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A kind of organosilicon super-weather-resistant anti-cracking anti-corrosion coating

An anti-corrosion coating and silicone technology, applied in anti-corrosion coatings, coatings, etc., can solve problems such as strong corrosion, coating cracks, environmental pollution, etc., and achieve the effects of convenient and safe construction, excellent weather resistance, and no environmental pollution.

Active Publication Date: 2019-08-02
江西凌志防腐科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Ordinary alkyd, acrylic and epoxy anti-corrosion coatings have a small linear expansion coefficient, which will inevitably lead to cracks in the coating under the long-term thermal expansion and contraction of the base material, and the cracking of the coating will lead to the failure of the anti-corrosion effect
[0003] There are many forms of coating failure, but the failure mode of cracking and peeling will cause the coating to completely lose its protective effect on the substrate
Although there have been patent reports for the preparation of anti-cracking coatings containing isocyanates and their modified resins, due to the strong toxicity, low boiling point, and strong corrosion of isocyanates, there are likely to be safety hazards in the process of coating preparation and construction. Hidden dangers, serious environmental pollution and great harm

Method used

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  • A kind of organosilicon super-weather-resistant anti-cracking anti-corrosion coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] An organosilicon super-weather-resistant anti-cracking anti-corrosion coating, its raw materials are composed of: organosilicon elastic resin: 100 parts, surface-treated fumed silica powder: 10 parts, surface-treated rutile TiO 2 : 15 parts, zinc phosphate: 10 parts, aluminum tripolyphosphate: 15 parts, precipitated barium sulfate: 5 parts, mica powder: 5 parts, talcum powder: 2 parts, glass fiber: 10 parts, hydroxy silicone oil: 15 parts, pigment (Iron red pigment): 1 part, crosslinking agent (methyl tributyl ketoxime silane): 3 parts, coupling agent (γ-aminopropyl triethoxysilane): 0.5 part, catalyst (dilauric dibutyltin acid): 0.05 parts.

[0037] The silicone elastic resin is formed by copolymerization of low-viscosity α, ω-dihydroxypolydimethylsiloxane, diphenyldihydroxysilane and orthosilicate with a viscosity below 5000cs. The low-viscosity α, ω- The molar ratio of dihydroxypolydimethylsiloxane, diphenyldihydroxysilane and ethyl orthosilicate is 5:1:2, using iso...

Embodiment 2

[0042] A kind of organosilicon super-weather-resistant anti-cracking anti-corrosion coating, its raw material is composed of: organosilicon elastic resin: 100 parts, surface-treated fumed silica powder: 15 parts, surface-treated rutile TiO 2 : 10 parts, zinc phosphate: 15 parts, aluminum tripolyphosphate: 12 parts, precipitated barium sulfate: 4 parts, mica powder: 8 parts, talcum powder: 4 parts, glass fiber: 7 parts, hydroxy silicone oil: 18 parts, pigment (Carbon black pigment): 6 parts, crosslinking agent (3 parts of methyl tributylketoxime silane + 4 parts of phenyl tributylketoxime silane): 7 parts, coupling agent (γ-glycidyl ether oxygen Propyltrimethoxysilane): 1.5 parts, catalyst (dioctyltin dilaurate): 0.07 parts.

[0043] The silicone elastic resin is formed by copolymerization of low-viscosity α, ω-dihydroxypolydimethylsiloxane, diphenyldihydroxysilane and orthosilicate with a viscosity below 5000cs. The low-viscosity α, ω- The molar ratio of dihydroxypolydimethyl...

Embodiment 3

[0048] A kind of organosilicon super-weather-resistant anti-cracking anti-corrosion coating, its raw material is composed of: organosilicon elastic resin: 100 parts, surface-treated fumed silica powder: 20 parts, surface-treated rutile TiO 2 : 5 parts, zinc phosphate: 20 parts, aluminum tripolyphosphate: 10 parts, precipitated barium sulfate: 3 parts, mica powder: 10 parts, talc powder: 5 parts, glass fiber: 5 parts, hydroxy silicone oil: 20 parts, pigment (cobalt blue pigment): 10 parts, crosslinking agent (3 parts of tetrabutylketoxime silane + 7 parts of phenyl tributylketoxime silane): 10 parts, coupling agent (γ-glycidyl ether oxypropyl 1 part of trimethoxysilane+1 part of γ-methacryloxypropyltrimethoxysilane): 2 parts, catalyst (dibutyltin diacetate): 0.1 part.

[0049] The silicone elastic resin is formed by copolymerization of low-viscosity α, ω-dihydroxypolydimethylsiloxane, diphenyldihydroxysilane and orthosilicate with a viscosity below 5000cs. The low-viscosity α, ...

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Abstract

The invention discloses an organic silicon-containing super-weather-resistant type anti-cracking and anti-corrosion coating, which is prepared from the following raw materials: 100 parts of organic silicon elastic resin, 10-20 parts of fumed silica powder subjected to surface treatment, 5-15 parts of rutile type TiO2 subjected to surface treatment, 10-20 parts of zinc phosphate, 10-15 parts of aluminum tripolyphosphate, 3-5 parts of precipitated barium sulphate, 5-10 parts of mica powder, 2-5 parts of talcum powder, 5-10 parts of glass fibers, 15-20 parts of hydroxyl silicone oil, 1-10 parts of pigment, 3-10 parts of a crosslinking reaction agent, 0.5-2 parts of a coupling agent and 0.05-0.1 part of a catalyst. The super-weather-resistant type anti-cracking and anti-corrosion coating not only has excellent weather resistance so as to be long in service life, but also has good elasticity so as to overcome the coating cracking behavior caused by thermal expansion and cold contraction deformation of a metal base material under temperature gradient; furthermore, the coating also has excellent corrosion resistance, hydrophobicity and environmental friendliness.

Description

technical field [0001] The invention relates to the technical field of production of architectural anticorrosion coatings, in particular to an organosilicon super-weather-resistant anti-cracking anticorrosion coating. Background technique [0002] In terms of metal corrosion protection, the use of anti-corrosion coatings has always been one of the most economical and effective means in modern industry. In recent years, as the use environment of steel structures has become more and more harsh, strong acid-base environment, high salt spray environment, high temperature difference environment and high humidity environment have all put forward severe tests on the use effect and life of traditional anti-corrosion coatings. Especially in high latitudes and coastal areas, where the temperature difference between day and night and the four seasons are large, the steel structure will continue to expand and recover under the repeated temperature gradient, which will cause the anti-cor...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D183/06C09D5/08C09D7/62C09D7/61
Inventor 陈世龙樊波张春晖张宝华张举明陈倩倩丁晓林王香娣柳时允
Owner 江西凌志防腐科技有限公司
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