High-performance coconut shell activated carbon adsorbent for separating methane/nitrogen and preparation method of high-performance coconut shell activated carbon adsorbent

A technology of activated carbon and coconut shell, applied in the field of activated carbon adsorbent and its preparation, high-performance coconut shell activated carbon adsorbent and its preparation field, can solve the problems of difficult to meet industrial application requirements, accelerate global warming, and difficult to separate adsorbents, etc. , to achieve the effect of small pressure drop, improved production efficiency and uniform pore size distribution

Active Publication Date: 2018-05-22
CCTEG CHINA COAL RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] my country is rich in coalbed methane resources, but the degree of utilization is low, especially the low-concentration coalbed methane extracted underground, most of which are directly discharged into the atmosphere. Methane in coalbed methane is a high calorific value carbon energy, and the exhaustion directly causes huge energy Waste, and because methane is also a greenhouse gas with a significant greenhouse effect, its damage to the ozone layer is 21 times that of carbon dioxide. If a large amount of methane in coalbed methane cannot be recycled, it will accelerate global warming and seriously pollute the environment.
Since

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] Example 1, CH 4 / N 2 Preparation of special coconut shell activated carbon for separation

[0048]The coconut shell is crushed to a length of about 5mm, heated to 600°C at a speed of 10°C / min in a tube furnace, and kept at a constant temperature for 30min. The volatile content of the carbonized coconut shell is 10%, and the ash content is 2.3%. After cooling and taking out, the ball mill grinds until 95% passes through a 400-mesh sieve, then mixes it evenly with water at a mass ratio of 10:1, and with coal tar binder at a mass ratio of 2:1, and forms a 4mm cylindrical material on a four-column press After natural air-drying, carry out secondary carbonization: raise the temperature to 650°C at 5°C / min, keep the temperature constant for 1h; The mass ratio of the secondary carbonization material is 1:1, activated at 850°C for 40 minutes, then cooled naturally, washed with water until neutral, and then dried to obtain high-performance CH 4 / N 2 Separation of dedicated c...

Embodiment 2

[0050] Example 2, CH 4 / N 2 Preparation of special coconut shell activated carbon for separation

[0051] The coconut shell is crushed to a length of about 3mm, heated to 600°C at a speed of 10°C / min in a tube furnace, and kept at a constant temperature for 30min. The volatile content of the carbonized coconut shell is 10%, and the ash content is 2.3%. After cooling and taking out, the ball mill grinds to 95% through a 200-mesh sieve, then mixes it with water at a mass ratio of 10:1, and mixes it with (phenolic resin and bentonite 1:1) binder at a mass ratio of 10:3. Form a 4mm cylindrical material strip on a four-column press, and after natural air drying, perform secondary carbonization, raise the temperature to 600°C at a rate of 5°C / min, and keep the temperature for 1h; then place it in 15wt%K 2 CO 3 Immerse in alkaline solution for 6 hours, dry at 120°C and perform physical activation with water vapor. The mass ratio of water vapor and secondary carbonized material is ...

Embodiment 3

[0053] Example 3, CH 4 / N 2 Preparation of special coconut shell activated carbon for separation

[0054] The coconut shell is crushed to a length of about 3mm, heated to 700°C at a speed of 20°C / min in a tube furnace, and kept at a constant temperature for 50min. The volatile content of the carbonized coconut shell is 8.6%, and the ash content is 2.5%. After cooling and taking out, the ball mill grinds the powder until 95% passes through a 200-mesh sieve, then mixes it evenly with water at a mass ratio of 5:1, and with silicone oil binder at a mass ratio of 10:4, and forms a 4mm cylindrical strip on a four-column press , after natural air-drying, carry out secondary carbonization, raise the temperature to 650°C at a rate of 5°C / min, and keep the temperature constant for 30 minutes; The mass ratio with the secondary carbonization material is 1:1, activated at 800°C for 120 minutes, then cooled naturally, washed with water until neutral, and then dried to obtain high-performa...

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Abstract

The invention discloses a high-performance coconut shell activated carbon adsorbent for separating methane/nitrogen and a preparation method of the high-performance coconut shell activated carbon adsorbent. The preparation method comprises the following steps: performing primary carbonization on coconut shells; grinding the coconut shells subjected to the primary carbonization to obtain carbon powder; mixing the carbon powder with an adhesive and water, and performing extrusion forming, thus obtaining a raw material rod; performing secondary carbonization on the raw material rod to obtain a carbonized material; performing immersion modification and activation treatment on the carbonized material in sequence, thus obtaining the high-performance coconut shell activated carbon adsorbent. Theinvention provides a preparation method of fruit shell-based columnar activated carbon. Compared with conventional coconut shell broken carbon, the high-performance coconut shell activated carbon adsorbent has the advantages of regular shape, small pressure drop, high intensity and the like. As the air flow speed is extremely high during adsorption and separation, certain pressure is generated; furthermore, cyclic and repeated use is required, so that the columnar coconut shell activated carbon is more suitable for being used in a pressure swing adsorption process. Compared with a carbon molecular sieve which adopts phenolic resin, the high-performance coconut shell activated carbon adsorbent adopts coconut shells, so that a large number of raw materials can be obtained in Hainan of Chinaand Southeast Asia regions; the raw materials are wide in source and reasonable in prices, so that stable quality and reasonable price can be guaranteed more easily.

Description

technical field [0001] The invention relates to an activated carbon adsorbent for separating methane / nitrogen and a preparation method thereof, in particular to a high-performance coconut shell activated carbon adsorbent and a preparation method thereof, belonging to the field of comprehensive energy utilization. Background technique [0002] my country is rich in coalbed methane resources, but the degree of utilization is low, especially the low-concentration coalbed methane extracted underground, most of which are directly discharged into the atmosphere. Methane in coalbed methane is a high calorific value carbon energy, and the exhaustion directly causes huge energy Waste, and because methane is also a greenhouse gas with a significant greenhouse effect, its damage to the ozone layer is 21 times that of carbon dioxide. If a large amount of methane in coalbed methane cannot be recycled, it will accelerate global warming and seriously pollute the environment. Since 2011, the...

Claims

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Application Information

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IPC IPC(8): B01J20/20B01J20/30C01B32/324C01B32/336C01B21/04B01D53/047C07C7/12C07C9/04C10L3/10
CPCB01D53/047B01J20/20C01B21/0461C07C7/12C10L3/105C10L2290/542C07C9/04Y02C20/20
Inventor 张进华王鹏李雪飞李兰廷李艳芳车永芳郭昊乾李小亮王宇航
Owner CCTEG CHINA COAL RES INST
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