Method for preparing wastewater heavy metal adsorbing material by using ionothermal system
An adsorption material and ion heat technology, applied in chemical instruments and methods, adsorption water/sewage treatment, water pollutants, etc., can solve the problems of low synthesis yield and high synthesis cost of zeolite molecular sieves, and the reaction is also easy to control and produce. Low cost and good hole forming effect
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Embodiment 1
[0032] The 2-methylimidazole and bromoethane were mixed in a 2:1 ratio, put into a three-necked beaker and stirred, and the three-necked beaker was heated and evaporated at 80° C. for 5 hours to obtain a bromide ionic liquid. Urea and choline chloride are mixed uniformly according to 3:1, and the solid mixture is melted by heating at 80°C to obtain a eutectic solvent. The bromide ionic liquid, the eutectic solvent, aluminum nitrate, and sodium silicate are mixed according to a ratio of 0.5:1.5:2:3, and stirred at 90° C. to make them uniformly mixed to obtain a homogeneous mixture. Put the homogeneous mixture in a reaction kettle with a polytetrafluoroethylene lining, and then put it in an oven, the temperature of the oven is 120°C, take it out after 72 hours of reaction, and then rapidly cool under the protection of nitrogen, then filter, and then Wash with distilled water and wash 4-6 times to pH=7-7.5, and then dry it to obtain a primary solid. The primary solid is added to ...
Embodiment 2
[0034] The 2-methylimidazole and bromoethane were mixed in a 2:1 ratio, put into a three-necked beaker and stirred, and the three-necked beaker was heated and evaporated at 80° C. for 6 hours to obtain a bromide ionic liquid. Urea and choline chloride are mixed uniformly according to 3:1, and the solid mixture is melted by heating at 80°C to obtain a eutectic solvent. The bromide ionic liquid, the eutectic solvent, aluminum nitrate, and sodium silicate are mixed in a ratio of 0.7:2:3:4, and stirred at 90° C. to make them uniformly mixed to obtain a uniform mixture. Put the homogeneous mixture in a reaction kettle with a polytetrafluoroethylene lining, and then put it into an oven, the temperature of the oven is 130°C, take it out after 72 hours of reaction, and then rapidly cool under the protection of nitrogen, then filter, and then Wash with distilled water and wash 4-6 times to pH=7-7.5, and then dry it to obtain a primary solid. The primary solid is added to the solution c...
Embodiment 3
[0036] The 2-methylimidazole and bromoethane were mixed in a 2:1 ratio, put into a three-necked beaker and stirred, and the three-necked beaker was heated and evaporated at 80° C. for 7 hours to obtain a bromide ionic liquid. Urea and choline chloride are mixed uniformly according to 3:1, and the solid mixture is melted by heating at 80°C to obtain a eutectic solvent. The bromide ionic liquid, the eutectic solvent, aluminum nitrate, and sodium silicate are mixed in a ratio of 1:3:4:5, and stirred at 90° C. to make them uniformly mixed to obtain a homogeneous mixture. Put the homogeneous mixture in a reaction kettle with a polytetrafluoroethylene lining, and then put it in an oven, the temperature of the oven is 140°C, take it out after 72 hours of reaction, and then rapidly cool under the protection of nitrogen, then filter, and then Wash with distilled water and wash 4-6 times to pH=7-7.5, and then dry it to obtain a primary solid. The primary solid is added to the solution c...
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