Heat-resisting flame-retardant plastic film and preparation method thereof

A plastic film, heat-resistant technology, applied in the field of plastic film, can solve the problems affecting the popularization of heat insulation film technology, high cost of tin oxide coating, obstacles of heat insulation film, etc., and achieves simple and controllable preparation method, excellent mechanical properties, The effect of improving adhesion

Inactive Publication Date: 2017-09-19
HEFEI WANZHIJING DOORS & WINDOWS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As a general-purpose material, polypropylene is widely used for its small specific gravity, easy processing, corrosion resistance, non-toxicity and excellent comprehensive performance. Now most polypropylene films have the problem of flammability
In addition, forming a permanent heat-insulating film on the door and window glass can certainly have the desired effect when it is necessary to prevent strong light from raising the room temperature too much, but in seasons or periods that need to be conducive to sunlight to increase the room temperature, the existence of the heat-insulating film Instead, it became an obstacle
At this stage, the cost of directly sputtering tin oxide coating on the glass plate is still relatively high, which affects the promotion of thermal insulation film technology to a certain extent.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A kind of heat-resistant flame-retardant plastic film, polypropylene resin 66g, polyvinyl alcohol 15g, potato starch 6g, nano silicon dioxide 12g, bis-tert-butylperoxycumene 3g, polycarbonate 8g, carboxymethyl fiber Plain sodium 3g, inorganic flame retardant molybdenum disulfide 0.5g, plasticizer dioctyl phthalate 5g, styrene-butadiene thermoplastic elastomer 2g, heat stabilizer zinc stearate 0.16g.

[0023] The preparation method of the above-mentioned heat-resistant and flame-retardant plastic film comprises the following steps:

[0024] (1) Weigh polypropylene resin, polyvinyl alcohol, starch, bis-tert-butylperoxycumene, and polycarbonate according to weight, add them to the autoclave, and fill them with 1-2MPa nitrogen to maintain pressure. Stir and react at ~100°C for 1 to 2 hours, after cooling to room temperature, take out the milled powder to obtain the modified polypropylene resin;

[0025] (2) Weigh nano-silica, polycarbonate, sodium carboxymethyl cellulose, ...

Embodiment 2

[0027] A kind of heat-resistant flame-retardant plastic film, comprises the raw material of following weight: 68g of polypropylene resin, 12g of polyvinyl alcohol, 6g of cornstarch, 12g of nano silicon dioxide, 2g of bis-tert-butylperoxycumene, polycarbonate 7g, sodium carboxymethylcellulose 2g, inorganic flame retardant antimony trioxide 0.3g, plasticizer dibutyl phthalate 3g, styrene-butadiene thermoplastic elastomer 2g, heat stabilizer ricinoleic acid Calcium 0.15g.

[0028] The preparation method of the above-mentioned heat-resistant and flame-retardant plastic film comprises the following steps:

[0029] (1) Weigh polypropylene resin, polyvinyl alcohol, starch, bis-tert-butylperoxycumene, and polycarbonate according to weight, add them to the autoclave, and fill them with 1-2MPa nitrogen to maintain pressure. Stir and react at ~100°C for 1 to 2 hours, after cooling to room temperature, take out the milled powder to obtain the modified polypropylene resin;

[0030] (2) W...

Embodiment 3

[0032] A heat-resistant and flame-retardant plastic film, comprising the following raw materials: 70g polypropylene resin, 15g polyvinyl alcohol, 6g wheat starch, 14g nano silicon dioxide, 3g bis-tert-butylperoxycumene, polycarbonate 8g, sodium carboxymethylcellulose 3g, inorganic flame retardant aluminum hydroxide 0.5g, plasticizer dibutyl phthalate 3g, styrene-butadiene thermoplastic elastomer 4g, heat stabilizer zinc stearate 0.22g.

[0033] The preparation method of the above-mentioned heat-resistant and flame-retardant plastic film comprises the following steps:

[0034] (1) Weigh polypropylene resin, polyvinyl alcohol, starch, bis-tert-butylperoxycumene, and polycarbonate according to weight, add them to the autoclave, and fill them with 1-2MPa nitrogen to maintain pressure. Stir and react at ~100°C for 1 to 2 hours, after cooling to room temperature, take out the milled powder to obtain the modified polypropylene resin;

[0035] (2) Weigh nano-silica, polycarbonate, s...

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PUM

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Abstract

The invention discloses a heat-resisting flame-retardant plastic film and a preparation method thereof. The plastic film comprises the following raw materials in parts by weight: 60-80 parts of polypropylene resin, 10-20 parts of polyvinyl alcohol, 3-8 parts of starch, 8-15 parts of nanometer silicon dioxide, 1-5 parts of bis(tert-butyldioxyisopropyl) benzene, 5-10 parts of polycarbonate, 1-5 parts of sodium carboxymethylcellulose, 0.2-0.6 part of an inorganic flame retardant, 3-6 parts of a plasticizer, 1-5 parts of a styrene-butadiene thermoplastic elastomer and 0.06-0.28 part of a thermal stabilizer. The preparation method comprises the steps of modifying polypropylene resin, mixing materials and reacting. The components of the plastic film disclosed by the invention are safe and nontoxic; the preparation method is simple and controllable; the plastic film has excellent heat resistance, flame resistance and weather fastness; and the plastic is light in weight and has excellent mechanical properties, such as, chemical substance resistance, impact strength and tearing strength.

Description

technical field [0001] The invention relates to the technical field of plastic films, in particular to a heat-resistant and flame-retardant plastic film and a preparation method thereof. Background technique [0002] At present, with the development of the economy, plastics have been widely used in industry and life. China's plastic film industry is in a stage of vigorous development. Moreover, with the continuous emergence of various new materials, new equipment and new processes, China's plastic films will be developed in the direction of diversified, specialized and multifunctional composite films. As a general-purpose material, polypropylene is widely used due to its small specific gravity, easy processing, corrosion resistance, non-toxicity and excellent comprehensive performance. Most polypropylene films now have the problem of flammability. In addition, forming a permanent heat-insulating film on the door and window glass can certainly have the desired effect when i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L29/04C08L3/02C08L69/00C08K13/02C08K3/36C08K5/14C08K5/12C08K3/30C08K3/22
CPCC08L23/12C08J5/18C08J2323/12C08J2429/04C08K2003/2224C08K2003/2227C08K2003/3009C08K2201/011C08L2201/02C08L2201/08C08L2203/16C08L2205/035C08L2312/00C08L29/04C08L3/02C08L69/00C08K13/02C08K3/36C08K5/14C08K5/12C08K3/30C08K3/22C08K3/2279
Inventor 武娟
Owner HEFEI WANZHIJING DOORS & WINDOWS CO LTD
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