A method of resource utilization of waste plastics in urban solid waste to promote iron ore reduction

A technology for recycling waste plastics, which is applied in the fields of ecological environmental protection and comprehensive utilization of resources, and can solve the problems of not considering the crushing of waste plastics, the low metallization rate of pellets, and the difficulty in application.

Active Publication Date: 2019-10-11
UNIV OF SCI & TECH BEIJING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0007] In the prior art, the Chinese patent (Application No.: 201410348368.7) titled "An iron-based carbon-containing pellet with waste plastic as a carbon source and its preparation method" discloses an iron pellet with waste plastic as a carbon source. Based carbon-containing pellets and their preparation methods, but the patent only uses a mixture of several waste plastics as the reducing agent, and requires the particle size of the waste plastics to be less than 80 meshes. It is difficult to crush plastic waste plastics. The patent does not consider how to economically Efficiently realize the shredding of waste plastics, especially for the film waste plastics produced in large quantities in daily life, this method is more difficult to apply
In addition, a large number of experiments have proved that it is difficult to obtain a high degree of reduction when using waste plastic alone as a carbon-containing pellet reducing agent because the decomposition temperature of the plastic is much lower than the reduction temperature of iron oxides.
[0008] The Chinese patent with the application number 201310578312.6 discloses a method of using waste plastics to directly reduce limonite or hematit

Method used

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  • A method of resource utilization of waste plastics in urban solid waste to promote iron ore reduction
  • A method of resource utilization of waste plastics in urban solid waste to promote iron ore reduction
  • A method of resource utilization of waste plastics in urban solid waste to promote iron ore reduction

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Embodiment 1

[0029] according to figure 1 As shown, the present invention provides a method for low-temperature carbonization-iron ore reduction synergistic resource utilization of waste plastics in urban solid waste, using polyethylene and polyvinyl chloride film waste plastics, which are the main components of waste plastics in municipal solid waste, as raw materials, Break it into fragments with a side length of 10-20 mm, mix the two at a mass ratio of 1:1, and mix them evenly with anthracite powder (see Table 1 for the composition of anthracite). The proportion of waste plastics in the mixed reducing agent is 20%, coal If the particle size of the powder is less than 0.2mm, heat the mixture at 450°C for 20 minutes, discharge it after cooling, and then crush it to 0.2mm to obtain a mixed reducing agent.

[0030] will contain Nb 2 o 5 3.18% low niobium ferroniobium concentrate ore powder containing titanium (see Table 2 for the composition of ferroniobium concentrate), weight is the mix...

Embodiment 2

[0036] The mixed reducing agent was prepared by the method described in Example 1. The high-phosphorite ore powder with a phosphorus content of 0.38%, the weight of high-phosphorite (see Table 3 for the composition of high-phosphorite) 16% mixed reducing agent (preparation method is the same as in Example 1, and anthracite coal powder is set Be the control group of reductant), weight is the CaCO of pyrite weight 39% 3 , the fluorspar whose weight is 5% of the iron ore weight, and the binder whose weight is 2% of the iron ore weight are transported to the mixer through a belt for mixing, and the moisture content of the mixed material is adjusted to 7%. The mixed material is conveyed to the double-roller ball pressing machine through the belt to make carbon-containing pellets, the pressure is 15MPa, and the size of the pellets is 40×30×20mm pillow-shaped ellipsoid. The raw balls are dried and spread on the carbonaceous refractory material of the rotary hearth furnace in a singl...

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Abstract

A method for recycling plastic wastes in urban solid wastes to promote iron ore reduction comprises the following steps: drying film waste plastics separated from the urban solid wastes, shearing andcrushing the dried film plastic wastes, fully mixing the crushed film plastic wastes with a carbon reducing agent powder, performing low-temperature carbonization treatment at 400-550 DEG C to obtaina carbonization product, crushing the carbonization product to form a reducing agent containing carbon pellets, uniformly mixing and compacting the reducing agent containing carbon pellets with an iron-containing material to prepare carbon-containing pellets, conveying the carbon-containing pellets to a rotary hearth furnace, and performing rapid reduction. The initial reduction temperature of thepellets is significantly reduced and the reduction rate is accelerated to obtain high-quality metalized pellets, and the waste plastics are decomposed and consumed in the reduction process, and provide energy for the furnace heating of the rotary hearth furnace. The method solves a problem that existing direct reduction methods for processing the waste plastics cannot realize the preprocessing offilm thermoplastic plastic wastes in the urban solid waste in the manner of low cost, high efficiency and large scale, promotes the reduction of iron ores, and has the advantages of simple process, short flow, high efficiency, low cost, and good social and economic benefits.

Description

technical field [0001] The invention mainly belongs to the fields of ecological environmental protection and resource comprehensive utilization, and specifically relates to a method for pretreatment of film waste plastic in urban domestic garbage and using it as an iron ore reducing agent, which is used for resource utilization of film waste plastic in urban domestic waste. Background technique [0002] The garbage problem can be said to be a "world problem" accompanying the history of human civilization. With the continuous deepening of my country's new urbanization process, the scale and number of cities are growing explosively. According to the household registration population statistics of municipal districts at the end of 2015, there are 134 large cities with a population of more than 1 million. According to the annual discharge of about 300 kilograms of domestic waste per person, the annual urban domestic waste production is nearly 200 million tons, and it is still g...

Claims

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Application Information

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IPC IPC(8): C21B13/10C22B1/24
CPCC21B13/0066C21B13/105C22B1/24Y02P10/20
Inventor 王广王静松薛庆国张诗瀚张浩
Owner UNIV OF SCI & TECH BEIJING
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