Easily-degradable anti-shrinkage polypropylene master batch and preparation method thereof
A polypropylene, anti-shrinkage technology, applied in the field of polypropylene masterbatch
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Embodiment 1
[0049] Embodiment 1 raw material preparation
[0050] 1. Preparation of calcium fruit fiber:
[0051] The preparation method of the calcium fruit fiber comprises the following steps: uniformly mixing fresh calcium fruit stems, calcium fruit leaves and waste sawdust at a mass ratio of 7:4:1.5, placing them in an ultrasonic cleaning machine at 200W and 30KHz for cleaning for 4 minutes, draining Drying, crushing, adding water with 1 times the amount of the crushed material, ultrasonic extraction at room temperature 300W, 40KHz for 12min, and then performing high-voltage pulse electric field treatment for 12min under the conditions of electric field strength 30kV / cm, pulse time 500μs, and pulse frequency 300Hz; adjust the pH value 8. Add biological enzyme with 0.2% mass of the mixture, and enzymatically hydrolyze at 55°C for 12 minutes; the enzymolyzed solution is concentrated under reduced pressure to a solid content of 50%, and placed in a microwave dryer at 2000W and 140°C for ...
Embodiment 2
[0073] An easily degradable, shrink-resistant polypropylene masterbatch, mainly prepared from the following raw materials in parts by weight:
[0074] 40 parts of polypropylene, 18 parts of calcium fruit fiber, 9 parts of polyethylene / winter rye peptide complex, 9 parts of modified nano-carbon, 2 parts of ultraviolet absorber, 2 parts of ethylene-methyl acrylate copolymer, 1 part of anti-aging agent 1 part, 1 part of tributyl citrate, 1 part of coupling agent, 0.8 part of bitter almond oil, 0.4 part of composite antioxidant;
[0075] Described composite antioxidant is that antioxidant 1010, antioxidant 168 and biological antioxidant are uniformly mixed by mass ratio 1.5:2:3;
[0076] The ultraviolet absorber is UV-531;
[0077] The ethylene-methyl acrylate copolymer uses American DuPont EMA1125AC.
[0078] The preparation method comprises the following steps: first, accurately weigh each raw material according to the formula, and according to the principle of the equal-incre...
Embodiment 3
[0080] An easily degradable, shrink-resistant polypropylene masterbatch, mainly prepared from the following raw materials in parts by weight:
[0081] 30 parts of polypropylene, 17 parts of calcium fruit fiber, 8 parts of polyethylene / winter rye peptide complex, 8 parts of modified nano-carbon, 1 part of ultraviolet absorber, 1.5 parts of ethylene-methyl acrylate copolymer, 0.8 parts of anti-aging agent part, 0.8 part of tributyl citrate, 0.8 part of coupling agent, 0.6 part of bitter almond oil, 0.3 part of composite antioxidant;
[0082] Described composite antioxidant is that antioxidant 1010, antioxidant 168 and biological antioxidant are uniformly mixed in a mass ratio of 1:1:2;
[0083] The ultraviolet absorber is UV-531;
[0084] The ethylene-methyl acrylate copolymer is preferably US DuPont EMA1125AC.
[0085] The preparation method comprises the following steps: first, accurately weigh each raw material according to the formula, and according to the principle of the...
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