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Flame-retardant heat-resistant polyurethane adhesive

A polyurethane adhesive, heat-resistant technology, applied in the direction of adhesive additives, polymer adhesive additives, non-polymer adhesive additives, etc., can solve the problems of poor heat resistance and flame retardancy, and limit polyurethane adhesive The use of adhesives and other issues can be achieved to reduce water absorption, excellent mechanical properties, and enhance strength

Inactive Publication Date: 2017-12-26
安徽大松树脂有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the existing polyurethane adhesives have poor heat resistance and flame retardancy, which seriously limits the use of polyurethane adhesives in some special fields.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A flame-retardant heat-resistant polyurethane adhesive proposed by the present invention, its raw materials include: 70 parts of poly(1,4-butylene adipate) by weight, poly(1,5-pentanediol carbonate) 10 parts of diol, 15 parts of bis-ferrocenyl alcohol, 50 parts of isophorone diisocyanate, 10 parts of sucrose, 3 parts of chain extender, 12 parts of 1-aminoethylidene-1,1-diphosphonic acid, seaweed Calcium acid fiber 1 part, walnut shell powder 8 parts, polyimide 1 part, amino silicone oil 5 parts, epoxy resin 2 parts, aldehyde ketone resin 10 parts, attapulgite 3 parts, nano-alumina 15 parts, 1, 2 parts of 2-dimethylolcarborane, 80 parts of solvent, and 0.1 part of antioxidant.

Embodiment 2

[0020] A kind of flame-retardant and heat-resistant polyurethane adhesive proposed by the present invention, its raw material comprises by weight: 45 parts of poly(1,4-butylene adipate), poly(1,5-pentanediol carbonate) 35 parts of diol, 8 parts of bis-ferrocenyl alcohol, 70 parts of isophorone diisocyanate, 2 parts of sucrose, 15 parts of chain extender, 3 parts of 1-aminoethylidene-1,1-diphosphonic acid, seaweed 8 parts of calcium acid calcium fiber, 2 parts of walnut shell powder, 5 parts of polyimide, 1 part of amino silicone oil, 5 parts of epoxy resin, 2 parts of aldehyde and ketone resin, 9 parts of attapulgite, 3 parts of nano-alumina, 1, 10 parts of 2-dimethylolcarborane, 30 parts of solvent, and 0.8 parts of antioxidant.

Embodiment 3

[0022] A flame-retardant heat-resistant polyurethane adhesive proposed by the present invention, its raw materials include: 67 parts of poly(1,4-butylene adipate) by weight, poly(1,5-pentanediol carbonate) 19 parts of diol, 13 parts of bis-ferrocenyl alcohol, 55 parts of isophorone diisocyanate, 9 parts of sucrose, 7 parts of triethanolamine, 10 parts of 1-aminoethylidene-1,1-diphosphonic acid, alginic acid 3 parts of calcium fiber, 6 parts of walnut shell powder, 2.8 parts of polyimide, 4.2 parts of amino silicone oil, 3 parts of epoxy resin, 8 parts of aldehyde and ketone resin, 4.5 parts of attapulgite, 12 parts of nano-alumina, 1,2 - 4 parts of dimethylolcarborane, 73 parts of acetone, 0.2 part of hindered phenol antioxidant;

[0023] Wherein, the attapulgite is γ-aminopropyltriethoxysilane modified attapulgite;

[0024] The nano-alumina is modified nano-alumina; the modified nano-alumina is prepared according to the following process: add phenol and paraformaldehyde to t...

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PUM

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Abstract

The invention discloses a flame-retardant heat-resistant polyurethane adhesive. The flame-retardant heat-resistant polyurethane adhesive comprises the following raw materials in parts by weight: 45-70 parts of poly(1,4-butylene adipate), 10-35 parts of poly(1,5-glutaryl carbonate)diol, 8-15 parts of biferrocenyl alcohol, 50-70 parts of isophorone diisocyanate, 2-10 parts of sucrose, 3-15 parts of a chain extender, 3-12 parts of 1-aminoethylidene-1,1-diphosphonic acid, 1-8 parts of calcium alginate fiber, 2-8 parts of walnut shell powder, 1-5 parts of polyimide, 1-5 parts of amino silicone oil, 2-5 parts of epoxy resin, 2-10 parts of aldehyde ketone resin, 3-9 parts of attapulgite, 3-15 parts of nano alumina, 2-10 parts of 1,2-dimethylol carborane, 30-80 parts of a solvent, and 0.1-0.8 part of an antioxidant. The flame-retardant heat-resistant polyurethane adhesive provided by the invention has excellent heat resistance and flame retardancy, high curing speed and high adhesive strength with a substrate.

Description

technical field [0001] The invention relates to the technical field of adhesives, in particular to a flame-retardant and heat-resistant polyurethane adhesive. Background technique [0002] Adhesive refers to a natural or synthetic, organic or inorganic substance that can connect two or more parts or materials together through the adhesion and cohesion of the interface. It can be divided into epoxy resin adhesives, polyurethane adhesives, polyvinyl acetate adhesives, etc. [0003] Polyurethane adhesives refer to adhesives containing carbamate groups or isocyanate groups in the molecular chain, and its molecules contain isocyanate and carbamate groups with strong polarity and high chemical activity. Porous materials such as wood, leather, fabric, paper, ceramics, and materials with smooth surfaces such as metal, glass, rubber, plastics, etc. all have excellent chemical adhesion, and have good toughness, adjustability, and low temperature resistance. Has been widely used in f...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J175/06C09J11/08C09J11/06C09J11/04C08G18/66C08G18/42C08G18/44C08G18/32
CPCC09J175/06C08G18/3212C08G18/3218C08G18/4202C08G18/4238C08G18/44C08G18/6651C08G18/6655C08G18/6659C08K2003/2227C08K2201/011C08K2201/014C08L2201/02C08L2201/08C08L2205/035C08L2205/16C09J11/04C09J11/06C09J11/08C08L5/04C08L79/08C08L63/00C08L61/02C08L83/08C08K13/06C08K9/06C08K3/22C08K9/04C08K3/346C08K5/5317C08K5/55
Inventor 朱立芳
Owner 安徽大松树脂有限公司
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