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Graphene anticorrosive coating, preparation method of anticorrosive coating, and method for coating wind power spindle

A technology for anti-corrosion coatings and wind power spindles, applied in anti-corrosion coatings, epoxy resin coatings, devices for coating liquids on the surface, etc., can solve problems such as general anti-corrosion capabilities, achieve outstanding physical isolation, improve cathodic protection, and improve dispersion sexual effect

Inactive Publication Date: 2018-06-01
JIANGYIN ZENKUNG FORGING CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The anti-corrosion ability of the existing technology is average, and the general idea of ​​anti-corrosion is adopted, just like Dayu's thought of flood control before flood control, and this may not be the best solution

Method used

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  • Graphene anticorrosive coating, preparation method of anticorrosive coating, and method for coating wind power spindle
  • Graphene anticorrosive coating, preparation method of anticorrosive coating, and method for coating wind power spindle

Examples

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Embodiment 1

[0017] The present invention is a graphene anticorrosion coating, comprising the following components in weight percent: Graphene 0.01, polymethylsiloxane 35, epoxy resin 10 with a solid content of 50%, anticorrosion material 5, auxiliary agent 3, silane coupling Agent 1, the balance is the base material that acts as a solvent. The anti-corrosion material is zinc powder. The epoxy resin is polyglycidyl ether; the auxiliary agent includes a curing agent and a leveling agent; the silane coupling agent is vinyltriethoxysilane. The curing agent includes methyl ethyl ketone peroxide; the leveling agent is BYK361; the base material is composed of the following components in weight percentage: cuprous oxide 25, xylene 10, zinc oxide 10, iron oxide 2.5, ethylbenzene 2.5, oxide Copper 1, polyamide dispersion: 0.5; pyrithione 2.5.

[0018] The method for preparing graphene anti-corrosion coating, graphene is prepared the dispersed graphene oxide colloid by adopting modified Hummers me...

Embodiment 2

[0021] The only difference from Example 1 is that it includes the following components in weight percentage: graphene 7, polymethylsiloxane 45, epoxy resin 15 with a solid content of 50%, anti-corrosion material 20, auxiliary agent 6, silane couple Joint agent 3, the balance is the base material that acts as a solvent. The anti-corrosion material is zinc-chromium alloy powder. Epoxy resin is triglyceride propyl ether; The auxiliary agent includes curing agent and leveling agent; The silane coupling agent is vinyl tris (β-methoxyethoxy) silane and N-(β- Aminoethyl)-γ-aminopropylmethyldimethoxysilane. The curing agent includes a mixture of cumene hydroperoxide, benzoyl peroxide, and dibenzoyl peroxide; the base material is composed of the following components in weight percent: cuprous oxide 50, xylene 25, zinc oxide 25 , iron oxide 10, ethylbenzene 10, copper oxide 2.5, polyamide dispersion: 0.3; pyrithione 10.

[0022] The conditions for vacuum heating and ignition are: in ...

Embodiment 3

[0025] The only difference from Example 1 is that it includes the following components in weight percentage: graphene 3, polymethylsiloxane 40, epoxy resin 12 with a solid content of 50%, anti-corrosion material 10, auxiliary agent 4, silane couple Joint agent 2, the balance is the base material used as solvent. The anti-corrosion material is zinc liquid. The epoxy resin is propylene oxide phenyl ether; the silane coupling agent is vinyl tris(β-methoxyethoxy)silane. The curing agent includes benzoyl peroxide; the base material is composed of the following components in weight percent: cuprous oxide 35, xylene 18, zinc oxide 18, iron oxide 7, ethylbenzene 7, copper oxide 1.5, polyamide dispersion Body: 0.7; pyrithione 5.

[0026] The conditions for vacuum heating and ignition are: in a vacuum environment with a vacuum degree of -0.098Mpa, graphene is ignited at 500°C.

[0027] The method of coating the surface of the wind power main shaft with graphene anti-corrosion coating...

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Abstract

The invention discloses a graphene anticorrosive coating. The graphene anticorrosive coating comprises the following components by weight percent: 0.01-7% of graphene, 35-45% of methyl-silicone, 10-15% of epoxy resin with the solid content of 50%, 5-20% of a preservative, 3-6% of an assistant, 1-3% of a silane coupling agent and the balance of a base material serving as a solvent. The invention further discloses a preparation method of the graphene anticorrosive coating and a method for coating a wind power spindle by using the graphene anticorrosive coating. The graphene anticorrosive coatinguses the fact that two-dimensional carbon nanosheet structures of graphene of thermally reduced graphene are stacked layer by layer to form a dense physical anticorrosive insulating layer; the silanecoupling agent modifying technique of the thermally reduced graphene is studied, the silane hydrolysis hydroxyl and an oxygen-containing group on the surface of the thermally reduced graphene form achemical bond, the silane amino directly participates into the curing of the epoxy resin, a dense anticorrosive film is formed through overlap joint; the synergistic activation of the graphene and a zinc powder is studied to form a conductive path protected by a metal base cathode, the excellent electrochemical protection is realized, the multi-anticorrosion technique facing the wind power spindlein the severe marine service environment is formed; the reverse thinking is adopted to change corrosion prevention into leading.

Description

technical field [0001] The invention relates to graphene anticorrosion coatings. Background technique [0002] Large-scale wind power main shafts, especially offshore large-scale wind power main shafts, have high anti-corrosion requirements. It is generally expected that the service life of wind power main shafts can reach 20 years. However, the current anti-corrosion measures for wind power main shafts are not high in anti-corrosion performance, and it is difficult to achieve 20 years. The amount of zinc used in the current anti-corrosion method High cost, high cost, serious zinc fog pollution on the work site, and poor working environment for workers. The patent application publication number is CN107192327A: a wheel gauge for coating and the high anti-corrosion coating process of the wind power main shaft using the wheel gauge, which is realized by changing the mechanical structure of the coating; the patent authorization announcement number is CN 102775877B: Western wind...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D183/04C09D163/00C09D5/10C09D7/61B05D5/00B05D7/00
CPCB05D5/00B05D7/54B05D2301/00B05D2504/00B05D2518/12C08K2003/0893C09D5/106C09D183/04B05D2420/01B05D2420/02C08L63/00C08K13/02C08K3/08C08K3/04
Inventor 徐建东申吉余兰驹
Owner JIANGYIN ZENKUNG FORGING CO LTD
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