Method for sintering belite-calcium sulphoaluminate-calcium sulphosilicate cement at low temperature and product thereof
A calcium sulfoaluminate, low-temperature firing technology, applied in the field of materials, can solve the problems of complex process, short holding time, and low calcination temperature of sulfur-containing calcium silicate cement, so as to reduce the initial cost, increase the environmental pressure, and increase the calcination temperature. low effect
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Embodiment 1
[0024] The ratio of raw materials and water consumption designed in this embodiment are as shown in Table 2.
[0025] Table 2 Embodiment 1 raw material ratio and water consumption
[0026] Example 1 coal gangue Tailings bauxite Desulfurization gypsum sugar filter mud water Mass / g 203.6 118.4 65.4 612.6 373
[0027] The specific implementation steps are as follows:
[0028] 1) Mixing: Weigh the raw materials according to the ratio and place them in a planetary mill, add water, grind for 15 minutes, take out the slurry and pour it into the mold, demould after molding, and obtain a block sample;
[0029] 2) Hydrothermal synthesis: put the above sample in a digital display constant temperature stirring circulation curing box that has been heated to a set temperature of 60°C, take it out and cool it after constant temperature curing for 9 hours;
[0030] 3) Calcination: After the cooled block sample is crushed, it is placed in a high-temperature ...
Embodiment 2
[0035] The ratio of raw materials and water consumption designed in this embodiment are as shown in Table 4.
[0036] Table 4 embodiment 2 raw material ratio and water consumption
[0037] Example 2 Pile residual slurry Tailings bauxite Phosphogypsum Carbide slag water Mass / g 538.4 205.1 69.2 187.3 150
[0038] The specific implementation steps are as follows:
[0039] 1) Mixing: Weigh the raw materials according to the ratio and place them in a planetary mill, add water, grind for 15 minutes, take out the slurry and pour it into the mold, demould after molding, and obtain a block sample;
[0040] 2) Calcination: Place the block sample in a high-temperature furnace, calcinate at 750°C for 80 minutes, take it out for rapid cooling, and grind it with a ball mill until the specific surface area is 370m 2 / kg to get Belite-calcium sulfoaluminate-calcium sulfosilicate cement.
[0041] The measured properties of the cement are shown in Table 5. ...
Embodiment 3
[0045] The ratio of raw materials and water consumption designed in this embodiment are as shown in Table 6.
[0046] Table 6 embodiment 3 raw material ratio and water consumption
[0047]
[0048]
[0049] The specific implementation steps are as follows:
[0050] 1) Mixing: Weigh the raw materials according to the proportion and place them in the planetary mill, add water, grind for 20 minutes, take out the slurry and pour it into the mold, demould after molding, and obtain a block sample;
[0051]2) Hydrothermal synthesis: Place the above sample in an autoclave that has been heated to a set temperature of 130°C, and take it out to cool after constant temperature curing for 4.5 hours;
[0052] 3) Calcination: After the cooled block sample is crushed, it is placed in a high-temperature furnace, calcined at 1050°C for 120 minutes, taken out for rapid cooling, and ground by a ball mill until the specific surface area is 390m 2 / kg to get Belite-calcium sulfoaluminate-ca...
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