A method for preparing ternary molybdenum-based nitride nanomaterials
A nanomaterial and nitride technology, which is applied in the field of nanomaterials, can solve the problems of low purity of ternary molybdenum nitrides, and achieve the effects of simple and easy-to-control reaction process, wide source of raw materials and low price.
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0036]Add 5mmol metal molybdenum powder, 10mmol ferric oxide and 80mmol sodium azide into a 20ml stainless steel autoclave, seal it and put it into an electric furnace capable of temperature programming, and the furnace temperature rises from room temperature to 800°C, then maintained at 800°C for 5 hours and then cooled to room temperature naturally. The final product in the autoclave consisted of black deposits and residual gas. Collect the black sediment stuck on the inner surface of the kettle wall, wash it with distilled water and absolute ethanol several times, filter the sample obtained, and dry the sample in a vacuum drying oven at 50°C for 4 hours, and finally collect it for characterization .
[0037] The phase analysis of the powder was carried out by a Japanese Rigaku D / max-γA X-ray powder diffraction (XRD) instrument, Cu Kα Graphite monochromator, tube voltage and current are 40kV and 20mA, scanning speed 10.0° min -1 . figure 1 It is the X-ray diffraction sp...
Embodiment 2
[0039] Add 5mmol metal molybdenum powder, 10mmol cobalt chloride and 80mmol sodium azide into a 20ml stainless steel autoclave, seal it and put it into an electric furnace capable of temperature programming, and the furnace temperature rises from room temperature to 800 within 80 minutes °C, and then maintained at 800 °C for 5 hours and then cooled to room temperature naturally. The final product in the autoclave consisted of black deposits and residual gas. Collect the black sediment stuck on the inner surface of the kettle wall, wash it with distilled water and absolute ethanol several times, filter the sample obtained, and dry the sample in a vacuum drying oven at 50°C for 4 hours, and finally collect it for characterization .
[0040] Figure 5 It is the X-ray diffraction spectrogram of the product prepared in Example 2. Depend on Figure 5 It can be seen that in the X-ray diffraction spectrum, 2θ has all diffraction peaks at 10-80o, among which the diffraction intensi...
Embodiment 3
[0042] Add 5mmol metal molybdenum powder, 10mmol nickel chloride and 80mmol sodium azide into a 20ml stainless steel autoclave, seal it and put it into an electric furnace capable of temperature programming, and the furnace temperature rises from room temperature to 800 within 80 minutes °C, and then maintained at 800 °C for 5 hours and then cooled to room temperature naturally. The final product in the autoclave consisted of black deposits and residual gas. Collect the black sediment stuck on the inner surface of the kettle wall, wash it with distilled water and absolute ethanol several times, and filter the sample obtained, and dry the sample in a vacuum drying oven at 50°C for 4 hours, and finally collect it for characterization .
[0043] Figure 10 For the X-ray diffraction spectrum of the product prepared in embodiment 3, all diffraction peaks in the figure can be marked as the ternary nitride Ni of cubic phase 2 Mo 3 N No other impurity peaks appeared. The morpho...
PUM
| Property | Measurement | Unit |
|---|---|---|
| size | aaaaa | aaaaa |
| size | aaaaa | aaaaa |
| size | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to View More