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Graphene composite PP fibers and preparation method thereof

A graphene composite, graphene technology, applied in the direction of melt spinning, single-component polyolefin rayon, etc., can solve the problems of polymer performance, poor toughness at fiber agglomeration, unable to improve fiber performance, etc. Good electrostatic performance

Inactive Publication Date: 2018-02-27
SHAOXING BIAODIAN TEXTILE TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there will be the following problems in its specific application. One is the dispersion of the added inorganic fillers. Different sizes of inorganic fillers have a more obvious effect on the performance of polymers. Generally, the smaller the particle size (inorganic fillers), the better the performance of polymers. However, if the filler is too small, there will be a problem of agglomeration, and once the inorganic filler is agglomerated in the fiber, the toughness of the fiber agglomeration will be extremely poor; the second is the control of the amount of inorganic filler added, if the addition is too small, the fiber cannot be improved The performance of the fiber; adding too much will affect the performance of the fiber itself; how to effectively add inorganic fillers to effectively improve the comprehensive performance of the fiber is a research hotspot

Method used

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preparation example Construction

[0037] A preparation method of graphene composite PP fiber, comprising the following steps: step 1, heating and melting half of the PP (polypropylene) composite masterbatch to obtain a composite masterbatch melt; step 2, dissolving PP in a solvent, adding anion Stir and disperse evenly after the surfactant; Step 3, add the solution obtained in Step 2 dropwise to the composite masterbatch solution under stirring; Step 4, Extrude the solution obtained in Step 3 and stretch it into silk, Obtain PP wire; step 5, melt another composite masterbatch to obtain a composite masterbatch solution, pass the PP wire through the composite masterbatch solution at a uniform speed, and obtain PP wire coated with a composite masterbatch, and the diameter of the PP wire is 0.001-1mm , preferably 0.5-0.6mm; the speed at which PP wire passes through the composite masterbatch suspension is 0.1-1m / s, preferably 0.4-0.8m / s; step 6, rolling the PP wire obtained in step 5 into a ball, And re-melting, an...

Embodiment 1

[0040] A kind of graphene composite PP fiber, comprises each material of following weight portion:

[0041] Composite masterbatch 25 parts

[0042] PP 90 parts

[0043] Polyethylene glycol 40 parts

[0044] KH550 5 parts.

[0045] Wherein, a kind of composite masterbatch, comprises each material of following parts by weight:

[0046] Graphene 10 parts

[0047] Sodium polyacrylate 10 parts

[0048] 1 part fatty amine salt

[0049] Aluminum oxide 15 parts

[0050] 1 part microcrystalline cellulose

[0051] 10 parts ethanol or acetone

[0052] Silicone 1 part

[0053] 1 plant polyphenol,

[0054] Wherein, the graphene is 3 layers of graphene.

Embodiment 2

[0056] A kind of graphene composite PP fiber, comprises each material of following weight portion:

[0057] Composite masterbatch 10 parts

[0058] PP 90 parts

[0059] Methanol 30 parts

[0060] Sodium fatty alcohol sulfate 2 parts.

[0061] Wherein, a kind of composite masterbatch, comprises each material of following parts by weight:

[0062] Graphene 29 parts

[0063] Sodium polyacrylate 10 parts

[0064] 5 parts fatty amine salt

[0065] Aluminum powder 15 parts

[0066] 2 parts microcrystalline cellulose

[0067] 10 parts ethanol

[0068] Silicone 3 parts

[0069] 1 plant polyphenol,

[0070] Described graphene is 10 layers of graphene.

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Abstract

The invention belongs to the field of preparation of composite fibers and particularly relates to graphene composite PP fibers and a preparation method thereof. The graphene composite PP fibers comprise the following matters: grapheme, sodium polyacrylate, a cationic surface active agent, a filler, microcrystalline celluloses, a solvent, silica gel and plant polyphenol, wherein the filler is one of or a variety of or any quality ratio of aluminum oxide, aluminum powder, titanium dioxide or pyrophyllite powder; the solvent is ethanol or acetone; the grapheme is 3-10 layers of grapheme. The graphene composite PP fibers and the preparation method thereof provided by the invention have the benefit that the comprehensive performance of the PP fiber is effectively improved.

Description

technical field [0001] The invention belongs to the field of composite fiber preparation, and in particular relates to a graphene composite PP fiber and a preparation method. Background technique [0002] PP (polypropylene) fiber has light weight, high strength, good elasticity, wear resistance, corrosion resistance, electrical insulation and warmth retention, and occupies a large market in the field of fiber application. However, polypropylene fiber has high resistivity (7×10Ω.cm) and low thermal conductivity. Compared with other chemical fibers, polypropylene fiber has the best electrical insulation and warmth retention, but it is prone to static electricity during processing; and polypropylene fiber has the best electrical insulation and warmth retention properties. Low melting point (165~173°C), poor stability to light and heat. [0003] In the prior art, in order to expand the application range of PP fibers, the comprehensive properties of PP fibers are usually changed...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L33/02C08L1/04C08L83/04C08K13/02C08K3/04C08K3/22C08K3/08C08K3/34C08K5/17D01F6/46D01F1/10D01D5/08
CPCC08L23/12C08L2203/12C08L2205/035D01D5/082D01F1/10D01F6/46C08L33/02C08L1/04C08L83/04C08K13/02C08K3/04C08K3/22C08K3/08C08K3/34C08K5/17
Inventor 刘娜邵群领
Owner SHAOXING BIAODIAN TEXTILE TECH
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