Self-repairing three-dimensional carbon fiber/memory alloy aircraft shell layer and preparation method thereof

A memory alloy and carbon fiber technology, which is applied to the field of self-healing three-dimensional carbon fiber/memory alloy aircraft shell and its preparation, can solve the problems of reduced bearing capacity, layered splitting of composite materials, and increased difficulty in recovery of composite materials, so as to improve the bearing capacity. ability, the effect of relieving internal stress and reducing internal defects

Active Publication Date: 2018-04-20
浙江万丰飞机制造有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It can be seen from the above prior art that the composite material prepared by combining carbon fiber and polymer material has the characteristics of low density and high strength, but the carbon fiber composite material is prone to produce microcracks of different sizes under the action of external load environment, making the composite The internal layering of the material splits, resulting in a reduction in the bearing capacity and increasing the difficulty of recovery of the composite material. Therefore, carbon fiber composite materials with self-healing properties have become a difficult research point

Method used

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  • Self-repairing three-dimensional carbon fiber/memory alloy aircraft shell layer and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] (1) T700 carbon fiber is used as the weft yarn, the wavy nickel-titanium memory alloy is used as the warp yarn, and a three-dimensional angular interlocking structure is adopted. The warp yarn is interwoven with the weft yarn every two layers in the thickness direction, and a three-dimensional angular interlocking with a volume fraction of 45% is prepared. Base fabric, wherein the content of carbon fiber in the three-dimensional corner interlocking base fabric is not less than 60%.

[0026] (2) Immerse the three-dimensional angular interlocking base fabric in an electrolyte solution with a concentration of 3 wt %, anodize for 2 minutes at a relative current density of 8 mA / g, wash and dry, and obtain an oxidized three-dimensional angular interlocking base fabric.

[0027] (3) After mixing the repairable epoxy resin modified by diphenylmethane bismaleimide and polyethersulfone according to the mass ratio of 2:5, put it into the mold, and spread the microcapsules containin...

Embodiment 2

[0029] (1) T700 carbon fiber is used as the weft yarn, the wavy nickel-titanium memory alloy is used as the warp yarn, and a three-dimensional angular interlocking structure is adopted. The warp yarn is interwoven with the weft yarn every two layers in the thickness direction, and a three-dimensional angular interlocking with a volume fraction of 50% is prepared. Base fabric, wherein the content of carbon fiber in the three-dimensional corner interlocking base fabric is not less than 60%.

[0030] (2) Immerse the three-dimensional angular interlocking base fabric in an electrolyte solution with a concentration of 5 wt %, anodize for 3 minutes at a relative current density of 10 mA / g, wash and dry, and obtain an oxidized three-dimensional angular interlocking base fabric.

[0031] (3) After mixing the repairable epoxy resin modified by diphenylmethane bismaleimide and polyethersulfone according to the mass ratio of 3:10, put it into the mold, and spread the microcapsules contain...

Embodiment 3

[0033] (1) T700 carbon fiber is used as the weft yarn, the wavy nickel-titanium memory alloy is used as the warp yarn, and a three-dimensional angular interlocking structure is adopted. The warp yarn is interwoven with the weft yarn every two layers in the thickness direction, and a three-dimensional angular interlocking with a volume fraction of 46% is prepared. Base fabric, wherein the content of carbon fiber in the three-dimensional corner interlocking base fabric is not less than 60%.

[0034] (2) Immerse the three-dimensional angular interlocking base fabric in an electrolyte solution with a concentration of 4 wt%, anodize it at a relative current density of 9mA / g for 2.5min, wash and dry, and obtain an oxidized three-dimensional angular interlocking base fabric.

[0035] (3) After mixing the repairable epoxy resin modified by diphenylmethane bismaleimide and polyethersulfone according to the mass ratio of 2.5:7, put it into the mold, and spread the microcapsules containin...

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Abstract

The invention provides a self-repairing three-dimensional carbon fiber/memory alloy aircraft shell layer and a preparation method thereof. The self-repairing three-dimensional carbon fiber/memory alloy aircraft shell layer comprises carbon fiber-based three-dimensional base cloth and a self-repairing polymer filler. The preparation method specifically comprises the following steps: taking carbon fiber as weft yarn and a wavy memory alloy as warp yarn, adopting a three-dimensional angle interlocking structure, and interweaving each two layers of the warp yarn with the weft yarn in the thicknessdirection to prepare three-dimensional angle interlocking base cloth; immersing the three-dimensional angle interlocking base cloth in electrolyte for anodic oxidation treatment, and carrying out cleaning and drying to obtain oxidized three-dimensional angle interlocking base cloth; and after uniformly mixing repairable epoxy resin and polyethersulfone, putting the mixture into a mold, flatly paving micro-capsules containing photosensitizer in the mold, soaking the base cloth in the mold, and carrying out standing adsorption, heating, pressurizing and microwave curing to obtain the self-repairing three-dimensional carbon fiber/memory alloy aircraft shell layer. The shell layer prepared with the method provided by the invention has the advantages of being low in weight, high in strength, capable of self-repairing internal damages, and prolonged in service life.

Description

technical field [0001] The invention belongs to the technical field of carbon fiber aircraft shell materials, in particular to a self-repairing three-dimensional carbon fiber / memory alloy aircraft shell and a preparation method thereof. Background technique [0002] With the increasing development of aircraft and aviation technology, the performance of aircraft is continuously improved, and the structural weight coefficient of aircraft is required to be continuously reduced. Therefore, it poses a huge challenge to the material and structure of aircraft, and light weight has become the main trend of aircraft and aircraft development. . At present, the materials used in aircraft and aircraft shells are mostly conventional materials such as aluminum alloy and steel combined with advanced composite materials. In order to reduce the weight factor of the aircraft, the proportion of composite materials is continuously increasing. Requirements in terms of life, manufacturability an...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L81/06C08L63/00C08K9/00C08K7/06C08J5/24
CPCC08J5/24C08J2381/06C08J2463/00C08K7/06C08K9/00
Inventor 陈滨刘国正吴士强张昭
Owner 浙江万丰飞机制造有限公司
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