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Low-emulsion-addition and high-scrubbing-resistance water-based interior wall emulsion and preparation thereof

A water-based emulsion, the technology of adding amount, applied in the direction of latex paint, coating, etc., can solve the problems of pollution, affecting flexibility, etc., and achieve the effect of uniform dispersion, improved scrub resistance and excellent scrub resistance

Inactive Publication Date: 2017-05-31
中山市巴德富化工科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, people's living environment needs to become safer, greener and healthier; when the existing acrylic emulsion is applied to water-based interior wall latex paint, the amount of acrylic resin contained in the lowest-grade latex paint generally The amount will not be lower than 8% of the whole latex paint; because the acrylate emulsion itself has the characteristics of hot stickiness and brittleness, when the amount of acrylic resin is increased, the temperature of the wall due to the direct sunlight in summer is as high as 50°C or even Higher, and the heat of the wall will definitely cause the resin in the coating to become soft and sticky, which will have a negative impact on the stain resistance of the coating; if you try to increase the surface hardness of the polymer particles to overcome its thermal stickiness It is cold and brittle and improves its scrub resistance. Due to the increase of coating hardness, it will eventually affect its flexibility and even become more brittle; although various additives can be introduced through the coating formulation to improve the composition of the coating in the later stage. Film performance or flexibility, but the introduction of additional or excessive additives will eventually produce more VOCs, which will bring pollution to the environment and human health problems; as far as the emulsion itself is concerned, the lower addition amount in the coating formulation It can reduce the emission of VOC and make the environment more environmentally friendly and safe; the second is based on weakening the influence of the hot-viscous, cold-brittle nature of the emulsion on the coating, making the coating more stain-resistant and has excellent scrub resistance

Method used

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  • Low-emulsion-addition and high-scrubbing-resistance water-based interior wall emulsion and preparation thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0038] a. Preparation of pre-emulsion: add 45% deionized water and 28% emulsifier, turn on the agitator, and turn on the agitator at 300 Hz, and drop in styrene, butyl acrylate, isooctyl acrylate, and alkyl carboxylic acid successively Cross-linking monomer, siloxane, organic oil and persulfate, continue stirring for 30 minutes;

[0039] b. Add the remaining deionized water and emulsifier into another reactor, stir evenly, and raise the temperature to 85°C; put in 20% pre-emulsion, and stir for 20 minutes;

[0040] c. Continuously and evenly drop the remaining pre-emulsion, keep the heat at 85-87°C, add dropwise for 4 hours, and keep warm for 30 minutes after the dropwise addition;

[0041] (2) Post-processing stage

[0042] a. Cool down to below 50°C;

[0043] b. After the temperature of the emulsion drops to room temperature, filter and pack.

Embodiment 1

[0045] Embodiment 1 a kind of acrylate emulsion

[0046] The acrylate emulsion is prepared from the following raw materials in parts by weight:

[0047] 25 parts of styrene, 8 parts of butyl acrylate, 8 parts of isooctyl acrylate, 2.5 parts of alkyl carboxylic acid crosslinking monomer, 1 part of siloxane, 1.5 parts of organic oil, 1.7 parts of emulsifier, 0.3 parts of persulfate With 52 parts of water;

[0048] Described alkyl carboxylic acid cross-linking monomer is 1 part of itaconic acid, 1.5 parts of acrylic acid;

[0049] Described siloxane is vinyltrimethoxysilane;

[0050] Described organic matter oil is epoxidized soybean oil;

[0051] Described emulsifier is 1.2 parts of sodium dodecyl diphenyl oxide disulfonate, 0.5 part of potassium lauryl polyoxyethylene ether sulfate;

[0052] Described persulfate is potassium persulfate;

[0053] The preparation method of the acrylate emulsion comprises the following steps:

[0054] (1) Synthesis stage

[0055] a. Prepara...

Embodiment 2

[0062] Embodiment 2 a kind of acrylate emulsion

[0063] The acrylate emulsion is prepared from the following raw materials in parts by weight:

[0064] 25 parts of styrene, 10 parts of butyl acrylate, 6.2 parts of isooctyl acrylate, 2.5 parts of alkyl carboxylic acid crosslinking monomer, 1.5 parts of siloxane, 1 part of organic oil, 1.5 parts of emulsifier, 0.3 parts of persulfate With 53 parts of water;

[0065] Described alkyl carboxylic acid cross-linking monomer is acrylic acid;

[0066] Described siloxane is vinyltriethoxysilane;

[0067] Described organic matter oil is tung oil;

[0068] Described emulsifier is potassium dodecyl diphenyl oxide disulfonate;

[0069] Described persulfate is ammonium persulfate;

[0070] Its preparation method is identical with embodiment 1.

[0071] Through the scrub resistance test, the latex paint with 6% emulsion addition amount prepared by the interior wall emulsion of the present invention can reach 2450 times of scrub resista...

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Abstract

The invention belongs to the field of latex coatings, and particularly relates to low-emulsion-addition and high-scrubbing-resistance water-based interior wall emulsion and preparation thereof. The water-based interior wall emulsion is prepared from the following raw materials in parts by weight: 10 to 25 parts of styrene, 5 to 20 parts of butyl acrylate, 5 to 20 parts of iso-octyl acrylate, 0.5 to 5 parts of an alkyl carboxylic acid cross-linking monomer, 0.5 to 5 parts of siloxane, 1 to 5 parts of organic matter oil, 1.0 to 2.5 parts of an emulsifier, 0.1 to 0.5 part of persulfate and 50 to 55 parts of water. The prepared emulsion has extremely high wetting, dispersing and wrapping capability for a pigment filler, so that a latex paint obtained under the condition of low emulsion addition is endowed with high scrubbing resistance.

Description

[0001] Technical field: [0002] The invention belongs to the field of latex coatings, in particular to a water-based emulsion for interior walls with low emulsion addition and high scrub resistance and its preparation. [0003] Background technique: [0004] With the improvement of people's living standards in the world today, the pursuit of human beings has already changed from the problem of food and clothing to the pursuit of spirit and even prolonging life. Simple architectural coatings or simple interior decoration are no longer enough to meet people's inner needs. Therefore, people's living environment needs to become safer, greener and healthier; when the existing acrylic emulsion is applied to water-based interior wall latex paint, the amount of acrylic resin contained in the lowest-grade latex paint generally The amount will not be lower than 8% of the whole latex paint; because the acrylate emulsion itself has the characteristics of hot stickiness and brittleness, wh...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F212/08C08F220/18C08F222/02C08F220/06C08F230/08C08F2/26C09D125/14C09D191/00C09D5/02C09D7/12
CPCC08F2/26C08F212/08C08L2205/025C08L2205/03C09D5/024C09D125/14C08L91/00C08F220/1804C08F220/1808C08F222/02C08F220/06C08F230/08
Inventor 彭妃湛张城平杜嘉俊邱南源方旭峥杨文涛
Owner 中山市巴德富化工科技有限公司
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