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Method and treatment system for reducing silicon content in industrial water

A technology for industrial water and silicon content, applied in water/sewage treatment, water/sewage multi-stage treatment, water/sludge/sewage treatment, etc., can solve the problem of increasing the silicon removal load of the primary desalination station and the small processing capacity , environmental pollution and other issues, to achieve the effect of improving the conductivity of water quality, stable pH value of water quality, and wide source of raw materials for treatment

Inactive Publication Date: 2018-05-11
PANZHIHUA IRON & STEEL RES INST OF PANGANG GROUP
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The water standard for industrial boilers has strict restrictions on the content of silicon. Most of the silicon in the water must be removed before entering the boiler. Silica scale is dense and hard, which is difficult to clean with ordinary methods, which seriously affects the heat transfer efficiency and safe operation of the equipment, and is likely to bring hidden dangers to production safety
In thermal power plants, silicic acid in water is a harmful substance, which will not only form scale on the furnace tube with high heat load, but also cause salt accumulation on the turbine blades, resulting in failure of boilers and turbines
Fouling can reduce power output by 10% to 20%, and thermal efficiency by 10%
Although the amount of silicate scale is small, it is very harmful, especially it can interact with other ions, which not only increases the amount of scale formation, but also increases the hardness of scale, which brings huge hidden dangers to industrial boilers
[0003] The traditional silicon removal method commonly used in boiler feed water is to use solid magnesium salt and resin method to remove silicon technology. The main problems of the above method are: complex process, small processing capacity, large amount of waste residue, low efficiency, unstable effect, etc., and The resin method also requires complex equipment and processes such as water quality modification and decarbonization, which seriously pollutes the environment and requires high operating costs.
In addition, when the silicon content in the water source is high, the existing silicon removal methods have limited processing capacity, which brings great difficulties to the subsequent treatment of the desalinated water system and increases the silicon removal load of the first-level desalinated water station. The quality of desalinated water cannot fully meet the production requirements, especially the SiO in the effluent of primary desalinated water 3 2- The concentration cannot reach the standard

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-3

[0083] A method for reducing silicon content in industrial water, which is treated by compound addition of several chemicals, including:

[0084] Produce a certain period of time, add 7wt% soda ash, sodium hydroxide and unslaked lime (that is, what embodiment 1 adds is soda ash, what embodiment 2 adds is sodium hydroxide, what embodiment 2 adds is sodium hydroxide in the raw water of high silicon water quality to be treated earlier. 3 What is added is quicklime), and then add 0.25wt% polyaluminum chloride after mixing evenly, after mixing evenly for 20 minutes, then add 1.5wt% cationic polyacrylamide, and then carry out precipitation and filtration treatment to reduce water silicon content.

[0085] The soluble silicon content in the raw water with high silicon water quality in Examples 1-3 is 7117 μg / L, the soluble silicon content in the treated water is 1188 μg / L, 1175 μg / L and 1182 μg / L respectively, and the silicon removal rate is 83.3 %, 83.5% and 83.4%.

Embodiment 4-6

[0087] A method for reducing silicon content in industrial water, which is treated by compound addition of several chemicals, including:

[0088] Produce a certain period of time, add 3wt% milk of lime earlier in the raw water of high silicon water quality to be treated, stir and mix and then add 0.15wt% polyaluminum sulfate, polyferric chloride and polyferric sulfate (i.e. embodiment 4 What added was polyaluminum sulfate, what embodiment 5 added was polyferric chloride, what embodiment 6 added was polyferric sulfate), after mixing uniformly for 40min, add 1.0wt% cationic polyacrylamide again, then Precipitation and filtration are carried out to reduce the silicon content in the water.

[0089] The soluble silicon content in the raw water with high silicon water quality in Examples 1-3 is 5216 μg / L, the soluble silicon content in the treated water is 965 μg / L, 948 μg / L and 955 μg / L respectively, and the silicon removal rate is 81.5 %, 81.8% and 81.7%.

Embodiment 7-9

[0091] A method for reducing silicon content in industrial water, which is treated by compound addition of several chemicals, including:

[0092] For a certain period of production, add 8wt% sodium hydroxide to the raw water with high silicon quality to be treated, stir and mix well, then add 0.35wt% polyaluminum chloride, mix evenly for 60 minutes, then add 2.0wt% Cationic polyacrylamide, anionic polyacrylamide and nonionic polyacrylamide (that is, what was added in embodiment 7 was cationic polyacrylamide, what was added in embodiment 8 was anionic polyacrylamide, and what was added in embodiment 9 was anionic polyacrylamide. Dosing is non-cationic polyacrylamide), followed by precipitation and filtration treatment to reduce the silicon content in water.

[0093] The soluble silicon content in the raw water with high silicon water quality in Examples 1-3 is 10087 μg / L, the soluble silicon content in the treated water is 1817 μg / L, 1810 μg / L and 1795 μg / L respectively, and th...

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Abstract

The invention belongs to the technical field of industrial water treatment and relates to a method and treatment system for reducing the silicon content in industrial water. The method for reducing the silicon content in industrial water utilizes compounding and adding of several agents for treatment and comprises adding a silicon removing agent into raw water to be treated, carrying out uniform mixing, adding a flocculant A into the mixture, carrying out uniform mixing, optionally adding a flocculant B into the mixture, and carrying out precipitation and filtration to reduce the silicon content of the water. The silicon removing agent comprises an alkali metal compound and / or an alkaline earth metal compound. The flocculant A includes an inorganic high-molecular flocculant. The flocculantB includes an organic polymer flocculant. The method and system can effectively reduce the silicon content in the raw water and effectively relieve the silicon removal load in the primary desalination water station system. The method has simple processes, is easy to operate and has good treatment effects.

Description

technical field [0001] The invention belongs to the technical field of industrial water treatment, and in particular relates to a method and a treatment system for reducing silicon content in industrial water. Background technique [0002] Silicon compounds in industrial water will cause different degrees of harm to the production process. The water standard for industrial boilers has strict restrictions on the content of silicon. Most of the silicon in the water must be removed before entering the boiler. Silica scale is dense and hard, which is difficult to clean by ordinary methods, which seriously affects the heat transfer efficiency and safe operation of the equipment, and easily brings hidden dangers to production safety. In thermal power plants, silicic acid in water is a harmful substance. It will not only form scale on the furnace tubes with high heat load, but also cause salt accumulation on the turbine blades, resulting in failure of boilers and turbines. Foulin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/04
CPCC02F1/5245C02F1/56C02F1/60Y02A20/131
Inventor 任艳丽于秀芳邵国庆张景垒
Owner PANZHIHUA IRON & STEEL RES INST OF PANGANG GROUP
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