Molybdenum platinum porous composite material as well as preparation method and application thereof
A porous composite material and composite material technology, which is applied in the field of electrocatalyst research, can solve the problems of hydrogen being immature, unfavorable for wide application, general performance, etc., and achieve the effects of improving application value, stable structure, and simple operation
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Embodiment 1
[0038] Preparation of platinum / molybdenum sulfide / carbon nanotube composites (pt-MoS x / CNTs)
[0039] (1) Electrode pretreatment: Take a glassy carbon electrode (PINE USA, rotating disk electrode, diameter 5mm), and perform polishing, washing, and 20KHz ultrasonic pretreatment for 60s in sequence;
[0040] (2) Preparation of carbon nanotube-modified glassy carbon electrodes: add a certain amount of arrayed carbon nanotubes to a mixture of ethanol and water with a volume ratio of 1:4, and ultrasonically form a suspension at 40KHz for 2 hours. Add dropwise on the surface of the glassy carbon electrode pretreated in step (1), dry naturally to form a uniform thin layer of carbon nanotubes, and obtain a carbon nanotube-modified glassy carbon electrode;
[0041] (3) Prepare the electroplating solution: add ammonium thiomolybdate and sodium perchlorate to a certain amount of deionized water, adjust the pH to 0~13 with ammonia water and hydrochloric acid, and obtain the electroplati...
Embodiment 2
[0048] Preparation of platinum / molybdenum disulfide / carbon nanotube composites (pt-MoS 2 / CNTs)
[0049] (1) Electrode pretreatment: Take a glassy carbon electrode (PINE USA, rotating disk electrode, diameter 5mm), and perform polishing, washing, and 20KHz ultrasonic pretreatment for 60s in sequence;
[0050] (2) Preparation of carbon nanotube-modified glassy carbon electrodes: add a certain amount of arrayed carbon nanotubes to a mixture of ethanol and water with a volume ratio of 1:4, and ultrasonically form a suspension at 40KHz for 2 hours. Add dropwise on the surface of the glassy carbon electrode pretreated in step (1), dry naturally to form a uniform thin layer of carbon nanotubes, and obtain a carbon nanotube-modified glassy carbon electrode;
[0051] (3) Prepare the electroplating solution: add ammonium thiomolybdate and sodium perchlorate to a certain amount of deionized water, adjust the pH to 0~13 with ammonia water and hydrochloric acid, and obtain the electropla...
Embodiment 3
[0056] Preparation of platinum-molybdenum / carbon nanotube composites (pt-Mo / CNTs)
[0057] (1) Electrode pretreatment: Take a glassy carbon electrode (PINE USA, rotating disk electrode, diameter 5mm), and perform polishing, washing, and 20KHz ultrasonic pretreatment for 60s in sequence;
[0058] (2) Preparation of carbon nanotube-modified glassy carbon electrodes: add a certain amount of arrayed carbon nanotubes to a mixture of ethanol and water with a volume ratio of 1:4, and ultrasonically form a suspension at 40KHz for 2 hours. Add dropwise on the surface of the glassy carbon electrode pretreated in step (1), dry naturally to form a uniform thin layer of carbon nanotubes, and obtain a carbon nanotube-modified glassy carbon electrode;
[0059] (3) Prepare the electroplating solution: add potassium molybdate and sodium perchlorate to a certain amount of deionized water, adjust the pH to 0~13 with ammonia water and hydrochloric acid, and obtain the electroplating solution 0-10...
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