Flame-retardant heat-resistant polyurethane adhesive
A polyurethane adhesive, heat-resistant technology, applied in the direction of adhesive additives, polymer adhesive additives, non-polymer adhesive additives, etc., can solve the problems of poor heat resistance and flame retardancy, and limit polyurethane adhesive The use of adhesives and other issues can be achieved to reduce water absorption, excellent mechanical properties, and enhance strength
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Embodiment 1
[0018] A flame-retardant heat-resistant polyurethane adhesive proposed by the present invention, its raw materials include: 70 parts of poly(1,4-butylene adipate) by weight, poly(1,5-pentanediol carbonate) 10 parts of diol, 15 parts of bis-ferrocenyl alcohol, 50 parts of isophorone diisocyanate, 10 parts of sucrose, 3 parts of chain extender, 12 parts of 1-aminoethylidene-1,1-diphosphonic acid, seaweed Calcium acid fiber 1 part, walnut shell powder 8 parts, polyimide 1 part, amino silicone oil 5 parts, epoxy resin 2 parts, aldehyde ketone resin 10 parts, attapulgite 3 parts, nano-alumina 15 parts, 1, 2 parts of 2-dimethylolcarborane, 80 parts of solvent, and 0.1 part of antioxidant.
Embodiment 2
[0020] A kind of flame-retardant and heat-resistant polyurethane adhesive proposed by the present invention, its raw material comprises by weight: 45 parts of poly(1,4-butylene adipate), poly(1,5-pentanediol carbonate) 35 parts of diol, 8 parts of bis-ferrocenyl alcohol, 70 parts of isophorone diisocyanate, 2 parts of sucrose, 15 parts of chain extender, 3 parts of 1-aminoethylidene-1,1-diphosphonic acid, seaweed 8 parts of calcium acid calcium fiber, 2 parts of walnut shell powder, 5 parts of polyimide, 1 part of amino silicone oil, 5 parts of epoxy resin, 2 parts of aldehyde and ketone resin, 9 parts of attapulgite, 3 parts of nano-alumina, 1, 10 parts of 2-dimethylolcarborane, 30 parts of solvent, and 0.8 parts of antioxidant.
Embodiment 3
[0022] A flame-retardant heat-resistant polyurethane adhesive proposed by the present invention, its raw materials include: 67 parts of poly(1,4-butylene adipate) by weight, poly(1,5-pentanediol carbonate) 19 parts of diol, 13 parts of bis-ferrocenyl alcohol, 55 parts of isophorone diisocyanate, 9 parts of sucrose, 7 parts of triethanolamine, 10 parts of 1-aminoethylidene-1,1-diphosphonic acid, alginic acid 3 parts of calcium fiber, 6 parts of walnut shell powder, 2.8 parts of polyimide, 4.2 parts of amino silicone oil, 3 parts of epoxy resin, 8 parts of aldehyde and ketone resin, 4.5 parts of attapulgite, 12 parts of nano-alumina, 1,2 - 4 parts of dimethylolcarborane, 73 parts of acetone, 0.2 part of hindered phenol antioxidant;
[0023] Wherein, the attapulgite is γ-aminopropyltriethoxysilane modified attapulgite;
[0024] The nano-alumina is modified nano-alumina; the modified nano-alumina is prepared according to the following process: add phenol and paraformaldehyde to t...
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