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Fracturing fluid composition for delayed crosslinking in an ultrahigh temperature environment

A technology of delayed cross-linking and composition, applied in drilling compositions, chemical instruments and methods, etc., can solve the problems of non-delayed gel formation, poor operation safety, poor sand-carrying ability of fracturing fluid, etc. Construction cost and effect of reducing formation damage

Active Publication Date: 2017-06-20
北京清水兰德油田技术服务有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although organic acid esters of high-valent metal ions as crosslinking agents can theoretically meet the thermal stability requirements of the formation environment at temperatures above 180°C, the existing high-temperature fracturing fluids have insufficient temperature resistance, no delay in gel formation, and chemical agents Large amount of fracturing fluid and other problems, resulting in poor sand-carrying capacity of fracturing fluid, poor operation safety, complex equipment and high construction costs
In particular, due to the structural defects of the existing cross-linking agent, the metal ions in the cross-linking agent are released intensively in the early stage, and the metal ions cannot be released synchronously with the change of the well-entering environment, so that the fracturing fluid is transported to the bottom formation. Cross-linking has already formed before, making the pumping pressure increase

Method used

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  • Fracturing fluid composition for delayed crosslinking in an ultrahigh temperature environment
  • Fracturing fluid composition for delayed crosslinking in an ultrahigh temperature environment
  • Fracturing fluid composition for delayed crosslinking in an ultrahigh temperature environment

Examples

Experimental program
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Effect test

Embodiment 1

[0033]Dissolve 3.6 grams of carboxymethylhydroxypropyl guar gum WGA-5 in 1000ml of water, add 0.002 grams of bactericide BioClear-1000, and let it stand for 2 hours to form a base liquid; at room temperature, add 1g of quaternary ammonium salt-type clay stabilizer ClayTreat -3C, 1g of 50% glutaraldehyde aqueous solution, 0.5g of sodium carbonate, and 1g of NE-940 are stirred and dissolved, take 400ml of base liquid in a Warring mixer, start stirring, and add 0.4g of delayed cross-linking agent ZXL -LTD (the weight ratio of tetra-n-butyl zirconate, glyoxal, glycerol and polyethylene polyamine is 1:3:2.5:3.5, add water to form a homogeneous phase and then heat the reaction, the reaction temperature is 85 ° C, the reaction time 6 hours; Wherein, polyethylene polyamine mixture is the mixture of ethylenediamine, triethylenetetramine and pentaethylenehexamine, and its mixing ratio is mass parts 1:2:1.5), and record vortex closing time is 125 seconds, becomes The glue is uniform, and...

Embodiment 2

[0035] Dissolve 4.2 grams of carboxymethylhydroxypropyl guar gum WGA-5 in 1000ml of water, add 0.002 grams of fungicide BioClear-1000, and let it stand for 2 hours to form a base liquid; at room temperature, add 1g of quaternary ammonium salt-type clay stabilizer ClayMaster -5C, 0.5g 25% potassium hydroxide solution, 1g FlowGas stirring and dissolving, take 400ml of base liquid in the Warring mixer, start stirring, add 2.0g delayed crosslinking agent (triisopropyl chromium (III) The weight ratio of acid ester, glyoxal, glycerin and polyvinyl polyamine is 1:2:4:2.5, add water to form a homogeneous phase and then heat the reaction, the reaction temperature is 140°C, and the reaction time is 3 hours; among them, polyethylene The polyamine mixture is a mixture of ethylenediamine and tetraethylenepentamine, the mixing ratio is 1:2 by mass), the recorded vortex closing time is 267 seconds, the gel is uniform, and it can be hung after 11 minutes of vortex closing. Take 45 grams of th...

Embodiment 3

[0037] Dissolve 4.8 grams of carboxymethylhydroxypropyl squash gum CGA-7 in 1000ml of water, add 0.002 grams of bactericide BioClear-1000, and let it stand for 2 hours to form a base solution; at room temperature, add 0.5 grams of tetramethylammonium chloride, 1 g of 50% glutaraldehyde aqueous solution, 0.5 g of 25% potassium hydroxide solution, 1 gram of NE-118 and 2 g delayed crosslinking regulator CTD (ie: 50% sorbitol aqueous solution). After stirring and dissolving, take 400ml of base liquid in a Warring mixer, start stirring, add 0.8g of delayed crosslinking agent TXL-LTD (tetra-n-butyl titanate, glyoxal, glycerin and polyethylene polyamine) The weight ratio is 1:4:3:2, add water to form a homogeneous phase and then heat the reaction, the reaction temperature is 85°C, and the reaction time is 6 hours; among them, the polyethylene polyamine is pentaethylene hexamine), and the recorded vortex closure time is 573 seconds, the gel is uniform, and it can be hung after 12 minu...

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Abstract

The invention discloses a fracturing fluid composition for delayed crosslinking in an ultrahigh temperature environment. The fracturing fluid composition comprises a plant gum thickener, a delayed crosslinking agent, a fracturing aid and water, wherein the delayed crosslinking agent is obtained through a reaction of raw materials comprising a trivalent or more metal ester compound, glyoxal, glycerol and polyethylene polyamine. The fracturing fluid composition can form a stable, uniform and sagging fracturing fluid jelly, and the crosslinking and jelly formation time of the fracturing fluid can be delayed, and the delay time can be controlled in the range of 3-10 min. The viscosity of jelly obtained by a delayed crosslinking system at 180 DEG C or above is 100 mPas or above. The polymer use amount and the crosslinking agent use amount of the fracturing fluid composition are significantly lower than those of conventional high temperature fracturing fluid systems, so the formation damage of the fracturing fluid is greatly reduced, and the construction cost is greatly reduced.

Description

technical field [0001] The invention relates to a fracturing fluid composition, in particular to a fracturing fluid composition capable of delaying crosslinking in an ultra-high temperature environment. Background technique [0002] With the world's increasing demand for energy and the advancement of exploration technology, the exploration and development of oil and gas resources continues to develop in depth, and more and more major exploration target layers are showing a trend of comprehensive sinking. The number of abnormally high-temperature deep wells with well depths greater than 4500 m and temperatures exceeding 170 °C is increasing. The high temperature and high pressure in deep formations have brought many difficulties to oil and gas formation stimulation. [0003] A series of problems such as the lack of high-temperature-resistant fracturing fluids suitable for temperatures above 180 °C, and the incompatibility of fracturing design theory and technology for ultra-h...

Claims

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Application Information

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IPC IPC(8): C09K8/68
CPCC09K8/605C09K8/608C09K8/685C09K8/885C09K8/887C09K8/90C09K2208/12C09K2208/26
Inventor 范淼王勃张方凯刘晟化京衡
Owner 北京清水兰德油田技术服务有限公司
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