Emulsion with core-shell structure and environment-friendly interior wall coating containing emulsion

A core-shell structure and interior wall coating technology, which is applied to biocide-containing paints, antifouling/underwater coatings, coatings, etc., can solve the problem of not balancing environmental protection and usability, stain resistance, and Reduced scrubability, increased VOC content, etc., to achieve excellent stain resistance, excellent scrub resistance, and improved conversion rate

Inactive Publication Date: 2018-09-04
NIPPON PAINT GUANGZHOU
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this coating has serious drawbacks, due to the T of the coating film g It is also very low, and it tends to become soft and sticky when the temperature is high, which greatly reduces the stain resistance and scrub resistance of the product, and cannot balance environmental protection and usability well.
Conversely, if the product's T g If the temperature is increased, the minimum film-forming temperature will also increase accordingly. If you want to form a film at a lower temperature, you must add a film-forming aid, which greatly increases the VOC content in the product.

Method used

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  • Emulsion with core-shell structure and environment-friendly interior wall coating containing emulsion
  • Emulsion with core-shell structure and environment-friendly interior wall coating containing emulsion
  • Emulsion with core-shell structure and environment-friendly interior wall coating containing emulsion

Examples

Experimental program
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preparation example Construction

[0068] The preparation method of above-mentioned core-shell structure emulsion comprises the following steps:

[0069] 1) Preparation of pre-emulsion: add emulsifier and sodium polyacrylate into water, mix uniformly, then add mixed monomer 1, mix uniformly, fully emulsify, and obtain pre-emulsion;

[0070]2) Seed polymerization: adding a part of the initiator and the mixed monomer 2 into the pre-emulsion to carry out a polymerization reaction to obtain a seed emulsion;

[0071] 3) Emulsion polymerization: adding the remaining initiator and mixed monomer 3 into the seed emulsion to carry out a polymerization reaction, and then adding a pH buffer to adjust the pH value of the reaction solution to obtain a core-shell structure emulsion;

[0072] The mixed monomer 1 is composed of methyl methacrylate, styrene, butyl acrylate and methacrylic acid, and n 甲基丙烯酸甲酯 +n 苯乙烯 丙烯酸丁酯 +n 甲基丙烯酸 (that is, the total substance amount of methyl methacrylate and styrene is less than the total su...

Embodiment 1

[0095] A kind of core-shell structure emulsion, its raw material composition is as shown in the following table:

[0096] The raw material composition table of a kind of core-shell structure emulsion of table 1

[0097]

[0098]

[0099] The preparation method of above-mentioned core-shell structure emulsion comprises the following steps:

[0100] 1) Preparation of pre-emulsion: Add polyoxyethylene alkylphenyl ether, sodium lauryl sulfate and sodium polyacrylate into deionized water, mix well, then add mixed monomer 1 (containing 6 parts of methyl methacrylate ester, 2 parts of styrene, 7 parts of butyl acrylate and 4 parts of methacrylic acid), heated to 80°C, stirred and emulsified for 0.5h to obtain a pre-emulsion;

[0101] 2) Seed polymerization: Add 0.4 parts of ammonium persulfate and mixed monomer 2 (containing 3 parts of hydroxypropyl acrylate) dropwise to the pre-emulsion, and after 1 hour, the dropwise addition is completed, and then polymerized at 80°C for 2 ...

Embodiment 2

[0104] A kind of core-shell structure emulsion, its raw material composition is as shown in the following table:

[0105] The raw material composition table of a kind of core-shell structure emulsion of table 2

[0106] raw material

parts by mass

Methyl methacrylate

18

Styrene

8

Butyl acrylate

10

Methacrylate

4

ethyl acrylate

3

Sodium polyacrylate

1.5

Polyoxyethylene alkylphenyl ether

0.8

Sodium dodecyl sulfate

2

sodium bicarbonate

0.5

Ammonium persulfate

0.5

Deionized water

51.7

[0107] The preparation method of above-mentioned core-shell structure emulsion comprises the following steps:

[0108] 1) Preparation of pre-emulsion: Add polyoxyethylene alkylphenyl ether, sodium lauryl sulfate and sodium polyacrylate into deionized water, mix well, then add mixed monomer 1 (containing 6 parts of methyl methacrylate ester, 3 parts of styrene, 7 parts of b...

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Abstract

The invention discloses an emulsion with a core-shell structure and an environment-friendly interior wall coating containing the emulsion. The emulsion with the core-shell structure is obtained by semi-continuous polymerization of methyl methacrylate, styrene, butyl acrylate and methacrylic acid, wherein the environment-friendly interior wall coating consists of the emulsion with the core-shell structure, titanium white powder, a filler, a dispersing agent, a wetting agent, a defoaming agent, a thickening agent, a bactericide, a mildew inhibitor, a pH regulator and water. The latex particles in the emulsion with the core-shell structure provided by the invention have a soft-shell hard-core structure, wherein soft shells can ensure that the prepared coating product also has excellent low-temperature film forming property without the addition of a film-forming auxiliary agent, and hard cores can ensure that the prepared coating product has high hardness after film formation of the coating product, does not turn soft or sticky at a high temperature, and still has the basic properties of excellent stain resistance, washing resistance and the like. The environment-friendly interior wallcoating provided by the invention does not contain volatile organic compounds (VOC), is safe and environmentally friendly, and has high hardness and excellent stain resistance and washing resistanceafter the film formation.

Description

technical field [0001] The invention relates to a core-shell structure emulsion and an environment-friendly interior wall paint containing the emulsion. Background technique [0002] Coatings have been widely used in people's lives, greatly improving people's living and working environments, and bringing huge economic benefits. At the same time, with the improvement of people's awareness of environmental protection and health, traditional solvent-based paints have been gradually replaced by water-based paints. Compared with solvent-based paints, water-based paints greatly reduce VOC. VOC can irritate human skin and eyes, damage the nervous system, hematopoietic system, and seriously endanger human health. [0003] VOC in water-based interior wall coatings mainly comes from the following three aspects: 1) Water-based interior wall coatings mainly use acrylic resin emulsions as film-forming substances, and the monomers of acrylic resin emulsions are not completely converted ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F265/02C08F220/14C08F220/06C08F220/18C08F220/20C08F212/08C09D151/00C09D7/61C09D7/63C09D7/65C09D5/16
CPCC09D7/63C09D7/65C09D7/70C09D151/003C08F265/02C09D5/1662C09D7/61C08L2201/08C08L71/02C08L1/284C08K13/04C08K7/26C08K3/34C08K5/47C08F220/18C08F220/1804C08F220/1802
Inventor 钟艳桃熊绍泊向慧周复荣黄理荣
Owner NIPPON PAINT GUANGZHOU
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