Method for increasing dyeing depth of para-aramid fibers and fabrics

A technology for dyeing para-aramid fibers and fabrics. It is applied in the direction of dyeing, textiles and papermaking. It can solve the problems of deep color, insufficient color fastness, high dyeing temperature, and easy occurrence of color flowers, so as to improve the dyeing effect, Expand the scope of application and improve the effect of dyeing depth

Inactive Publication Date: 2017-09-29
SINOPEC YIZHENG CHEM FIBER +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

According to the reported para-aramid dyeing technology, the fiber is generally pretreated by acid / alkali, and part of the method is to add a carrier and dye it through high temperature and high pressure. The dyeing temperature is as high as 160-180 ° C. The existing dyeing and finishing equipment cannot Realized, so the existing technology is still basically in the laboratory stage, and has not realized the application of industrialization, and the para-aramid fiber and fabric dyeing, the color of the dyed product is relatively light, and the darker color cannot be obtained, and the phenomenon of color flower is prone to appear , the color depth and color fastness are not enough, and there is no mention of whether the dyeing technology will corrode the dyeing and finishing equipment and cause environmental hazards

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Example 1: Plasma treatment or ultrasonic treatment of para-aramid short fibers using argon and oxygen mixed gas (or nitrogen, air is the same), take 5 g of para-aramid short fibers obtained by mechanical processing, and add Pretreatment agent 8g / L compounded by sodium hydroxide (concentration 5g / L) and scouring agent (concentration 4g / L), soft water 100mL (bath ratio 1:20), heated at 80°C for 20min, and then washed with water Removes surface oils. The degreased fiber is treated with high frequency by ultrasonic processor. Take by weighing Disperse Red A2 dyestuff 0.15g (dyeing concentration 3%) in beaker, add 75mL soft water (bath ratio 1:30), add by Cindy DNK (concentration 20g / L), fatty alcohol polyoxyethylene ether sodium sulfate (concentration 5g / L), sodium chloride (concentration 10g / L), 2.5g of dyeing auxiliaries, stirred and heated to about 60°C to disperse and mix the dyes and dyeing auxiliaries evenly, then adjust the pH with acetic acid / sodium acetate buffer...

Embodiment 2

[0027] Embodiment 2: get para-aramid filament 5g, add the pretreatment agent 8g / L compounded by sodium carbonate (concentration 8g / L) and scouring agent (concentration 5g / L) in Erlenmeyer flask, soft water 50mL (bath Ratio 1:10), heated at 90°C for 15 minutes, then washed with water to remove surface oil. And carry out high-speed agitation and cleaning in a washer with stirring for 10 minutes. Take by weighing Disperse Red A9 dyestuff 0.125g (dyeing concentration 2.5%) in beaker, add 80mL (bath ratio 1:16) (soft water, add by Cindy DNK (concentration 40g / L), fatty alcohol polyoxyethylene ether sodium sulfate ( Concentration 8g / L), sodium chloride (concentration 20g / L) compound dyeing auxiliaries 30g / L, stir and heat to about 60°C to disperse and mix the dyes and dyeing auxiliaries evenly, then use acetic acid / sodium acetate buffer solution Adjust the pH value to 4, and pour the prepared dye solution into the dyeing cup. Take the treated para-aramid fiber and put it into the d...

Embodiment 3

[0028]Embodiment 3: Get 5g of para-aramid filaments, and add preform compounded by sodium hydroxide (concentration 3g / L), sodium carbonate (concentration 3g / L) and scouring agent (concentration 5g / L) in the Erlenmeyer flask Treating agent 6g / L, soft water 70mL (bath ratio 1:14), heat at 90°C for 15min, then wash with water to remove surface oil. And wash it in a high-frequency ultrasonic cleaner for 20 minutes. Weigh 0.15 g of disperse blue B1 dye (dyeing concentration 3%) in a beaker, add 90 mL soft water (bath ratio 1:16), add HPS-301 (concentration 30 g / L), fatty alcohol polyoxyethylene ether sodium phosphate ( Concentration 8g / L), sodium sulfate (concentration 10g / L) compound dyeing auxiliaries 60g / L, stir and heat to about 60°C to disperse and mix the dyes and dyeing auxiliaries evenly, then adjust with acetic acid-sodium acetate buffer solution When the pH value is 3, pour the prepared dye solution into the dye cup. Take the treated fiber and put it into the dyeing cup...

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Abstract

The invention discloses a method for increasing the dyeing depth of para-aramid fibers and fabrics. A mechanical method is utilized to pretreat para-aramid, so that the fiber surfaces of the para-aramid are roughened, or regulated by a processing process, the internal structures of fibers are improved, so that the surface density of the fibers is decreased, and thereby a fibrillated or air hole-like structure is formed; after pretreatment agent is applied to carry out surface deoiling treatment on the treated para-aramid, screened dye is adopted, a high-temperature and high-pressure dyeing process is adopted, a dyeing auxiliary which is prepared from dyeing carrier, surfactant, electrolyte and the like is added in the process of dyeing to dye the para-aramid 1414 fibers and fabric, and after flood removal, washing and drying, required color and dyeing depth can be achieved. When the dyeing method disclosed by the invention is applied to dye para-aramid 1414 fibers and fabric, the degree of dyeing reaches more than 80 percent, the color depth value K / S can reach more than 16, the color fastness to rubbing of dyeing reaches level 3-4, and the color fastness to staining reaches level 4-5. After the process of dyeing the para-aramid 1414 fibers and fabric, the strength drop is less than 15 percent.

Description

technical field [0001] The invention relates to the field of dyeing of synthetic fiber materials, in particular to a para-aramid fiber dyeing method. Background technique [0002] Para-aramid fiber is poly-p-phenylene terephthalamide fiber (PPTA), which is one of the main varieties of aromatic polyamide fiber. Due to its comprehensive performance, it is widely used in protection, aerospace, high-strength ropes, high-temperature filtration, composite materials and other fields. With the continuous expansion of production capacity, more and more para-aramid fibers are used in protective clothing, gloves, sporting goods and other products, including high-temperature protective clothing, firefighting clothing, military uniforms, racing suits, space suits, etc. In addition to high-strength, flame-retardant, and temperature-resistant protective functions, clothing and gloves also need to meet the needs of warning, beauty, and easy identification through color. Therefore, there is...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06P3/04D06P5/20D06P1/16D06P1/673D06P1/613
CPCD06P1/0032D06P1/16D06P1/6133D06P1/6735D06P1/67358D06P3/043D06P5/2005D06P5/2011
Inventor 韩春艳廉志军陈建梅和超伟季轩周琼戴钧明
Owner SINOPEC YIZHENG CHEM FIBER
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