薇李年银孟祥海邹剑罗志锋杜娟
Owner SOUTHWEST PETROLEUM UNIV
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