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Antibacterial polyethylene cable material unlikely to change color

A technology of polyethylene and polyvinyl chloride, which is applied in the direction of circuits, electrical components, plastic/resin/wax insulators, etc., can solve the problem of mechanical properties, tensile strength and elongation at break, which cannot meet the requirements of cable materials, and are easy to oxidize Problems such as discoloration and antibacterial ability, to achieve thermal stability and mechanical properties enhancement, high degree of peeling and dispersion, and good filling effect

Inactive Publication Date: 2017-06-06
安徽新立电缆材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Experiments have shown that polyethylene is easier to breed bacteria, and pure polyethylene materials can no longer meet the requirements of cable materials.
Silver-based antibacterial agents are the most commonly used antibacterial agents, but there are limitations in their application in polyethylene products: they are prone to oxidative discoloration and the antibacterial ability is reduced; mechanical properties, especially tensile strength and elongation at break, are greatly reduced, which greatly limits their use. Application in cable materials; and organic antibacterial agents also have poor heat resistance, precipitation in easy solvent environments, and toxic decomposition products

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] An antibacterial and non-discoloring polyethylene cable material proposed by the present invention, its raw materials include by weight: 15 parts of ethylene-vinyl acetate copolymer, 20 parts of polyvinyl chloride, 30 parts of polyethylene, 14 parts of apatite, barium metaborate 5 parts, barium titanate 9 parts, polyacrylonitrile-based carbon fiber 6 parts, modified clay 8 parts, disproportionated rosin 2 parts, chitosan polysaccharide 6 parts, dioctyl terephthalate 2 parts, microcrystalline paraffin 1.2 parts, 0.8 parts of dicumyl peroxide, 0.9 parts of p-phenylenediamine, 0.4 parts of dodecenyl succinic anhydride, 1 part of cerium oxide, 0.2 parts of lanthanum oxide, 1.2 parts of polyphenol antioxidant 1076, antistatic agent 1.5 servings.

Embodiment 2

[0017] An antibacterial and non-discoloring polyethylene cable material proposed by the present invention, its raw materials include by weight: 25 parts of ethylene-vinyl acetate copolymer, 10 parts of polyvinyl chloride, 40 parts of polyethylene, 6 parts of apatite, barium metaborate 11 parts, barium titanate 4 parts, polyacrylonitrile-based carbon fiber 12 parts, modified clay 2 parts, disproportionated rosin 4 parts, chitosan polysaccharide 2 parts, dioctyl terephthalate 4 parts, microcrystalline paraffin 0.8 parts, 1.6 parts of dicumyl peroxide, 0.3 parts of p-phenylenediamine, 0.8 parts of dodecenyl succinic anhydride, 0.5 parts of cerium oxide, 0.24 parts of lanthanum oxide, 0.6 parts of polyphenol antioxidant 1076, antistatic agent 2.5 servings.

[0018] The modified clay is prepared by the following process: mix water, absolute ethanol, and glacial acetic acid evenly, add dodecyltrimethoxysilane, heat up and stir to obtain pretreated dodecyltrimethoxysilane; mix clay a...

Embodiment 3

[0020] An antibacterial and non-discoloring polyethylene cable material proposed by the present invention, its raw materials include by weight: 18 parts of ethylene-vinyl acetate copolymer, 18 parts of polyvinyl chloride, 32 parts of polyethylene, 12 parts of apatite, barium metaborate 7 parts, barium titanate 8 parts, polyacrylonitrile-based carbon fiber 8 parts, modified clay 6 parts, disproportionated rosin 2.5 parts, chitosan polysaccharide 5 parts, dioctyl terephthalate 2.5 parts, microcrystalline paraffin 1.1 parts, 1 part of dicumyl peroxide, 0.7 parts of p-phenylenediamine, 0.5 parts of dodecenyl succinic anhydride, 0.8 parts of cerium oxide, 0.21 parts of lanthanum oxide, 1 part of polyphenol antioxidant 1076, antistatic agent 1.8 servings.

[0021] The modified clay is prepared by the following process: mix 35 parts of water, 40 parts of absolute ethanol, and 7 parts of glacial acetic acid in parts by weight, add 6 parts of dodecyltrimethoxysilane, heat up and stir t...

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PUM

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Abstract

The invention discloses an antibacterial polyethylene cable material unlikely to change color. The antibacterial polyethylene cable material unlikely to change color comprises the following raw materials in parts by weight: 15-25 parts of an ethylene-vinyl acetate copolymer, 10-20 parts of polyvinyl chloride, 30-40 parts of polyethylene, 6-14 parts of apatite, 5-11 parts of barium metaborate, 4-9 parts of barium titanate, 6-12 parts of polyacrylonitrile-based carbon fibers, 2-8 parts of modified clay, 2-4 parts of disproportionated rosin, 2-6 parts of deacetylated chitosan polysaccharide, 2-4 parts of dioctyl terephthalate, 0.8-1.2 parts of microcrystalline wax, 0.8-1.6 parts of dicumyl peroxide, 0.3-0.9 part of p-phenylenediamine, 0.4-0.8 part of dodeceny succinicanhydride, 0.5-1 part of cerium oxide, 0.2-0.24 part of lanthanum oxide, 0.6-1.2 parts of a polyphenol antioxidant 1076 and 1.5-2.5 parts of an antistatic agent.

Description

technical field [0001] The invention relates to the technical field of plastics, in particular to an antibacterial non-discoloration polyethylene cable material. Background technique [0002] Polyethylene is the most widely used general-purpose plastic and is widely used in the field of cable materials. Experiments have shown that polyethylene is relatively easy to breed bacteria, and pure polyethylene materials can no longer meet the requirements of cable materials. Silver-based antibacterial agents are the most commonly used antibacterial agents, but there are limitations in their application in polyethylene products: they are prone to oxidative discoloration and the antibacterial ability is reduced; mechanical properties, especially tensile strength and elongation at break, are greatly reduced, which greatly limits their use. Application on cable materials; and organic antibacterial agents also have poor heat resistance, precipitation in easy solvent environment, and tox...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L23/08C08L27/06C08L93/04C08L5/08C08L91/06C08K13/06C08K3/34C08K7/06C08K3/24C08K5/14C08K5/18C08K5/12H01B3/44
CPCC08L23/06C08K2201/011C08L2201/08C08L2203/202C08L2205/035H01B3/441C08L23/0853C08L27/06C08L93/04C08L5/08C08L91/06C08K13/06C08K3/346C08K7/06C08K3/24C08K5/14C08K5/18C08K5/12
Inventor 唐亮
Owner 安徽新立电缆材料有限公司
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